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71.
Thermally conductive polymer matrix composite (PMC) foams with effective thermal conductivities (keff) higher than their solid counterparts have been developed for the first time. Using a material system consists of low density polyethylene and micron‐scale or submicron‐scale hexagon boron nitride platelets as a case example, this article demonstrates that foaming‐assisted filler networking is a feasible processing strategy to enhance PMC's keff, especially at a low hBN loading. Parametric studies were conducted to identify the structure‐to‐property relationships between foam morphology (e.g., cell population density, cell size, and foam expansion) and the PMC foam's keff. In particular, there exists an optimal cell size to maximize the PMC foam's keff for foams with up to 50% volume expansion. However, an optimal cell size is absent for PMC foams with higher volume expansion. X‐ray diffraction (XRD) analyses reveal that both the presence of hBN platelets and foam expansion promoted the crystallization of LDPE phase. Moreover, the XRD spectra also provide evidence for the effect of foam expansion on the orientation of hBN platelets. Overall, the findings provide new directions to design and fabricate thermally conductive PMC foams with low filler contents for heat management applications. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 42910. 相似文献
72.
Two series of heterocyclic aromatic polymers were synthesized from 4,4′‐(4,4′‐isopropylidenediphenoxy)bis(phthaltic anhydride) and 2,2′‐bis(3,4‐dicarboxyphenyl)hexafluoropropane dianhydride by two‐step method. The inherent viscosities were in the range of 24–45 cm3/g. The effects of the rigid benzoxazole group in the backbone of copolymer on the thermal, mechanical, and physical properties were investigated. These polymers exhibit good thermal stability. The temperatures of 5% weight loss (T5) of these polymers are in the range of 403–530°C in air and 425–539°C in nitrogen. The chard yields of these polymers are in the range of 15–24% in air and 54–61% in nitrogen. These polymers also have high glass‐transition temperatures and a low coefficient of thermal expansion and good mechanical properties. The poly(benzoxazol imide) has a higher tensile strength and modulus than those of neat polyimide. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009 相似文献
73.
Engineering and technology educators face potential limitations and problems should they neglect the diversity of social, cultural and political environments in which their students find themselves despite the apparent compression of time and space brought about by technological changes that the difference between individuals is getting smaller. This article looks at the evaluation of engineering and technology education from a social and cultural viewpoint and suggests that the evaluation should aim to be sensitive to local traditions and histories, and to particular wants, needs and fancies 相似文献
74.
I describe and question the argument that in psychological research, the significance test should be replaced (or, at least, supplemented) by a more informative index (viz., effect size or statistical power) in the case of theory-corroboration experimentation because it has been made on the basis of some debatable assumptions about the rationale of scientific investigation. The rationale of theory-corroboration experimentation requires nothing more than a binary decision about the relation between two variables. This binary decision supplies the minor premise for the syllogism implicated when a theory is being tested. Some metatheoretical considerations reveal that the magnitude of the effect-size estimate is not a satisfactory alternative to the significance test. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
75.
76.
Darko Vrečko Marko Nerat Damir Vrančić Gregor Dolanc Boštjan Dolenc Boštjan Pregelj Fabien Meyer Siu Fai Au Robert Makkus Đani Juričić 《International Journal of Hydrogen Energy》2018,43(12):6352-6363
One of the main challenges for wide-spread utilization of the solid oxide fuel cell (SOFC) power systems is how to achieve high electrical efficiency without increasing the degradation rate of the fuel cells. To run the SOFC power system at high efficiency over a long period of time, properly designed controllers are indispensable.Although a number of various approaches to control SOFC have been proposed so far, it seems that the design of control system, along with simple tuning procedure, has not been treated in a consistent manner. This issue is addressed in the present paper resulting in a feedforward-feedback control structure. The feedforward part is based on the stoichiometry of electro-oxidation, reforming and combustion reactions, which allow immediate response to variable current demand. The feedback part performs additional fine adjustment of fuel and air supply in order to minimize the undesired system temperatures variations. The selection of pairings of manipulated and controlled variables for control is based on physical knowledge of the system. Input/output pairing for single-loop feedback control is assessed by the relative gain analysis. An efficient procedure for tuning the parameters of the feedback controllers is suggested, relying on simple open-loop step responses of the system.The proposed low-level control is assessed on a detailed physical model of a 2.5 kW SOFC power system by simulating two nonstationary load regimes. Simulations show that the control provides a robust operation under large load variations while meeting the operating constraints. Due to its simplicity, the control is feasible for implementation on a real SOFC system. 相似文献
77.
