Prediction of the tensile capacity of cold formed angles experiencing shear lag

The present study deals with the shear lag phenomenon in cold formed angles under tension, which are connected on one leg. A new expression for shear lag factor which represents the net section reduction coefficient has been suggested in the present paper. The proposed expression based on the regression analysis of 108 experimental results reported in the literature is validated by experiments involving net section failure in angles under tension. Totally 18 experiments were carried out on single angles fastened with bolts to the gusset plates under tension loaded upto net section rupture mode of failure. The experimental test parameters considered are number of bolts, pitch and shear lag distances and ratio of connected leg length to unconnected leg length. The tensile capacities are evaluated by various specifications such as AS/NZS:4600:2005, NAS:2001, AISC:2005, BS:5950-Part5:1998, IS:800-2007 and the proposed equation. A comparative study of tensile capacities predicted based on various codes and the experiment results is presented in this paper. For the tested range of specimens, both NAS:2001 and AISC:2005 standards over-predicted the capacities for all the specimens. The IS:800-2007 and AS/NZS 4600:2005 predictions are good for the specimens with three bolted connections and unconservative in the case of specimen with two bolts. Both BS:5950-Part-5:1998 and the proposed equation for IS:801 predict good estimate of the tensile capacity of cold formed angle members. The proposed equation for cold formed steel tension members, which is in the same format of IS:800 (2007) (Indian code for Hot rolled steel design), has been demonstrated to be good.     

Modeling and Analysis of Workflows Using Petri Nets

A workflow system, in its general form, is basically a heterogeneous and distributed information system where the tasks are performed using autonomous systems. Resources, such as databases, labor, etc. are typically required to process these tasks. Prerequisite to the execution of a task is a set of constraints that reflect the applicable business rules and user requirements.In this paper we present a Petri Net (PN) based framework that (1) facilitates specification of workflow applications, (2) serves as a powerful tool for modeling the system under study at a conceptual level, (3) allows for a smooth transition from the conceptual level to a testbed implementation and (4) enables the analysis, simulation and validation of the system under study before proceeding to implementation. Specifically, we consider three categories of task dependencies: control flow, value and external (temporal).We identify several structural properties of PN and demonstrate their use for conducting the following type of analyses: (1) identify inconsistent dependency specifications among tasks; (2) test for workflow safety, i.e. test whether the workflow terminates in an acceptable state; (3) for a given starting time, test whether it is feasible to execute a workflow with the specified temporal constraints. We also provide an implementation for conducting the above analyses.     

Using Semantics for Policy-Based Web Service Composition

Proliferation of Web technologies and the ubiquitous Internet has resulted in a tremendous increase in the need to deliver one-stop Web services, which are often composed of multiple component services that cross organizational boundaries. It is essential that these Web services, referred to in this paper as service flows, be carefully composed in a dynamic and customized manner to suit to the changing needs of the customers. This composition should be conducted in such a manner that (i) the composed service flow adheres to the policies imposed by the organizations offering the component services, (ii) the selected component services are compatible with one another so that the entire composition would result in a successful service flow, and (iii) the selected component services most closely meet the customer requirements. In this paper, we propose a policy-based Web service composition that utilizes the semantics associated with the component services.We consider policies imposed by different entities while composing service flows, which include service policies (imposed by the organizations offering component services), service flow policies (associated with the entire service flow), and user policies (the user requirements expressed as policies). In addition to these policies, one may consider rules at the syntactic and semantic levels that can be used to select relevant component services in order to compose customized service flows, by considering the notions of syntactic, semantic and policy compatibility. We model the different policies and the service topic ontology using OWL, DAML-S, RuleML and RDF standards.Recommended by: Athman Bouguettaya and Boualem BenatallahThe work is supported by and a grant from the Meadowlands Environmental Research Institute, New Jersey Meadowlands Commission.     

Study of flavonoids in aqueous spinach extract using positive electrospray ionisation tandem quadrupole mass spectrometry

The presence of three flavonols (quercetin, kaempferol, myricetin) and two flavones (apigenin, luteolin) were investigated in the extract of fresh spinach leaves. Aqueous spinach extracts were prepared with a leaf/water ratio of 1:2 at 80 °C for 30 min stirring. Ferric ammonium sulphate method was used for measuring total polyphenols in the extracts and expressed as catechins and tannic acid equivalents. The flavonoids glycosides in the extract were hydrolysed to their aglycons with 1.2 M HCl in boiling 50% water methanol solution. The resulting aglycons were identified and quantified by a C18 reverse phase high-performance liquid chromatography (RP-HPLC). Furthermore, the results were confirmed by HPLC coupled to an electrospray ionisation tandem triple-quadrupole mass spectrometer ESI-MS performing low-energy collision induced dissociation (CID-MS/MS) in the collision cell (HPLC-ESI-MS/MS). Analyses were made in the multiple reaction monitory (MRM) mode. Results showed that total polyphenols contents in fresh spinach leaves were 270 mg kg⁻¹ and 390 mg kg⁻¹ as tannic acid and catechin equivalents, respectively, in which, major flavonoids aglycons were apigenin (170 mg kg⁻¹), quercetin (50 mg kg⁻¹) and kaempferol (30 mg kg⁻¹).     

