Gas–Surface Interactions on Quasicrystals

To commemorate the awarding of the Nobel Prize for Chemistry to Daniel Shechtman for his discovery of quasicrystals, this paper reviews our recent studies of the interaction of rare gases and hydrocarbon gases with the tenfold surface of quasicrystalline decagonal Al-Co-Ni.     

Mesoporous Silica Preparation Using Sodium Bicarbonate as Template and Application of the Silica for Hydrocracking of Used Cooking Oil into Biofuel

Silicon - The hydrocracking of used cooking oil into biofuel over mesoporous silica was systematically studied. This research aims to induce the silica pores using NaHCO3 and employ the heteropore...     

Analysis of turbulence and surface growth models on the estimation of soot level in ethylene non-premixed flames

Soot prediction in a combustion system has become a subject of attention, as many factors influence its accuracy. An accurate temperature prediction will likely yield better soot predictions, since the inception, growth and destruction of the soot are affected by the temperature. This paper reported the study on the influences of turbulence closure and surface growth models on the prediction of soot levels in turbulent flames. The results demonstrated that a substantial distinction was observed in terms of temperature predictions derived using the k-ε and the Reynolds stress models, for the two ethylene flames studied here amongst the four types of surface growth rate model investigated, the assumption of the soot surface growth rate proportional to the particle number density, but independent on the surface area of soot particles, f(A_s) = ρN_s, yields in closest agreement with the radial data. Without any adjustment to the constants in the surface growth term, other approaches where the surface growth directly proportional to the surface area and square root of surface area, f(A_s) = A_s and f(A_s) = √A_s, result in an under-prediction of soot volume fraction. These results suggest that predictions of soot volume fraction are sensitive to the modelling of surface growth.     

Rapid Detection of Oil Pollution in Soil by Using Laser-Induced Breakdown Spectroscopy

Detection of oil pollution in soil has been carried out using laser-induced breakdown spectroscopy(LIBS). A pulsed neodymium-doped yttrium aluminum garnet(Nd:YAG) laser(1,064 nm, 8 ns, 200 mJ) was focused onto pelletized soil samples. Emission spectra were obtained from oil-contaminated soil and clean soil. The contaminated soil had almost the same spectrum profile as the clean soil and contained the same major and minor elements. However, a C–H molecular band was clearly detected in the oil-contaminated soil, while no C–H band was detected in the clean soil. Linear calibration curve of the C–H molecular band was successfully made by using a soil sample containing various concentrations of oil. The limit of detection of the C–H band in the soil sample was 0.001 mL/g. Furthermore, the emission spectrum of the contaminated soil clearly displayed titanium(Ti) lines, which were not detected in the clean soil. The existence of the C–H band and Ti lines in oil-contaminated soil can be used to clearly distinguish contaminated soil from clean soil. For comparison, the emission spectra of contaminated and clean soil were also obtained using scanning electron microscope-energy dispersive X-ray(SEM/EDX) spectroscopy,showing that the spectra obtained using LIBS are much better than using SEM/EDX, as indicated by the signal to noise ratio(S/N ratio).     

Analysis of reflectance spectra of tropical seagrass species and their value for mapping using multispectral satellite images

ABSTRACT

Mapping of the distribution of individual seagrass species is essential for any attempts to manage seagrass ecosystems. It is therefore important to understand how the spectra of different seagrass species vary, in order to establish their unique absorption features and how these can be utilised for mapping by making use of remote-sensing images. This paper presents measurements of the reflectance spectra between 400 and 900 nm for nine tropical species of seagrass. Continuum removal and multispectral resampling procedures were applied to the spectra. Dendrogram analysis was carried out to identify species clustering as the basis for a mapping scheme. Spectral Angle Mapper (SAM) and Spectral Information Divergence (SID) approaches were employed for the classification of seagrass species using WorldView-2 images and measured spectra as the input endmember. Classification Tree Analysis (CTA) and an image segmentation approach using CTA (Object-Based Image Analysis – OBIA) were performed as a means of comparison. The results indicate that the absorption features and overall shape of the spectra for all seagrass species are relatively similar, and implied that the major differences are attributable to the absolute reflectance values. Consequently, SAM and SID produced results of low accuracy (<30%), whereas, CTA and OBIA delivered results exhibiting higher accuracy (60–92%). The use of a spectral-based classification algorithm was ineffective for the classification and mapping of seagrass species using multispectral images. The utilisation of absolute reflectance values was beneficial for the classification of seagrass species having similar spectral shape.     