Onno B. Bleijerveld Ya-Nan Zhang Serap Beldar Imo E. Hoefer Siu K. Sze Gerard Pasterkamp Dominique P. V. de Kleijn 《Proteomics. Clinical applications》2013,7(7-8):490-503
Cardiovascular disease (CVD) is the leading cause of death and loss of productive life years in the world. The underlying syndrome of CVD, atherosclerosis, is a complex disease process, which involves lipid metabolism, inflammation, innate and adaptive immunity, and many other pathophysiological aspects. Furthermore, CVD is influenced by genetic as well as environmental factors. Early detection of CVD and identification of patients at risk are crucial to reduce the burden of disease and to allow personalized treatment. As established risk factors fail to accurately predict which part of the population is likely to suffer from the disease, novel biomarkers are urgently needed. Proteomics can play a significant role in identifying these biomarkers. In this review, we describe the progress made in proteome profiling of the atherosclerotic plaque and several novel sources of potential biomarkers, including circulating cells and plasma extracellular vesicles. The importance of longitudinal biobanking in biomarker discovery is highlighted and exemplified by several plaque proteins identified in the biobank study Athero-Express. Finally, we discuss the PTMs of proteins that are involved in atherosclerosis, which may become one of the foci in the ongoing quest for biomarkers through proteomics of plaque and other matrices relevant to the progression of atherosclerosis. 相似文献
78.
Confidence measures are computed to estimate the certainty that target acoustic units are spoken in specific speech segments. They are applied in tasks such as keyword verification or utterance verification. Because many of the confidence measures use the same set of models and features as in recognition, the resulting scores may not provide an independent measure of reliability. In this paper, we propose two articulatory feature (AF) based phoneme confidence measures that estimate the acoustic reliability based on the match in AF properties. While acoustic-based features, such as Mel-frequency cepstral coefficients (MFCC), are widely used in speech processing, some recent works have focus on linguistically based features, such as the articulatory features that relate directly to the human articulatory process which may better capture speech characteristics. The articulatory features can either replace or complement the acoustic-based features in speech processing. The proposed AF-based measures in this paper were evaluated, in comparison and in combination, with the HMM-based scores on phoneme and keyword verification tasks using children’s speech collected for a computer-based English pronunciation learning project. To fully evaluate their usefulness, the proposed measures and combinations were evaluated on both native and non-native data; and under field test conditions that mis-matches with the training condition. The experimental results show that under the different environments, combinations of the AF scores with the HMM-based scores outperforms HMM-based scores alone on phoneme and keyword verification. 相似文献
79.
Zhu Dong-Mei Ching Wai-Ki Elliott Robert J. Siu Tak-Kuen Zhang Lianmin 《OR Spectrum》2017,39(4):1055-1069
In this paper, we propose a higher-order interactive hidden Markov model, which incorporates both the feedback effects of observable states on hidden states and their mutual long-term dependence. The key idea of this model is to assume the probability laws governing both the observable and hidden states can be written as a pair of higher-order stochastic difference equations. We also present an efficient procedure, a heuristic algorithm, to estimate the hidden states of the chain and the model parameters. Real applications in SSE Composite Index data and default data are given to demonstrate the effectiveness of our proposed model and corresponding estimation method.
相似文献80.
Allen H. P. Siu Y. K. Lee 《International journal for numerical methods in engineering》1997,40(22):4159-4182
The development of a three-dimensional least-squares finite element technique suitable for deformation analysis was presented. By adopting a spatial viewpoint, a consistent rate formulation that treats deformation as a process was established. The technique utilized the least-squares variational principle that minimizes the squares of errors encountered in any attempt to meet the field equations exactly. Both velocity and Cauchy stress rate fields were discretized by the same linear interpolation function. The discretization always yields a sparse, symmetric, and positive-definite coefficient matrix. A conjugate gradient iterative solver with incomplete-Choleski preconditioner was used to solve the resulting linear system of equations. Issues such as finite element formulation, mesh design, code efficiency, and time integration were addressed. A set of linear elastic problems was used for patch-test; both homogeneous and non-homogeneous deformations were considered. Additionally, two finite elastic deformation problems were analysed to gauge the overall performance of the technique. The results demonstrated the computational feasibility of a three-dimensional least-squares finite element technique for deformation analysis. © 1997 John Wiley & Sons, Ltd. 相似文献