Concurrent optimization of machining process parameters and tolerance allocation

With the advent use of sophisticated and high-cost machines coupled with higher labor costs, concurrent optimization of machining process parameters and tolerance allocation plays a vital role in producing the parts economically. In this paper, an effort is made to concurrently optimize the manufacturing cost of piston and cylinder components by optimizing the operating parameters of the machining processes. Design of experiments (DoE) is adopted to investigate systematically the machining process parameters that influence product quality. In addition, tolerance plays a vital role in assembly of parts in manufacturing industries. For the selected piston and cylinder component, improvements efforts are made to reduce the total manufacturing cost of the components. By making use of central composite rotatable design method, a module of DoE, a mathematical model is developed for predicting the standard deviation of the tolerance achieved by grinding process. This mathematical model, which gives 93.3% accuracy, is used to calculate the quality loss cost. The intent of concurrent optimization problem is to minimize total manufacturing cost and quality loss function. Genetic algorithm is followed for optimizing the parameters. The results prove that there is a considerable reduction in manufacturing cost without violating the required tolerance, cutting force, and power.     

媒染剂和染料用量对红土染料染色棉织物色牢度的影响

从红土中提取天然染料并将其应用于棉织物.改变媒染剂用量和染液用量进行染色试验.结果表明,与不使用媒染剂的试样相比,使用媒染剂的天然红土染色织物试样表现出较好的耐水洗、耐光和耐摩擦色牢度,且色牢度随着媒染剂用量的增加而提升.染料用量的增加未导致织物试样的色牢度明显提升.     

Optimization of sensitizer concentration for upconversion photoluminescence of Yb3+/Er3+: La10W22O81 nanophosphor rods

Yb³⁺/Er³⁺codoped La₁₀W₂₂O₈₁ (LWO) nanophosphor rods have been successfully synthesized by a facile hydrothermal assisted solid state reaction method, and their upconversion photoluminescence properties were systematically studied. X-ray diffraction patterns revealed that the nanophosphors have an orthorhombic structure with space group Pbcn (60). A microflowers-like morphology with irregular hexagonal nanorods was observed using field emission scanning electron microscopy for the Yb³⁺(2 mol%)/Er³⁺(2 mol%):LWO nanophosphor. The shape and size of the nanophosphor and the elements along with their ionic states in the material were confirmed by TEM and XPS studies, respectively. A green upconversion emission was observed in the Er³⁺: LWO nanophosphors under 980 nm laser excitation. A significant improvement in upconversion emission has been observed in the Er³⁺: LWO nanophosphors by increasing the Er³⁺ ion concentration. A decrease in the upconversion emission occurred due to concentration quenching when the doping concentration of Er³⁺ ions was greater than 2 mol%. An optimized Er³⁺(2 mol%): LWO nanophosphor exhibited a strong near infrared emission at 1.53 μm by 980 nm excitation. The green upconversion emission of Er³⁺(2 mol%): LWO was remarkably enhanced by co-doping with Yb³⁺ ions under 980 nm excitation because of energy transfer from Yb³⁺ to Er³⁺. The naked eye observed this upconversion emission when co-doping with 2 mol% Yb³⁺. In order to obtain the high upconversion green emission, the optimized sensitizer concentration of Yb³⁺ ions was found to be 2 mol%. The upconversion emission trends were studied as a function of stimulating laser power for an optimized sample. Moreover, the NIR emission intensity has also been enhanced by co-doping with Yb³⁺ ions due to energy transfer from Yb³⁺ to Er³⁺. The energy transfer dynamics were systematically elucidated by energy level scheme. Colorimetric coordinates were determined for Er³⁺ and Yb³⁺/Er³⁺: LWO nanophosphors. The energy transfer mechanism was well explained and substantiated by several fluorescence dynamics of upconversion emission spectra and CIE coordinates. The results demonstrated that the co-doped Yb³⁺(2 mol%)/Er³⁺(2 mol%): LWO nanophosphor material is found to be a suitable candidate for the novel upconversion photonic devices.