How Henri Lefebvre missed the modernist sensibility of Mies van der Rohe: vitalism at the intersection of a materialist conception of space and a metaphysical approach to architecture

This paper looks at two theoretical statements about ‘space’, both of which are grounded in a vitalist philosophy. The first is Henri Lefebvre's formulation of ‘spatial architectonics’, a structure of concepts which he develops in The Production of Space; the second is Mies van der Rohe's intuition of something he termed ‘authentic form’, a means of triggering new experiences and understandings through sensual engagement with space. Since there are other philosophers and other architects whose thinking about space has been influenced by vitalist philosophy, the discussion will begin with an explanation as to why Lefebvre and van der Rohe have been selected for reciprocal examination.     

Dynamic and kinetic modeling of isotopic transient responses for CO insertion on Rh and Mn–Rh catalysts

Isotopic transient tracer techniques have been employed to study heterogeneous hydroformylation on Rh/SiO₂ and Mn–Rh/SiO₂. Pulse injection of D₂ and allowed tracing of the deuterium and CO incorporation pathway into the aldehyde product. The d₁- and d₂-propionaldehyde responses showed a double-peak, or two-hump, response to the D₂ pulse, while showed a single-hump response to the pulse. Analysis of the product responses to the D₂ pulse in CO/H₂/C₂H₄ and CO/H₂/C₂H₄/C₂H₅CHO suggests that the first hump of the d₁- and d₂-propionaldehyde responses was due to rapid H/D exchange with adsorbed propionaldehyde via enol intermediates. The decay of the second hump was due to reaction of adsorbed acyl with spillover hydrogen/deuterium. The response was due to CO insertion followed by acyl hydrogenation. Compartment modeling of the product responses from the and D₂ pulse inputs allowed determination of residence times of adsorbed intermediates, surface coverages of adsorbed intermediates, and the elementary rate constants for acyl hydrogenation and CO insertion. Elementary rate constants for acyl hydrogenation determined from this study were consistent with the value calculated by transition state theory (TST). The addition of Mn promoter to Rh/SiO₂ increased coverages of , , and and shifted the rate-limiting step for propionaldehyde formation. Acyl hydrogenation is the rate-limiting step on Rh/SiO₂ while CO insertion and acyl hydrogenation are both kinetically significant on Mn–Rh/SiO₂.     

Identification of Host Attractants for the Ethiopian Fruit Fly, <Emphasis Type="Italic">Dacus ciliatus</Emphasis> Loew

The Ethiopian fruit fly, Dacus ciliatus, is an oligophagous pest of cucurbit crops, particularly melons, cucumbers, and marrows (summer squash). The present study aimed to identify host attractants for D. ciliatus and was guided by a behavioral bioassay and an electrophysiological assay. We tested volatile compounds from the fruits of a host plant, ripe and unripe Galia melon, Cucumis melo var. reticulates. Both sexes were attracted to melon volatiles. Those of ripe melon were preferred. Gas chromatography-electroantennographic detection analysis of the behaviorally active ripe melon volatiles consistently showed that 14 compounds elicited similar antennal responses from both sexes. Twelve compounds were identified by gas chromatography-mass spectrometry (GC-MS) using GC-MS libraries, retention indices (RI), and authentic standards. The electrophysiological activities of the compounds that were present at sufficient levels for identification, benzyl acetate, hexanyl acetate, (Z)-3-hexenyl acetate, (Z)-3-octenyl acetate, octanyl acetate, (Z)-3-decenyl acetate, and (E)-β-farnesene, were evaluated at six different dosage levels by using electroantennography (EAG). Benzyl and hexanyl acetates elicited dose responses only in males, while other tested compounds elicited dose responses in both sexes. The strongest responses were observed for doses between 100 ng and 10 μg. The dose response, in terms of attractiveness to synthetic compounds within the active range (as determined by EAG), also was evaluated in the behavioral bioassay. Synthetic acetates were attractive to both sexes when tested individually. Significant attraction was observed when individual compounds were applied in the bioassay arena at doses of 0.5–1 μg/dispenser. Blends of compounds in equal proportions also were attractive to the insects. The most attractive blend was a mixture of four or five identified acetates. The addition of an equal proportion of (E)-β-farnesene to this mixture had a deterrent effect.     

Who said what? Source memory for narrator and character agents in literary short stories.

