Small Changes,Big Impact: Tungsten Bronzes with Extremely Large Second Harmonic Generation Achieved by the Transition Metal Doping on the B-Site

Two novel transition metal-doped tungsten bronze oxides, Pb_2.15Li_0.85Nb_4.85Ti_0.15O₁₅ (PLNT) and Pb_2.15Li_0.55Nb_4.85W_0.15O₁₅ (PLNW), are synthesized by high-temperature solid-state reactions. The Rietveld method using the high-resolution synchrotron radiation indicates that PLNT and PLNW crystallize in the orthorhombic polar noncentrosymmetric space group, Pmn2₁ (no. 31). As a class of tungsten bronze oxide, PLNT and PLNW retain a unique rigid framework composed of d⁰ transition metal cation (Ti⁴⁺ or W⁶⁺)-doped highly distorted NbO₆ octahedra along with the subsequently generated Pb/LiO₁₂ and PbO₁₅ polyhedra. Interestingly, the d⁰ transition metal-doped tungsten bronzes, PLNT and PLNW, exhibit extremely large second-harmonic generation (SHG) responses of 56 and 67 × KH₂PO₄, respectively. The observed immeasurably strong SHG is mainly attributed to a net polarization originating from the alignment of highly distorted NbO₆ octahedra with doped transition metals in the frameworks. It is believed that doping transition metal cations at the B-site of the tungsten bronze structures should be an innovative strategy to develop novel high-performance nonlinear optical materials.     

Designing Metallic and Insulating Nanocrystal Heterostructures to Fabricate Highly Sensitive and Solution Processed Strain Gauges for Wearable Sensors

All‐solution processed, high‐performance wearable strain sensors are demonstrated using heterostructure nanocrystal (NC) solids. By incorporating insulating artificial atoms of CdSe quantum dot NCs into metallic artificial atoms of Au NC thin film matrix, metal–insulator heterostructures are designed. This hybrid structure results in a shift close to the percolation threshold, modifying the charge transport mechanism and enhancing sensitivity in accordance with the site percolation theory. The number of electrical pathways is also manipulated by creating nanocracks to further increase its sensitivity, inspired from the bond percolation theory. The combination of the two strategies achieves gauge factor up to 5045, the highest sensitivity recorded among NC‐based strain gauges. These strain sensors show high reliability, durability, frequency stability, and negligible hysteresis. The fundamental charge transport behavior of these NC solids is investigated and the combined site and bond percolation theory is developed to illuminate the origin of their enhanced sensitivity. Finally, all NC‐based and solution‐processed strain gauge sensor arrays are fabricated, which effectively measure the motion of each finger joint, the pulse of heart rate, and the movement of vocal cords of human. This work provides a pathway for designing low‐cost and high‐performance electronic skin or wearable devices.     

热处理非晶态Ni-P合金镀层的晶化过程

运用电沉积的方法在45钢基体上制备Ni-P合金镀层,使用差示扫描量热法(DSC)和热重法(TG)分析非晶态NiP合金镀层在20℃/min加热速率下的热效应和质量变化。在300℃和400℃分别对镀层进行0,15,30,45,60,75min的热处理,采用扫描电镜(SEM)、能谱仪(EDS)、X射线衍射仪(XRD)、显微硬度计对镀层进行表征。结果表明:Ni-P合金镀层在加热过程中的放热峰出现在284.8℃处,镀层的质量和元素组成稳定;晶化过程经历了非晶态、亚稳态NiP和Ni5P2、稳定态Ni3P的转变;经过热处理后,镀层的显微硬度显著提高,最大值达1036.56HV,约为镀态的2倍;热处理态镀层的耐NaCl溶液腐蚀性能比镀态有所下降,但两者都比45钢基体好。     

数控机床操控器人机界面优化设计研究

目的控制器和显示器共同组成数控机床控制面板的整体界面,是机床接受与执行命令的交互平台。从人机交互角度,聚焦于控制器的界面布局进行优化设计。方法基于人机工程学理论的优化流程,采用现场访谈、现场观察等方法,将人机工程学的理论转化为具体考核指标。结论从人机工程学的研究角度出发,结合工业设计、用户体验设计学等内容,从功能区域分区、操纵器色彩设计等方面优化数控机床控制器的界面,提高系统整体效能及使用者满意度,为数控机床系统开发设计提供参考。     

Bochner-Lebesgue空间内的最佳同时逼近

在本文中,我们研究了Bochner-Lebesgue空间内的相对于欧氏空间的Minkowski范数的最佳同时逼近.首先,给出了由距离函数表示的最佳同时逼近的刻画.然后,利用可测选择定理证明其函数取值于一个闭的可分子空间的Bochner-Lebesgue空间,其同时可逼近性等价于此闭的可分子空间的同时可逼近性.最后,指出子空间的可分性是同时可逼近性等价的必要条件.     

Application of Elastic Stiffness Damper with Disc Spring to Numerical Control Punch

The paper aims to analyze the impacts of punch damper stiffness on equipment base and vibration,and introduce the development and application of a disc spring damper featured hard-soft-hard variable stiffness. A damper has four damping columns with C-type disc springs whose laminates plate number gradually increases set by set. Compared with its counterparts,this kind of dampers has the advantages of high energy absorption and vibration damping effect,which not only can effectively reduce the vibration of the foundation of punch press,but also prevents the vibration range from increasing. Also,this kind of dampers is of low cost and convenient to use.     

Electrochemical corrosion behavior of 2A02 Al alloy under an accelerated simulation marine atmospheric environment

The corrosion behavior of 2A02 Al alloy under simulated marine atmospheric environment has been studied using mass-gain, scanning electron microscope/energy dispersive spectroscopy (SEM/EDS), laser scanning confocal microscopy, X-ray diffraction spectroscopy and localized electrochemical methods. The results demonstrate that the relationship between the corrosion induced mass-gain and the corrosion time is in accordance with the power rule. The mass-gain increases gradually during the corrosion time, while the corrosion rate decreases. With ongoing of the corrosion, corrosion products film changed from a porous to a compact structure. The various spectroscopic data show that the corrosion products films composed mainly of Al(OH)₃, Al₂O₃ and AlCl₃. The electrochemical corrosion behavior of the 2A02 Al alloy was studied by electrochemical impedance spectroscopy (EIS).