低密度微泡沫压井液的研究与应用

吐哈油田部分区块地层压力系数小于0.9,常规水基压井液对储层伤害大,若使用油基压井液成本高,环境污染严重。通过实验优选出了一种低密度水基微泡沫压井液。该压井液具有密度低、泡沫强度高、稳定性好、携砂能力强等优点。现场应用表明,低密度微泡沫压井液稳定时间大于48 h,密度在0.70~0.99 g/cm3之间可调,抗油污染能力强,抗油大于8%,抗温在100℃以上,岩心污染后渗透率恢复值大于80%;并且施工方便,成本低,具有储层保护能力,使用微泡沫压井液的井表皮系数在0.20~2.34之间。     

羧酸系列集油剂的水面集油性能

研究了十二烷酸、十四烷酸、十六烷酸和十八烷酸在淡水中的集油能力。结果表明，这4种羧酸在淡水表面的表面膜压随其分子中碳数的增加而增大。其中后两者的表面膜压高达45～50mN／m，显著高于各类油膜膜压，满足集油剂对表面活性物质膜压的要求。4种脂肪羧酸在淡水中使柴油油膜的收缩率在1min时达到最大值，分别为80．0％、81．8％、83．8％和88．2％。它们的己醇、正庚醇、正辛醇、仲辛醇溶液的集油持续性，总体上随羧酸分子碳数增加而增大。其中十六烷酸和十八烷酸集油能力非常接近，它们的正庚醇、正辛醇和仲辛醇溶液使柴油膜面积收缩率在120h后仍保持在66．0％～70．2％。该类集油剂毒性低，易为生物降解，有实际应用前景。     

加氢渣油催化裂化七集总动力学模型的建立

以加工加氢渣油的茂名石化3^＃重油催化裂化装置的工业数据为基础，针对加氢渣油的特点，提出了以渣油四组分作为划分原料集总基础的催化裂化七集总动力学模型。通过变尺度法（B-F-G-S）和龙格库塔法确定动力学参数，并通过工业实测数据验证，表明该模型具有良好的拟合性和外推性，较好地反映了加氢渣油催化裂化反应规律。     

Ni53Mn21Fe1Ga25铁磁性形状记忆合金的显微组织和相变行为

主要研究了少量掺铁对NiMnGa铁磁性形状记忆合金的相变行为和显微组织的影响.透射电镜结果表明1%(原子分数)Fe元素的加入并不会改变基体NiMnGa合金的显微结构,母相仍为L21有序结构,马氏体为7M马氏体,其亚结构为孪晶.DSC结果表明在马氏体逆相变发生前存在一个预相变,这在NiM1nGa系合金中还是第一次发现.研究表明掺铁NiMnGa合金仍然具有良好的磁性能.     

石膏转化制硫酸钾结晶动力学及结晶添加剂研究

研究了浓氨介质中石膏与氯化钾直接转化制硫酸钾的结晶动力学及结晶添加剂的作用效果。结果表明 ,硫酸钾在氨介质中的成核速率与晶体生长速率、悬浮密度、搅拌速率存在如下关联式 :B0 =5 .64 13×10 8G3.32 0 8Mt0 .0 559np0 .2 92 8。加入异丙醇、OP乳化剂及十二烷基苯磺酸钠等添加剂 ,可使硫酸钾结晶产品纯度提高 ,晶体形态整齐均匀     

Mixed oxide supported hydrodesulfurization catalysts—a review

Support effects form important aspect of hydrodesulfurization (HDS) studies and mixed oxide supports received maximum attention in the last two decades. This review will focus attention on studies on mixed oxide supported Mo and W catalysts. For convenience of discussion, these are divided into Al₂O₃ containing mixed oxide supports, TiO₂ containing mixed oxide supports, ZrO₂ containing mixed oxide supports and other mixed oxide supports containing all the rest. TiO₂ containing mixed oxides received maximum attention, especially TiO₂–Al₂O₃ supported catalysts. A brief discussion about their prospects for application to ultradeep desulfurization is also included. An overview of the available literature with emphasis on research carried out in our laboratory form the contents of this publication.     

Ca掺杂钨镁酸铅陶瓷材料的制备及其介电性能

研究了Ca掺杂钨镁酸铅(PMW)陶瓷材料的合成、结构、烧结以及介电性能。结果发现：在Ca^2 摩尔分数小于15％时，能形成单相的PCMW钙铁矿相，结构由原来的斜方相向立方相转变。用二步合成法制备的样品容易致密烧结，气孔率比一步法制备的样品小。Ca的加入降低了材料的介电损耗，在频率为1MHz时，介质损耗达到了10^-4。当Ca^2 摩尔分数大于10％时，材料的Curie峰宽化显著，介电常数温度系数降低。     

Explosive chemistry: Simulating the chemistry of energetic materials at extreme conditions

In this article, we review recent atomistic computational techniques to study the electronic structure aspects and chemistry of energetic materials at high-pressure and/or high temperature. While several mechanisms have been proposed for the initial events of energetic materials at high-pressure, we explore the validity of a proposed shear-induced local metallization via molecular bond bending in the insensitive explosive TATB. We study the effect of high-stress (both uniform and uniaxial) on the electronic energy band-gap and the first chemical event of a prototypical energetic material, that of nitromethane. We also determine chemical reactions rate laws and decomposition mechanisms from a quantum-based molecular dynamics simulation of HMX, a widely used explosive material, at conditions of high density and temperature similar to that encounter under detonation. Finally, we review a new multi-scale computational tool recently developed to model the shock-induced chemistry of energetic materials at the atomistic level, and report its applicability to shocked solid nitromethane. This revised version was published online in June 2006 with corrections to the Cover Date.     

网络管理中事件关联检测机制的研究

网络事件的关联检测是网络管理需要解决的一个关键问题,本文根据分布式网络管理的特点,首次明确定义了网络事件的基本关联关系,在此基础上提出了一种基于Petri Net的事件关联检测机制,实现了基于事件内容的细粒度关联检测,并且在事件检测中充分考虑了时间因素,有效地提高了事件关联检测的准确性。