Compatibilisation of PPE/SAN blends by triblock terpolymers: Correlation between block terpolymer composition, morphology and properties

Immiscible blends of poly(2,6-dimethyl-1,4-phenylene ether) (PPE) and poly(styrene-co-acrylonitrile) (SAN) with a weight composition of 60/40 were compatibilised by polystyrene-block-polybutadiene-block-poly(methyl methacrylate) triblock terpolymers (SBM) using a two-stage melt-processing approach. In order to investigate the influence of the SBM composition on the compatibilisation efficiency, the block lengths of the triblock terpolymers were systematically varied. The resulting morphological features of the blend systems as function of SBM composition and processing parameters are correlated with the resulting thermal and thermo-mechanical properties. In the ideal case, SBM should be located at the interface as PS is miscible with PPE while PMMA is miscible with SAN. The elastomeric middle block as an immiscible component should remain at the interface. This particular morphological arrangement is known as the ‘raspberry morphology’. A detailed TEM analysis of the blend morphologies following initial extrusion-compounding revealed a high compatibilisation efficiency of the SBM types with equal lengths of the end blocks and, furthermore, the desired raspberry morphology was achieved. In contrast, high PS contents in comparison to the other blocks led to a pronounced micelle formation in the PPE phase. Further evaluation of the blend structures following injection-moulding indicated that the morphologies remain relatively stable during this second melt-processing step. A detailed thermal analysis of all blend systems supports the interpretation of the observed morphological features. The fundamental correlation between SBM composition and blend morphology established in this study opens the door for the controlled development of interfacial properties of such compatibilised PPE/SAN blends during melt-processing.     

Liquid flow and phase holdup—measurement and CFD modeling for two-and three-phase bubble columns

Bubble columns are an important class of contacting devices in chemical industry and biotechnology. Their simple setup makes them ideal reactors for two- and three-phase operations such as fermentations or heterogeneous catalysis. Still, design and operation of these reactors is subject to widely empirical scale-up strategies. With recent advances in the development of measurement techniques, a more detailed approach to the development of optimized reactors for specific operations should become possible. This report is based on detailed measurements of local dispersed phase holdups in a pilot plant-sized bubble column operated at high superficial gas velocities and solid holdups. It deals with the influence of superficial gas velocity, solid loading and sparger geometry on measured and computed liquid flow velocities and holdup distributions. Liquid velocity measurements have been performed using the electrodiffusion method, modeling calculations have been carried out using the computational fluid dynamics (CFD) code CFX-4.3. Measurement results presented here give an insight into the development of liquid circulation and fluctuating velocity distribution depending on superficial gas velocity, solid loading and sparger geometry. CFD results implementing a multi-fluid model with k-ε turbulence and special momentum exchange terms for direct gas-solid interactions show that, even on standard PC workstations, this kind of computations can deliver qualitatively reasonable agreement with measurements.     

Extended bisection method for parameter identification of the transient heat conduction equation for thermo-elastic deformations during drilling

A new interdisciplinary approach is discribed to identifying unknown parameters using an extended version of the known interval bisection method. This developed method is based on the use of finite elements for calibrating the simulation calculation. The resulting thermo-elastic deformations which occur in drilling processes with impaired cooling lubrication are to be used as correction values for tool positioning in the NC control. Based on the strong impact on workpiece temperature of machining, a simulation approach is presented for calculating the temperature fields and their thermo-elastic consequences. In addition, methods are presented to correct these effects. This paper particularly deals with the temperature fields of drilling operations. Special attention is paid to the technique employed for iterative numerical determination of the unknown heat flux η _w and heat transfer coefficient \(\bar {\gamma }\) values. Finally, the data obtained from experiments are compared with those achieved by numerical simulation in order to verify the efficiency of simulation and determination of parameters.     

Wear Mechanism when Machining Compacted Graphite Iron

The industrial application of compacted graphite iron in the automotive industry is taking a rather long time due to its uneconomic machinability, because of a significant decrease in tool life. After six years of holistic research of the PTW in cooperation with foundries, manufactures and material scientists, the wear mechanism was understood and clarified: Sulphur in the microstructure of compacted graphite iron has direct influence on the formation of a manganese-sulphur layer on the cutting edge. For machining gray cast iron this layer protects the cutting edge against abrasive wear. Therefore the design of cutting tools for the machining of CGI must consider the absence of manganese-sulphur layer.     

