Heat Treatment Effect on Lignin and Carbohydrates in Corsican Pine Earlywood and Latewood Studied by PY–GC–MS Technique

Lignin-derived degradation products from non-treated (NT) and heat-treated (T) Corsican pine (Pinus nigra subsp. laricio) obtained by pyrolysis–gas chromatography–mass spectrometry (Py–GC–MS) were investigated, whereby the earlywood (EW) and latewood (LW) parts of the annual ring were considered separately. The data evaluation was done by principal component analysis (PCA) and the Kruskal–Wallis test. There are no differences in the pyrolysis products composition between EW and LW, but NT and T samples were discernible by PCA applied to Py–GC–MS data. Less phenols with longer chains (4-vinylguaiacol, and trans-isoeugenol) than those with shorter chains (guaiacol, 4-methylguaiacol) and an increase of anhydrosugar (AHS) were found among the pyrolysis products after heat treatment. These signs for autocondensation and side chain cleavages in the lignin during heat treatment were more evident in the EW than in the LW and for the crystallization of cellulose. A slight decrease of the carbohydrate/lignin ratio (C/L) after heat treatment indicates a greater degradation of carbohydrates compared to lignin. The relation of pyrolysis products of lignin and mechanical properties of wood was evaluated by regression analysis. An inverse correlation between short-chain phenols and MOE and a direct correlation between long-chain phenols and compression strength was found in case of NT wood, while a weak positive correlation could be observed between short-chain phenols and the density in T wood.     

Merit of hybrid EDFA/Raman amplification in fixed‐grid all‐optical network exploiting multirate transponders

The constant need to improve network capacity and reduce power consumption in current fixed‐grid WDM networks motivates researchers to find alternative solutions other than replacing the deployed equipment. One of the possible solutions is the use of hybrid EDFA/Raman amplifier, which improves signal‐to‐noise‐ratio in a point‐to‐point link. This work aims at quantifying, by means of a detailed power model, the effect of these novel ideas on the power consumption of the network, which is key to build a future green Internet. In particular, we consider the use of a randomly generated topology of 20 nodes to study the effect of hybrid amplification, fiber type, fiber span length, and sensitivity to average link length and average traffic per node. Results show that hybrid amplification in moderate pumping regime minimizes total network power consumption for networks made up of all 3 fiber types in particular for nonzero dispersion‐shifted fiber.     

On Nash equilibria for multicast transmissions in ad-hoc wireless networks

We study a multicast game in ad-hoc wireless networks in which a source sends the same message or service to a set of receiving stations via multi-hop communications and the overall transmission cost is divided among the receivers according to given cost sharing methods. We assume that each receiver gets a certain utility from the transmission and enjoys a benefit equal to the difference between his utility and the shared cost he is asked to pay. Assuming a selfish and rational behavior, each user is willing to receive the transmission if and only if his shared cost does not exceed his utility. Moreover, given the strategies of the other users, he wants to select a strategy of minimum shared cost. A Nash equilibrium is a solution in which no user can increase his benefit by choosing to adopt a different strategy. We consider the following reasonable cost sharing methods: egalitarian, semi-egalitarian next-hop-proportional, path-proportional, egalitarian-path-proportional and Shapley value. We prove that, while the first five cost sharing methods in general do not admit a Nash equilibrium, the Shapley value yields games always converging to a Nash equilibrium. We then turn our attention to the special case in which the receivers’ set R is part of the input (that is only the stations belonging to R have a positive utility which is set equal to infinity) and show that in such a case also the egalitarian and the egalitarian-path-proportional methods yield convergent games. In such a framework, we show that the price of anarchy is unbounded for the game yielded by the egalitarian method and provide matching upper and lower bounds for the price of anarchy of the other two convergent games with respect to two different global cost functions, that is the overall cost of the power assignment, that coincides with the sum of all the shared costs, and the maximum shared cost paid by the receivers. Finally, in all cases we show that finding the best Nash equilibrium is computationally intractable, that is NP-hard. Vittorio Bilò received the degree in Computer Science and the Ph.D. degree in Computer Science at the University of L’Aquila in 2001 and 2005 respectively. He is currently an assistant professor at the Department of Mathematics “Ennio De Giorgi” of the University of Lecce. His research interests include algorithms and computational complexity, communication problems in interconnection networks and game theoretical issues in non-cooperative networks. Michele Flammini received the degree in Computer Science at the University of L’Aquila in 1990 and the Ph.D. degree in Computer Science at the University of Rome “La Sapienza” in 1995. He is full professor at the Computer Science Department of the University of L’Aquila since March 2005. His research interests include algorithms and computational complexity, game theory, communication problems in interconnection networks and routing. He has authored and co-authored more than 70 papers in his fields of interest published in the most reputed international conferences and journals. Giovanna Melideo received the Laurea degree in computer science in 1997 from the University of L’Aquila (Italy) and the Ph.D. degree in computer engineering in 2001 from the University of Rome “La Sapienza”. From November 1999 to February 2000 she was visitor at IRISA/INRIA, University of Rennes 1, Rennes (France) in the ADP group. She was research fellow from June to October 2001 at the University of L’Aquila, where she is currently an assistant professor in the Computer Science Department. Her research interests include algorithms and complexity, algorithmic game theory, wireless networks, models for information integration and cooperative information systems, certification and security in e-service, distributed protocols and dependability. She has been a member of the scientific and organizing committee of the IFIP international workshop on Certification and Security in E-Services (CSES 2002), Montreal, Canada. Luca Moscardelli received the degree in Computer Science at the University of L’Aquila in 2004. He is currently a Ph.D. student in Computer Science at the University of L’Aquila. His current research interests include optimization problems in social and communication networks, and the analysis of the interaction between selfish agents in non-cooperative networks.     