One dimension of reading literacy involves the tracking of agents associated with the text. In a literary short story, there is a society of character agents and pragmatic agents. This study investigated the relative salience of different classes of agents in memory. Two experiments measured source memory as an index of agent salience in long-term memory. Patterns of source memory scores supported an invisible third-person narrator hypothesis and an agent amalgamation hypothesis, but not a structural prominence hypothesis: First-person narrator > nonnarrator character > third-person narrator > 0. Statement detection parameters did not significantly differ among the 3 classes of agents, so differences in source memory could not be explained by differences in the content of the speech acts. Source memory scores also could not be explained by surface features of the text, differences among readers, and sophisticated guessing on the basis of a story abstract. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Recent advances in chemokines and chemokine receptors

Chemokines are a superfamily of small cytokine-like molecules which have been described primarily on the basis of their ability to mediate the migration of verious cell types, particularly those of lymphoid origin. The receptors for these molecules are all seven-transmembrane domain G protein-coupled receptors that have historically been excellent targets for small-molecule drugs. This fact, coupled with the advent of large-scale DNA database mining and the recognition that chemokine receptors are also coreceptors for HIV, has driven discovery in this field at a tremendous rate. This process has included not just an expansion of the number of known chemokines and chemokine receptors, but also a greater appreciation for the variety of functions that chemokines are involved in. We review here the molecules that have come from the most recent years of chemokine research as well as many of the new functions that have been ascribed to them.     

Adaptation of the van Genuchten expression to the effects of temperature and density for compacted bentonites

The main objective of this work is to highlight the influence of variables like temperature and porosity (dry density) on the water retention curve of expansive clays for the analysis of thermo-hydro-mechanical coupled processes (THM problem).The paper presents retention curves of MX-80 bentonite measured under isochoric conditions for different dry densities and temperatures. The influence of dry density on the water retention capacity depends on the suction range, the limiting value being around 30 MPa. For suctions above this threshold value, the retention capacity in terms of water content is higher as the dry density increases, whereas for lower suctions, the lower the dry density the higher the water content for a particular suction. The retention capacity decreases with temperature, more than predicted by the change in interfacial tension of air–water, especially for high temperatures and low suctions.Accordingly, some modifications of the van Genuchten [van Genuchten, M.Th., 1980. A closed-form equation for predicting the hydraulic conductivity of unsaturated soils. Soil Sci. Soc. Am. J., 44, 892–898.] law have been proposed to fit the experimental values. Effects of temperature and porosity on the water retention capacity (other than the traditionally included in the air entry value coefficient) were incorporated through empirical laws that resemble the experimental evidences. By a fitting process, values of the coefficients in those laws were determined for the material used in this work.Finally, several 1D THM simulations using the computer code “CODE_BRIGHT” have been performed in order to analyse the consequences of considering or not temperature and density influences on the water retention curve.     

Rural tourism: A sustainable alternative

The aim of this article is to show and share the results of the research we made in order to improve the situation of sustainable interior rural tourism in Spain. We chose our region: Aragon and we studied the case. We had to consider the financial crisis in the hope that our results would contribute to minimize it. We knew beforehand that rural tourism had been less affected than other sectors but still it was important to reach our goal.     

Effects of postharvest UV‐C treatment on carotenoids and phenolic compounds of vine‐ripe tomatoes

Light red tomatoes were exposed to different doses of ultraviolet C (UV‐C) irradiation (1.0, 3.0 and 12.2 kJ m^?2). After treatment, the tomatoes were stored for 2 days at room temperature, and then analysed to determine the effect of irradiation on the main antioxidants, carotenoids and phenolic compounds and the results compared with the control samples. The lycopene content was found to have increased by 14% with respect to the control samples, while β‐carotene decreased. Cis‐isomers from lycopene also increased when the tomatoes were exposed to irradiation for more than 3 h. UV‐C irradiation also had a positive effect on total phenolic compounds; however, the same effect was not observed in the individually analysed phenolic compounds. While chlorogenic and ferulic acids increased in content, naringenin and rutin contents decreased. These results suggest that UV‐C irradiation of tomatoes could improve the beneficial effect of red tomatoes for human health by increasing the levels of certain bioactive compounds; it could also be used to obtain higher content of bioavailability components, such as cis‐isomers from lycopene.     

Quality assessment of dehydrated red bell pepper using tempering drying cycles

Quality assessment of red bell pepper dices preserved through batch dehydration introducing tempering cycles were performed in this work. The parameters considered were: the percentages of ascorbic acid and final antioxidant activity retention, as well as the influence of calcium chloride on diffusivity and colour values. Although, a similar final moisture content was reached through different red bell pepper dehydration processes, but the one with tempering cycles had better qualities than those without tempering. Ascorbic acid and final antioxidant activity retention showed higher values and so were colour intensities compared to control samples in all cases. In respect to the effective diffusivity coefficients, there was an increment as the calcium chloride concentration increased. As of the treatments with tempering cycles, the best scheme was 15 min drying time and 30 min tempering time at 60 °C.