Novel nitrogen‐containing epoxy resin. II. Cure kinetics by differential scanning calorimetry

The isothermal and nonisothermal cure behaviors of a novel nitrogen‐containing epoxy resin (XT resin) were studied by differential scanning calorimetry (DSC). Various kinetic parameters and details of cure process were obtained based on the Avrami theory. The results indicated that Avrami method is suitable for calculating the kinetic parameters up to the gel point at least. The apparent activation energy (E_a) for isothermal cure process was in agreement with that for nonisothermal cure process. E_a value in the early stage (78.5–81.0 KJ mol^?1) was about three times than that in the later stage (23.3–26.5 KJ mol^?1). The kinetic results from Avrami theory may present a combined effect of all factors, and which is helpful to understand the cure technique for XT–DDS system. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 3483–3489, 2006     

Charge/discharge characteristics of sulfur composite cathode materials in rechargeable lithium batteries

The charge and discharge characteristics of lithium batteries with sulfur composite cathodes have been investigated. The sulfur composites showed novel electrochemical characteristics. The analysis of the differential capacity indicated that the discharge process showed two voltage plateaus of 2.10 V and 1.88 V, and the charge process also presented two voltage plateaus of 2.22 V and 2.36 V. The overcharge test showed that the composite cannot be charged over 4.0 V, the voltage always stopped at about 3.9 V during charging, indicating that the composite presented the intrinsic safety for the overcharge of lithium batteries. The overcharge can cause serious safety problem for the conventional Li-ion batteries. The overcharge test also showed that the batteries with sulfur composite were destroyed when the upper cut-off voltage was over 3.6 V. However, the composite presented good reversible capacity after it was deep discharged even to 0 V. It showed stable cycleability and high cycling capacity of 1000 mAh g⁻¹ when cycling between 0.1 V and 3.0 V, indicative of the different characteristic from the conventional oxide cathode materials. The prototype polymer battery with the composite cathode material presented the energy density of 246 Wh kg⁻¹ and 401 Wh L⁻¹.     

探索新形势下军民融合式装备保障发展之路

从分析军民融合式装备保障的动因和存在的问题入手,阐述了构建完善军民融合式装备保障体系,必须要在思想观念、法规制度、体制机制、两用标准、军地人才、军用技术和民用技术等6个方面实现融合,为理解、贯彻装备保障走好军民融合式发展之路提供了一些思路和设想。     

抗日战争时期的青年心理探析

抗日战争是中华民族历史上的一次大浩劫,中国人民为此承受了太多的痛苦与磨难,特别是对于肩负着国家与民族振兴使命的青年更是如此.分析战时青年的心理变化及原因,指出政府和社会对青年人的心理没有采取恰当的方法进行有效的疏导,提出要总结和吸取历史的经验教训,为我们今天应对大灾难提供借鉴.     

浅谈土木工程专业毕业设计选题

结合土木工程专业毕业设计的具体情况,分析了毕业设计教学选题环节存在的问题,提出了相应的改进措施.     

不定积分中的几何背景和表格分部积分法

论述了数学背景对数学发展的重要性,提供了不定积分中的几何背景,介绍了不定积分的表格分部积分法及案例,对改革教学内容和改进教学方法进行了尝试。     

作为统一知识体的美术与设计

设计学和美术学是专业分科不断细化的结果,其实设计学和美术学具有共同的理论基础,是统一的知识体。设计和美术在现代主义思潮中的分离只是实践方向的分离,而它们的行动态度则带有相似的社会批判性质。二战后设计力求摆脱美术理论的影响,转而追求创建属于设计学自身的“准科学”理论。但是设计无法回避形式和价值评判这两大问题。美术史学科常常不拘于设计和美术之间人为的界限,为美术和设计共享的理论基础贡献新的知识。我们应当超越对专业化的执着,追求认知的整体性。     

各向异性介质涂覆曲面导体目标的散射

由于各向异性介质电磁参数为张量形式,使得各向异性介质涂覆导体目标的电磁散射建模和精确计算相当复杂和困难.引入高阶张量阻抗边界条件,可以大大简化建模过程,提高计算效率.论文针对各向异性介质涂覆曲面导体目标,采用基于平面近似的高阶张量阻抗边界条件,将一维二阶张量阻抗边界条件应用于柱面涂覆目标,二维二阶张量阻抗边界条件应用于三维曲面涂覆目标上,建立二者的高阶张量阻抗边界条件解.设计算例仿真,并与精确解/矩量法解比较.通过仿真,研究了各向异性介质涂覆目标电尺寸、涂覆厚度以及目标形状对高阶张量阻抗边界条件解的精度的影响.     

溶剂处理对烟梗梗丝内在质量的影响

为比较溶剂处理梗丝和常规工艺生产的梗丝的差别,采用溶剂处理烟梗梗条后在烟梗制丝线上制备梗丝,研究溶剂处理对梗丝内在质量的影响.通过仪器分析与感官质量对比,结果表明:与传统制备工艺相比,溶剂处理对烟梗的持水性、耐加工性和梗丝结构的影响较小,梗丝的填充值增加11.4%;其主要化学成分及致香成分含量有较大变化,对梗丝内在质量有一定程度的改善.     

街道改造中的色彩控制研究

以张家口市宣化区迎宾大道既有建筑外观改造和环境景观整治规划为例,通过城市色彩的整体协调及地域性的城市色彩特色进行街道改造的宏观控制;通过街道两侧既有建筑墙面、屋顶、装饰、标识物、地面、植物等景观要素的配色方案实现街道改造的微观控制,在整体性中形成富于变化的街道景观.