Preparation,characterization, and polymerization of novel maleimidobenzoxazine containing carboxylic moiety and its cocuring behaviors with epoxy resin

A novel benzoxazine containing maleimide and carboxylic moieties, 1‐[3‐(4‐carboxylphenyl)‐3,4‐dihydro‐2H‐benzo[e][1,3]‐oxazin‐6‐yl]maleimide (Mal‐Bz‐Co), was synthesized and the structure was identified by ¹H‐NMR and FTIR. Mal‐Bz‐Co exhibited good solubility in common organic solvents. The cure behavior of Mal‐Bz‐Co and cocure behavior of Mal‐Bz‐Co with o‐cresol formaldehyde epoxy resin were investigated by differential scanning calorimetry. Results indicated that Mal‐Bz‐Co showed a single curing exothermic peak at about 238.3°C. However, the maximum curing temperature (T_p) decreased to 146.1°C when Mal‐Bz‐Co cocured with o‐cresol formaldehyde epoxy resin in the molar ratio of 1 : 1. The T_p was about 92°C lower than that of Mal‐Bz‐Co. Thermogravimetric analysis showed that high‐decomposition temperature and char yield were observed for the cured resins of Mal‐Bz‐Co and Mal‐Bz‐Co/o‐CFER. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010     

建筑中水处理技术及应用分析

介绍了建筑中水的主要处理工艺及中水回用技术应用情况,讨论了建筑中水的经济影响因素、发展趋势和制约中水推广应用的原因。     

深部软弱围岩叠加拱承载体强度理论及应用研究

 目前,长锚索与锚喷网支护相结合的支护方式在深部软弱围岩中已经得到了广泛应用,但是对于这种联合支护结构的承载特点缺乏深入了解,特别是对于初次支护和二次支护的承载能力没有量化解析式。因此,在岩石力学理论的基础上,针对深部软弱围岩的“锚喷网+锚索”联合支护特点,提出由主压缩拱(锚杆支护)和次压缩拱(密集型锚索支护)共同构成的叠加拱承载体力学模型;根据弹塑性理论、锚杆的中性点理论和锚索的力传递机制推导初次支护和适当让压后二次支护的承载体强度方程;并将“围岩–支护结构”组成的共同体看作一种等效耦合围岩,运用弹塑性力学方法得到这种等效耦合围岩的力学参数随释放位移(让压位移)变化的关系式。工程计算表明,金川III矿区破碎硐室经叠加拱支护后,极限承载能力 可达到513.34 kN,等效耦合岩体 值可达到47.54°, 最大值为1.37 MPa,提高围岩的峰后强度,有利于硐室围岩的长期稳定;现场监测也表明,进行叠加拱承载体支护后的硐室围岩变形趋于平稳,收敛速率小于0.1 mm/d。     

Synthesis of dodecylbenzene via the alkylation of benzene and 1-dodecene over mesopore Beta zeolites

The alkylation of benzene with long chain α-olefins is a crucial process in the production of fine chemicals, which requires the upgrading from traditional homogeneous catalysis to heterogeneous catalysis involving zeolites. However, the application of zeolite catalysts has been limited by their fast deactivation due to constrained diffusion resulting from the sole micropores. To address this challenge, a desilication and secondary-crystallization strategy has been employed to fabricate hierarchically structured mesoporous Beta zeolites. The resultant mesoporous Beta zeolites demonstrate excellent catalytic activity and stability in the alkylation of benzene with 1-dodecene, arising from the exposed acid sites and enhanced internal diffusion. Importantly, the internal diffusion limitations for these mesopore Beta zeolites are negligible, which significantly extends their lifetime and improves their regeneration performance. To achieve these benefits, the degree of mesopores must be deliberately controlled. Overall, this approach provides a promising solution for achieving efficient and environmentally friendly alkylation processes.     

Measurement and prediction of isothermal vapor–liquid equilibrium of a-pinene + camphene/longifolene + abietic acid + palustric acid + neoabietic acid systems

The vapor–liquid equilibrium(VLE) data of a-pinene + camphene + [abietic acid + palustric acid + neoabietic acid] and a-pinene + longifolene + [abietic acid + palustric acid + neoabietic acid] systems at 313.15 K,333.15 K and 358.15 K were measured by headspace gas chromatography(HSGC). These data was compared with the predictions value by conductor-like screening model for realistic solvation(COSMO-RS).Moreover, the calculated data of COSMO-RS and Non-Random Two-Liquids(NRTL) models showed good...     

造纸企业能量系统"三环节"模型的建立及应用探讨(Ⅱ)--造纸企业能量系统用能分析与评价

根据"三环节"能量结构模型,对某造纸企业的能量系统进行了热量平衡、(火用)平衡以及能量效率进行了计算和分析,并分别对能量利用环节、能量回收环节和能量转换环节的能量利用、能量回收和能量转换效率进行了评价,分析研究了该厂各环节能量效率低下的因素,指出该厂具有巨大的节能潜力.     

激光对人眼的危害和防护

叙述了激光对人眼的危害作用，阐明了激光防护的重要性。列出了激光防护镜的标准。介绍了如何选择激光防护镜。     

一类非线性系统结构适应式预报器及其应用

本文给出一种变结构式推广的递推梯度算法和一类非线性系统结构适应式预报器。这种算法能够自动改变模型的结构。通过油田预报实践,表明这种预报器能跟踪系统结构性变化,从而提高变结构系统的预报精度。     

无腹筋混凝土短梁受剪承载力尺寸效应研究

《混凝土结构设计规范》(GB 50010—2010)中对于短梁受剪承载力的计算没有考虑梁高的影响,而现有研究表明无腹筋梁的抗剪承载力随梁有效高度的增加而降低。梁受剪尺寸效应的作用机制并没有统一的认识。为研究无腹筋梁的受剪尺寸效应及作用机制,设计了2组8根无腹筋梁,高度为200～1600mm,剪跨比为2.0。三点简支加载。获取了荷载 挠度曲线、纵筋应变、混凝土应变、裂缝宽度、裂缝张开 滑移位移。计算了临界斜裂缝上的应力。搜集并分析了已有的梁受剪尺寸效应试验数据。研究结果表明：无腹筋短梁抗剪承载力存在尺寸效应;骨料咬合机制对无腹筋短梁抗剪承载力贡献有限;受压区未开裂混凝土的强度具有明显的尺寸效应,进而引起了梁抗剪承载力的尺寸效应;我国规范中短梁和不配置抗剪钢筋的单向厚板的抗剪承载力计算公式基本合理,但对部分短梁和大尺寸梁的受剪承载力预测可能偏于不安全,建议在可靠度校准的基础上适当调整。     

高应力节理软岩巷道变形特征及其变形机理

为了解决高应力大变形节理软岩巷道支护控制难题,本文以贵州木孔煤矿+600 m运输大巷作为研究对象,进行现场调查原支护巷道围岩变形情况,分析围岩体物理力学性质,测定矿物成分,模拟围岩体节理分布状况,并研究了该巷道变形破坏特征及其变形机理.最后,通过对改进支护方案后的巷道进行现场实测数据收集,分析并验证新支护方案的合理性和有效性.