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81.
Demonstration and characterization of biomolecular enrichment on microfluidic aptamer-functionalized surfaces 总被引:1,自引:0,他引:1
Thai Huu NguyenAuthor VitaeRenjun PeiAuthor Vitae Milan StojanovicAuthor VitaeQiao LinAuthor Vitae 《Sensors and actuators. B, Chemical》2011,155(1):58-66
This paper demonstrates and systematically characterizes the enrichment of biomolecular compounds using aptamer-functionalized surfaces within a microfluidic device. The device consists of a microchamber packed with aptamer-functionalized microbeads and integrated with a microheater and temperature sensor to enable thermally controlled binding and release of biomolecules by the aptamer. We first present an equilibrium binding-based analytical model to understand the enrichment process. The characteristics of the aptamer-analyte binding and enrichment are then experimentally studied, using adenosine monophosphate (AMP) and a specific RNA aptamer as a model system. The temporal process of AMP binding to the aptamer is found to be primarily determined by the aptamer-AMP binding kinetics. The temporal process of aptamer-AMP dissociation at varying temperatures is also obtained and observed to occur relatively rapidly (<2 s). The specificity of the enrichment is next confirmed by performing selective enrichment of AMP from a sample containing biomolecular impurities. Finally, we investigate the enrichment of AMP by either discrete or continuous introduction of a dilute sample into the microchamber, demonstrating enrichment factors ranging from 566 to 686×, which agree with predictions of the analytical model. 相似文献
82.
Duc-Luong?Vu Choong-Gon?LeeEmail author 《Korean Journal of Chemical Engineering》2016,33(5):1606-1611
The present study proposes the application of ash-free coal (AFC) as a primary fuel in a direct carbon fuel cell (DCFC) based on a molten carbonate fuel cell (MCFC). AFC was produced by solvent extraction using microwave irradiation. The influence of AFC-to-carbonate ratio (3: 3, 3: 1, 3: 0 and 1: 3 g/g) on the DCFC performance at different temperatures (650, 750 and 850 oC) was systematically investigated with a coin-type cell. The performance of AFC was also compared with carbon and conventional hydrogen fuels. AFC without carbonate (AFC-to-carbonate ratio=3: 0 g/g) gave a comparable performance to other compositions, indicating that the gasification of AFC readily occurred without a carbonate catalyst at 850 oC. The ease of gasification of AFC led to a much higher performance than for carbon fuel, even at 650 oC, where carbon cannot be gasified with a carbonate catalyst. 相似文献
83.
Electrical characterization of individual metal‐coated polymer spheres used in isotropic conductive adhesives
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Hoang‐Vu Nguyen Jianying He Tore Helland Helge Kristiansen Knut E. Aasmundtveit 《应用聚合物科学杂志》2016,133(31)
Isotropic conductive adhesives (ICAs) filled with metal‐coated polymer spheres (MPS) have been proposed to improve the mechanical reliability compared to conventional ICAs filled with silver flakes. The electrical properties of MPS play an important role in the electrical performance of macroscopic MPS‐based ICAs. This article deals with the electrical characterization of individual MPS using a nanoindentation‐based flat punch method, in which the resistance and the deformation of single MPS were monitored simultaneously. Four groups of silver‐coated polymer spheres (AgPS) with identical polymer cores but different silver coating thicknesses were tested. The resistance of AgPS decreases gradually with increasing deformation degree of particles, and increases when the deformation of particles is reduced. In addition, the resistance of individual AgPS is dependent on the physical properties of the silver coating, such as thickness, uniformity, and porosity. The thicker the silver coating is, the lower and more stable the resistance of AgPS is. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43764. 相似文献
84.