Solid oxide fuel cell systems for distributed power generation and cogeneration

Solid oxide fuel cell (SOFC) is a promising technology for decentralized power generation and cogeneration. This technology has several advantages: the high electric efficiency, which can be theoretically improved through integration in power cycles; the low emissions; and the possibility of using a large variety of gaseous fuels.     

Reciprocal and variational principles in micropolar thermoelasticity of type II

In the present paper, in the context of thermoelasticity of type II (or thermoelasticity without energy dissipation), we establish reciprocal and variational principles of convolutional type for inhomogeneous and anisotropic micropolar thermoelastic materials with a center of symmetry. The results obtained in this work tend to generalize other variational principles (previously proved by the authors) not completely characterizing the initial-boundary value problem in concern.     

Meeting Interactivity Requirements in Mobile E-Witness: An Experimental Study

This paper describes the design and development of a session-layer load balancing mechanism and its deployment in a mobile surveillance system named Mobile E-Witness (MEW), which we have developed (Ghini et al., Multimedia Tools and Applications, 37(3), 293–318, 2008). The load balancing mechanism proposed in this paper allows MEW to effectively meet interactivity requirements and it is based on an “early retransmission” technique that exploits the overall bandwidth provided by a number of heterogeneous (broadband and metropolitan area) wireless adapters incorporated in MEW. This technique anticipates a suspected unavailability of the adapters in order to avoid the effects of network congestion and guarantee continuity of the communication service and support for multimedia services such as IP telephony. We have carried out an experimental evaluation of the MEW prototype in order to assess its effectiveness in meeting interactivity and responsiveness requirements. This paper summarizes our design and the principal results we have obtained from the evaluation mentioned above.     

Heterogeneous photocatalysis: guidelines on experimental setup,catalyst characterization,interpretation, and assessment of reactivity

Soon after the publication of the first pioneering works on heterogeneous photocatalysis, the number of papers on this topic continuously increased. This intriguing field of research is very complex as it endows with an interdisciplinary overview that involves different aspects of chemistry, physics, material and environmental sciences. Even if photocatalytic applications in real processes are often difficult to be implemented and scaled-up, investigations at laboratory scale are easy to be performed, and in some cases they may give rise to misconceptions. For this reason, the present work aims to sum up most of the common experimental techniques and procedures generally used in heterogeneous photocatalysis and to highlight the guidelines and the rules that a rigorous analysis and study of a photocatalytic system must follow. The paper focuses on the importance of standardization of photocatalytic experiments with special attention on the possibility to compare results obtained under different experimental conditions.