State of the Art Treatment of Non-Ferrous Castings 3-in-1 Heat Treatment Systems Combine Foundry Processes

The interior of a high-pressure die-casting is of an unsatisfactory quality. Engine blocks made with this die casting process show lower specific engine performance. Pressure die-casting can hardly be heat treated for obvious reasons PSM (Precision Sand Molds) process uses sand and organic binder to generate a mold and even allows the manufacturing of complex diesel engine blocks in aluminum alloys. Combined technologies are available for semi-permanent mold castings with cores and castings made in Precision Sand Molds with organic binders. Castings are placed into the special heat treatment furnace immediately after pouting without the operations in stand alone machinery. This patented Sand Lion^R 3-in-1 technology processes hot castings and carries out three (3) foundry processes simultaneously in one (1) automated machine: 1) De-coring and sand removal; 2) Thermal sand reclamation; 3) Solution heat treatment of castings. The combination of several main casting processes is reflected in significant reductions of energy consumption, of production costs, and improving the quality of the castings. Audits in foundries using the 3-in-1 process showed an average reduction in production costs of more than 30%.     

Life time dependency on the pre-coating treatment of a thermal barrier coating under thermal cycling

A thermal barrier coating system consisting of the single crystalline Ni-based superalloy CMSX 4, a Pt aluminide bond coat and an EB-PVD processed ceramic top coat was thermally cycled in order to study the influence of three different treatments prior the deposition of the ceramic top coat. Besides the standard treatment, one type of treatment was annealing in vacuum, while the other was annealing in an O containing ArH atmosphere; in both cases for 4 h at 1080 °C.Compared to the standard treatment, annealing in vacuum almost doubled and annealing in ArH atmosphere almost tripled the cyclic life time of the ceramic coating. The improvement was related to the creation of a defined alumina scale before and during TBC deposition.     

Using Discriminative Dimensionality Reduction to Visualize Classifiers

Neural Processing Letters - Albeit automated classifiers offer a standard tool in many application areas, there exists hardly a generic possibility to directly inspect their behavior, which goes...     

Determinants for Successful Agile Collaboration between UX Designers and Software Developers in a Complex Organisation

ABSTRACT

Agile and User-centered design processes have been reported to frequently putting contradictory demands on people working within these methodological frameworks. The current research addresses this point by focussing on the crucial relationship between software developer and designer. An online survey, a contextual inquiry, and a diary study were employed with 107 developers and designers in a large media organization to determine the factors for success in agile development cycles. The results from the survey show that while developers and designers have similar levels of satisfaction with agile processes, there are differences in the factors predicting those ratings. Developers are happier with the wider teamwork but want more access to and close collaboration with designers, while the latters’ concern was the quality of the wider teamwork. Additional contextual inquiries and a diary study with pairs of designers and developers reflected the survey findings that close cooperation (and proximity) was essential for improving communication, reducing inefficiencies, and avoiding suboptimal products being released. However, organizational processes, the setup of the work environment, and managerial traditions meant that this close collaboration and localized decision-making was found difficult to maintain. Results from the survey, the contextual inquiry, and the diary study found six factors for success from collaborations emerged.     

Automatic Construction and Verification of Isotopy Invariants

We extend our previous study of the automatic construction of isomorphic classification theorems for algebraic domains by considering the isotopy equivalence relation. Isotopism is an important generalisation of isomorphism, and is studied by mathematicians in domains such as loop theory. This extension was not straightforward, and we had to solve two major technical problems, namely, generating and verifying isotopy invariants. Concentrating on the domain of loop theory, we have developed three novel techniques for generating isotopic invariants, by using the notion of universal identities and by using constructions based on subblocks. In addition, given the complexity of the theorems that verify that a conjunction of the invariants form an isotopy class, we have developed ways of simplifying the problem of proving these theorems. Our techniques employ an interplay of computer algebra, model generation, theorem proving, and satisfiability-solving methods. To demonstrate the power of the approach, we generate isotopic classification theorems for loops of size 6 and 7, which extend the previously known enumeration results. This work was previously beyond the capabilities of automated reasoning techniques. The author’s work was supported by EPSRC MathFIT grant GR/S31099.