Influence of the preparation conditions on the size and morphology of nanocrystalline lanthanum orthoferrite

Nanocrystalline LaFeO₃ is prepared by the dehydration of coprecipitated lanthanum and iron(III) hydroxides. It is shown that the behavior of the samples during heating and the size distribution of LaFeO₃ nanocrystals can be considerably different depending on the scheme used for coprecipitation of lanthanum and iron hydroxides; independently of the method employed for coprecipitation of the initial compounds, sintering of the samples at 950°C leads to the formation of lanthanum orthoferrite crystals up to 100 nm in size.     

Production and structural features of a water-soluble polysaccharide from a mutant strain of Agrobacterium sp.

We have developed a mutant strain derived from Agrobacterium sp. ATCC 31750, which produces a water-soluble polysaccharide having potential utility to the food, feed, pharmaceutical and cosmetic industries. A high concentration of product (15 g/L) is obtained by 48 h cultivation of the mutant strain under optimized fermentation conditions. The water-soluble polysaccharide obtained from cultures of the mutant strain beta82 has Glc:Man:Gal in approximate molar ratios of 5.8:6.7:1.0. The molecular weight of the polysaccharide was determined to be approximately 1000 kDa by HPSEC analysis. Linkage analysis contained 3-Glcp, 3-Manp, terminal Glcp and terminal Manp, as well as a small proportion of 3- and 3,4-Galp, and 4,6-Manp residues. Based on analyses using FT-IR and ¹³C NMR spectrometers, most glycosidic bonds joining these sugar residues are of the α-type, and acetyl groups are apparently attached to the polymer chain at random.     

Effects of surfactant/silica and silica/cerium ratios on the characteristics of mesoporous Ce-MCM-41

Using the surfactant CTMABr (cetyltrimethyl ammonium bromide) and cerium(IV) sulfate, mesoporous Ce-MCM-41 molecular sieves were produced under a hydrothermal condition with various surfactant/silica (surfactant/Si) and silica/cerium (Si/Ce) ratios. Changes to the structural traits caused by changing the molar ratios of both surfactant/Si and Si/Ce were investigated. XRD (X-ray diffraction), FT-IR (fourier transform infrared spectroscopy), and SEM (scanning electro microscopy) were used for the characterization of prepared mesoporous samples. Among the tested molar ratios, surfactant/Si ratio of 0.5 and 0.2 showed highest values of d_1 0 0 and intensity, respectively, for the Si-MCM-41. XRD analysis also identified a quintessential hexagonal structure of Ce-MCM-41 for the Si/Ce molar ratio higher than 40 (maintaining the surfactant/Si ratio at 0.2). When cerium content was increased to have the Si/Ce molar ratio of 20, the hexagonal structure of Ce-MCM-41 was collapsed due to the structural stress of substituted cerium. FT-IR results confirmed calcination of Ce-MCM-41 and the incorporation of Ce⁴⁺ ions of cerium sulfate into the silica surface with proper removal of the surfactant. Rod-like shape with rounded edges of the prepared Ce-MCM-41 samples was identified by SEM. These results suggest surfactant/Si ratio of 0.2 and Si/Ce ratio of 40 for the production of Ce-MCM-41 with the highest level of crystallinity.     

Generalized model of the formulation of the required composition of pitch-coke mixtures

Known methods of calculating the required compositions of pitch-coke mixtures in producing large graphitized electrodes are not widely used [1, 2]. This may be attributed to the multivariance of the problem, the probabilistic character of the technological operations, the lack of well-founded optimization criteria, and the sensitivity of the characteristics of the product to variation in the parameters of the initial materials and their ratios in the mixture. The only means of solving the problem is physical modeling, taking account of current computer capabilities.     

Testing a new composition of periclase spinel objects

On the basis of periclase powder (70%) and aluminomagnesia spinel (30%), synthesized from secondary aluminum production waste and caustic magnesite, test objects are produced of periclase spinel composition satisfying the requirements of GOST 1579-006-00190495-98. The articles are successfully tested in the working layer for lining tunnel furnace cars of OAO Kombinat Magnezit. __________ Translated from Novye Ogneupory, No. 8, pp. 16–17, August 2008.     

Heating furnace monolithic refractory lining

Contemporary solutions are presented for completion of a monolithic refractory lining for a heating furnace using products produced by OOO Keralit. __________ Translated from Novye Ogneupory, No. 3, pp. 80–83, March 2008.     

Granular-structure chromium-bearing refractories: Properties and uses

Results are presented on the corrosion resistance of chromium-bearing refractories of granular structure acted on by corrosive molten slags, metals, and glasses. It is possible to recommend these refractories to customers for particular conditions of use. Chromium-bearing refractories increase the working lives of furnaces considerably. __________ Translated from Novye Ogneupory, No. 1, pp. 55–61, January, 2008.     

Formation of the complex oxide NaNdTiO<Subscript>4</Subscript>

The processes of phase formation in the Na₂CO₃-TiO₂ and Na₂CO₃-TiO₂-Nd₂O₃ systems are investigated in the temperature range 600–900°C. The high-temperature solid-phase reactions underlying the process of formation of complex oxide NaNdTiO4 are studied. It is established that the synthesis of the NaNdTiO₄ compound occurs through the reaction of the intermediate product Na₈Ti₅O₁₄ with neodymium oxide in the temperature range 720–780°C. The optimum method is proposed for synthesizing NaNdTiO₄, which makes it possible to reduce the temperature of the synthesis, to avoid the formation of impurities, and to obtain the product in a finely dispersed state.     

Investigation of the functional role of sepiolite in organosilicate composites

The functional role of sepiolite in organosilicate composites is investigated. It is demonstrated that the addition of the organomodified sepiolite to organosilicate composites during their fabrication in amounts of 1 wt % increases the thixotropy and pseudoplasticity of “polydimethylphenylsiloxane-silicate-inorganic pigment” suspensions and prevents sedimentation of pigments and fillers, as well as the formation of dense sediments in the course of storage. Upon introduction of this stabilizing additive, the physicomechanical and protective properties of organosilicate coatings remain good. Original Russian Text ? S.V. Chuppina, 2008, published in Fizika i Khimiya Stekla.