Influence of expandable graphite on fire resistance and water resistance of flame-retardant coatings

Expandable graphite (EG) coating and ammonium polyphosphate-pentaerythritol-melamine (APP-PER-MEL) coating were prepared. Thermal degradation and char formation of the coatings were investigated by differential thermal analysis (DTA), thermogravimetry (TG), X-ray diffraction (XRD), scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). The results have shown that the anti-oxidation and fire-resistant properties of expandable graphite coating containing EG with size of 74 μm are better than those of APP-PER-MEL coating. The static immersion test was applied to study water resistance of the coatings, and the fire protection test and mechanical test were used to analyse heat insulation and mechanical properties of coatings before and after water immersion. The fire-resistant and mechanical properties of APP-PER-MEL coating were severely damaged by water immersion, whereas EG coating containing 8.5% EG with size of 74 μm could retain the good fire resistance even after 500 h water immersion.     

活性酯硬化水玻璃砂的研究

用焙烧活性砂混制而成的活性酯硬化水玻璃砂与普通酯硬化水玻璃砂相比，强度成倍提高，从而减少水玻璃的加入量，改善水玻璃砂的溃散性。实验证明：原砂的表面活性直接影响在水玻璃砂中水玻璃的加入量，是改善水玻璃砂溃散性的关键之一。焙烧活性砂的水玻璃加入量只要１．５％～２．０％，即能满足实际生产的强度要求。     

基体碳对C/CF/Cu复合材料的影响

采用树脂碳化和碳气相沉积相结合的方法制备了碳/碳纤维(C/CF)先驱丝,用压力浸渗凝固成型方法制备了碳/碳纤维/铜(C/CF/Cu)复合材料,借助于扫描电镜下复合材料界面和相分布观察以及显微硬度和滑动摩擦磨损测试,探讨了基体碳(树脂碳化碳和沉积碳)对C/CF/Cu复合材料成型、显微硬度及摩擦磨损的影响.结果表明,碳化和碳气相沉积处理的C/CF先驱丝相对致密并阻碍铜液的压力浸渗成型,但该先驱丝硬度高于碳化处理的C/CF先驱丝.碳化和碳气相沉积处理的C/CF/Cu复合材料滑动摩擦磨损耐磨性高于纯铜,而且滑动摩擦系数也高于纯铜.C/CF/Cu复合材料是一种具有摩阻功能的复合材料.     

Application of an analytical phase transformation model

Employing isothermal and isochronal differential scanning calorimetry, an analytical phase transformation model was used to study the kinetics of crystallization of amorphous Mg82.3Cu17.7 and Pd40Cu30P20Ni10 alloys. The analytical model comprised different combinations of various nucleation and growth mechanisms for a single transformation. Applying different combinations of nucleation and growth mechanisms, the nucleation and growth modes and the corresponding kinetic and thermodynamic parameters, have been determined. The influence of isothermal pre-annealing on subsequent isochronal crystallization kinetics with the increase of pre-annealing can be analyzed. The results show that the changes of the growth exponent, n, and the effective overall activation energy Q, occurring as function of the degree of transformation, do not necessarily imply a change of nucleation and growth mechanisms, i.e. such changes can occur while the transformation is isokinetic.     

空心微球表面化学镀Ni薄膜的工艺研究

比较空心微球表面化学镀Ni薄膜的工艺.分别以Sn-Pd胶体溶液和[Ag(NH3)2]+溶液作为活化剂,将空心微球表面进行活化,再采用化学镀的方法分别在其上淀积金属Ni薄膜.使用扫描电子显微镜(SEM)、能量色散光谱(EDS)和X-射线衍射光谱(XRD)对两种工艺所镀Ni薄膜的表面微观结构和组分进行表征.结果表明:用Sn-Pd胶体溶液活化后的空心微球表面淀积了均匀、致密的金属Ni薄膜,该薄膜是由大小约100 nm的颗粒组成;而以[Ag(NH3)2]+溶液活化后的空心微球表面淀积的金属Ni薄膜,是由大小约1 μm的颗粒组成.并分析了这两种镀层形成的机理.     

高速精密定位X-Y工件台动态精度分析

根据高速精密X-Y工件台的工艺参数的特点,对高速精密定位X-Y工件台的动态精度进行分析,包括阶跃输入时间响应、频率响应、系统的动刚度kD的分析.并从结构及材料方面提出了使高速精密定位X-Y工件台达到良好技术性能指标的方法.     

Airslip结晶器内凝固壳形成特性分析

根据Airslip结晶器的传热特性,建立了凝固壳厚度和临界凝固壳厚度的数学模型.理论分析和实验结果表明,凝固壳厚度与铸造速度的乘积为常数,铸造速度增大,凝固壳厚度减小,铸锭表面质量提高;铸造速度的波动引起凝固壳厚度的波动,降低了铸锭的表面质量;铸锭直径和铸造速度的乘积也为常数,铸锭直径增大,铸造速度相应减小.     

Feedrate optimization and tool profile modification for the high-efficiency ball-end milling process

Trend in die/mold machining is to produce highly quailed surface using the high-speed hard machining with the ball-end cutter. The ball-end milling is, however, less efficiency than the flat end milling. It is important to optimize the feedrate that gives the maximum material removal rate constrained by an allowable surface roughness. The state-of-art of the CBN ball-end cutter technology allows increasing the tooth feed for high-speed and high-efficiency machining. However, because the spherical shape of the cutter can result in the scallop-liked cusps on the machined surface, the surface roughness consideration makes a feedrate limitation to the CBN cutter. In this paper, the optimization of the feedrate by considering the generated-scallop effect of the ball-end cutter has been studied. It was found that the tooth feed must be kept within one third of the path pick in order to keep the feed-interval scallop height not over the path-interval scallop height. Therefore, the potential capability of the CBN cutter for the larger tooth feed (i.e. high efficient) machining can not be fully exploited. It was found a notch-cut on the center of the ball-end cutter reduced the feed-interval cusp height, thus allowing an increased feedrate of more than 50% compared with the standard ball-end cutter. If the parameters of the notch-cut profile can be optimized, it is believed that the feedrate can be further increased.     

液锻连挤硅线石粒子/铝复合材料的摩擦磨损行为

采用液锻连挤成形工艺获得了一种新型硅线石颗粒增强LY12铝基复合材料,其性能可与常规热挤压件媲美.摩擦磨损性能测试表明:硅线石颗粒增强铝基复合材料具有优良的摩擦磨损性能,且其耐磨性能随粒子体积分数增加而增加.材料经液锻连挤后,硅线石粒子在强大三向压应力作用下嵌镶于基体内,粒子很难拉脱,承受摩擦力的作用时,硅线石粒子起支承作用,粒子硬度高,故使复合材料整体耐磨性能提高.     

冲压成形仿真过程中有限元网格模型的建立

网格模型对冲压成形模拟的精度和效率影响极大 ,文中阐述了有限元网格模型建立的方法 ,并从单元尺寸、单元类型、自适应网格再划分技术等方面论述了如何解决精度与效率的问题。