TaqMan probe real‐time polymerase chain reaction targeting the ATPase 6 gene for the detection of pork adulteration in meat and meatballs

We developed an assay for detecting pork adulteration in meat and meatballs using real‐time polymerase chain reaction involving specific primers and a TaqMan probe targeting the porcine mitochondrial (mt) ATPase 6 gene. We proved the specificity of the probe by showing no amplification from DNA isolated from six different meat‐providing species: cattle, dog, mouse, chicken, goat, and horse. On the contrary, DNA isolated from pork was positive for amplification, with a Ct (threshold cycle) of 18.69 using a standard amount of DNA template (50 ng). The presence of matrix and food processing steps in meatball sample had no influence on the specificity of the probe. The developed technique also has a good repeatability (CV, coefficient of variation = 3.86% for meat and 5.07% for meatballs), showing good linearity and sensitivity, with a limit of detection up to 5 pg of pork total DNA, which equivalent to approximately 6.8 copies of pork mtDNA. In addition, the analysis of spiked pork in beef meatballs showed that the method could determine up to 1% pork contamination. Moreover, the system was successfully applied to detect pork adulteration in commercial meatballs by detecting the presence of pork DNA in two samples.     

基于形态损伤监测的复合层板弯曲模型

迫切需要研究有效的技术进行结构的健康监测,提高复合结构的安全性和完整性。研究的主要目的是,采用灵敏的压电材料和现代仪器如扫描激光振动计(SLV),以评估基于动力学的复合层板损伤探测技术。采用两个不同的驱动传感器系统测试一个嵌层的E-玻璃/环氧复合板,两个传感器分别为:1)带有PZT(铅-锆酸盐-钛酸盐)调节器的扫描激光振动计(PZT-SLV);2)带有PZT调节器的聚偏二乙烯氟化物(PVDF)传感器。同时进行了有限元分析以补充损伤探测。试验和数值弯曲模型被用于探测剥离的发生、位置和尺寸。采用三种相对新的损伤探测算法(即简化裂隙平滑方法,广义不规则维数方法及应变能方法)分析试验和数值弯曲模型数据以及均荷表面的曲率。损伤探测成果证实PZT-SLV系统更便利和有效,能够扫描到整个试件的大部分点;可直接获得弯曲模型的PZT-PVDF系统,该系统显示对损伤具有良好敏感性。基于三个模式连续利用的GSM,GFD和SEM损伤探测算法及由此引出的ULS曲率,可以成功识别组合板中剥离的发生、位置和相对尺寸。     

Numerical investigation of pocketed slip slider bearing with non-Newtonian lubricant

Boundary slip as well as surface texturing is an effective method to improve the tribological performance of lubricated mechanical components. This article analyzes the combined effect of single texturing (pocketing) and wall slip on pressure that strongly related to the load-carrying capacity of slider bearing. The modified Reynolds equation for lubrication with non-Newtonian power-law fluid is proposed. The equation was solved numerically using a finite difference equation obtained by means of the micro-control volume approach. Further, numerical computations for slider bearing with several power-law indexes were compared with the presence of the pocket and slip. The numerical results showed that the characteristic of non-Newtonian is similar to Newtonian fluid with respect to hydrodynamic pressure distribution. The maximum load support is achieved when the pocket depth is equal to the film thickness.