Trang Vu Ye Xue Trinh Vuong Matthew Erbe Christopher Bennet Ben Palazzo Lucas Popielski Nelson Rodriguez Xiao Hu 《International journal of molecular sciences》2016,17(9)
This study reports the formation of biocompatible hydrogels using protein polymers from natural silk cocoon fibroins and sheep wool keratins. Silk fibroin protein contains β-sheet secondary structures, allowing for the formation of physical cross-linkers in the hydrogels. Comparative studies were performed on two groups of samples. In the first group, ultrasonication was used to induce a quick gelation of a protein aqueous solution, enhancing the ability of Bombyx mori silk fibroin chains to quickly entrap the wool keratin protein molecules homogenously. In the second group, silk/keratin mixtures were left at room temperature for days, resulting in naturally-assembled gelled solutions. It was found that silk/wool blended solutions can form hydrogels at different mixing ratios, with perfectly interconnected gel structure when the wool content was less than 30 weight percent (wt %) for the first group (ultrasonication), and 10 wt % for the second group (natural gel). Differential scanning calorimetry (DSC) and temperature modulated DSC (TMDSC) were used to confirm that the fibroin/keratin hydrogel system was well-blended without phase separation. Fourier transform infrared spectroscopy (FTIR) was used to investigate the secondary structures of blended protein gels. It was found that intermolecular β-sheet contents significantly increase as the system contains more silk for both groups of samples, resulting in stable crystalline cross-linkers in the blended hydrogel structures. Scanning electron microscopy (SEM) and atomic force microscopy (AFM) were used to analyze the samples’ characteristic morphology on both micro- and nanoscales, which showed that ultrasonic waves can significantly enhance the cross-linker formation and avoid phase separation between silk and keratin molecules in the blended systems. With the ability to form cross-linkages non-chemically, these silk/wool hydrogels may be economically useful for various biomedical applications, thanks to the good biocompatibility of protein molecules and the various characteristics of hydrogel systems. 相似文献
85.
Pham Binh Thai Prakash Indra 《Bulletin of Engineering Geology and the Environment》2019,78(3):1911-1925
Bulletin of Engineering Geology and the Environment - Landslide susceptibility assessment was performed using the novel hybrid model Bagging-based Naïve Bayes Trees (BAGNBT) at Mu Cang Chai... 相似文献
86.
Ha Vu Thi Thu Nguyen Manh B. Tam Tran Nhu Thu Vu Thi Yen Pham Thi Hai Phong Pham Hong Nhiem Dao Ngoc Hung Le Quoc Hai Tran Quang 《Journal of Applied Electrochemistry》2022,52(3):607-616
Journal of Applied Electrochemistry - In this study, a sensitive and selective electrochemical sensor based on a zirconia oxide-decorated gold nanoflake nanocomposite-modified glassy carbon... 相似文献
87.
88.
Roland Vogel Regine Boldt Marijan Vučak Liane Häußler 《Polymer Engineering and Science》2014,54(9):2057-2063
It has been reported in the technical literature that whiskers of rodlike single crystals can be used in order to generate shish‐kebab structures or other different lamellae morphologies during isothermal or dynamic crystallization of sheared or presheared polymer melts. The expected advantage of the changed crystalline structure is a reinforcing effect of the composite. A lot of papers reported about the application of inorganic and organic whiskers such as cellulose and chitin whiskers. This study reports on an attempt to use acicular PCC as appropriate whisker for improving mechanical properties of polypropylene. In this article special attention is given to demonstrate the effect of flow induced crystallization under varying shear conditions in order to improve the mechanical properties. The effects were demonstrated using rheology, thermal analysis, tensile testing, and transmission electron microscopy. POLYM. ENG. SCI., 54:2057–2063, 2014. © 2013 Society of Plastics Engineers 相似文献
89.
Many materials, upon fracturing, emit electrons (exo-electrons) by a process called fracto-emission. For a substance or mixture that can deflagrate or detonate upon impact or friction, these exo-electrons may contribute to the initiation of deflagration or detonation. Some materials, such as p-type semiconductors, can absorb exo-electrons and, as used as additives, can reduce the impact or friction sensitivity of propellants or explosives. It was found that the addition of 1% p-type silicon powder did decrease the impact sensitivity of a propellant consisting of ammonium perchlorate in a polybutadiene matrix, but did not reduce the impact sensitivity of powdered cyclotetramethylenetetranitramine (HMX), cyclotrimethylenetrinitramine (RDX), and pentaerythritol trinitrate (PETN). 相似文献
90.
A multivariable missile autopilot is synthesized using an H∞ approach. A tradeoff is achieved between performance, actuators solicitation and uncertainties in the actuators and bending modes dynamics. Robust stability and performance of the control law are then studied in the face of large real parametric aerodynamic uncertainties: computational techniques for real and mixed μ analysis (namely De Gaston and Safonov's, Dailey's, Jones’, Young and Doyle's, Fan, Tits and Doyle's and Safonov and Lee's methods) are briefly reviewed before being used to compute either the exact value, or an interval of the structured singular value (SSV). For small amounts of parameters, the upper and lower bounds provided by these methods are compared to the exact value, computed by De Gaston and Safonov's method. For larger amounts of parameters, NP hardness of the problem prohibits the use of algorithms which compute the exact value: these algorithms are indeed necessarily exponential-time. As an alternative in this case, the use of polynomial-time methods for computing upper and lower bounds leads in our examples to accurate approximates of the real and mixed structured singular values. 相似文献