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31.
32.
目的 探究贵州主栽辣椒的品质差异,并进行样品品质综合性评价。方法 对25种贵州主栽辣椒的营养指标进行测定,针对品质指标进行统计分析、相关性分析和聚类分析。结果 25种辣椒果实的含水量、辣椒红素、还原糖、总氨基酸、粗脂肪、粗纤维、辣椒素和二氢辣椒素的平均含量分别为0.53 g/g、56.68μg/g、11.08 mg/g、34.86μmol/g、14.95%、22.41%、2.20 g/kg、1.11 g/kg。各个品质在不同材料间的差异明显,其中以二氢辣椒素含量的变异系数最大,达70.24%,最小的为粗纤维,只有13.19%。通过隶属函数分析可知,综合品质最优的品种为黔椒11号。通过相关性分析得出辣椒红素与还原糖、总氨基酸显著负相关(P<0.05),与辣椒素、二氢辣椒素显著正相关(P<0.05);还原糖与总氨基酸、辣椒素显著负相关(P<0.05),与粗脂肪、粗纤维、二氢辣椒素显著正相关(P<0.05);总氨基酸与粗脂肪、含水量、辣椒素、二氢辣椒素显著正相关(P<0.05);粗纤维与辣椒素显著正相关(P<0.05)。通过聚类分析将所有样品分为4类。第1... 相似文献
33.
Yu-Xian Chi Ju-Qing Qiu Wen-Ting Zhu Jing Jin Shu-Yun Niu Guang-Ning Zhang 《Journal of Inorganic and Organometallic Polymers and Materials》2012,22(1):125-133
Four new lanthanide(Ш) coordination polymers, [Ln(p-aminobenzoate)2(DMF)(HCOO) (H2O)]n (Ln = Sm 1, Tb 2, Pr 3) and {[Pr(2,5-dcp)(CH3COO)(H2O)]·1.5H2O}n (4) (DMF = N,N-dimethylformamide, 2,5-dcp = pyridine-2,5-dicarboxylate), have been synthesized by hydrothermal method. The structures are
determined by the single-crystal X-ray diffraction. The four polymers all crystallize in the monoclinic space group P21/n. Polymers 1 and 2 are isostructural; both SmIII ion of polymer 1 and TbIII ion of polymer 2 are eight-coordinate. Although polymer 3 possesses the same asymmetric unit as polymers 1 and 2, the three are not isomorphous. The PrIII ions in polymers 3 and 4 are nine-coordinate. In polymers 1, 2 and 3 the neighboring units are bridged by formyloxy and extend into infinite chains, which are connected by hydrogen bonds to
form a hydrogen bond network. However, polymer 4 is bridged by pyridine-2,5-dicarboxylate and acetates to form an infinite 3D network. At room temperature, the IR, UV–Vis–NIR
and emission spectra of the four polymers were measured and analyzed. The four polymers emit in the visible or NIR region.
The luminescent properties are discussed. 相似文献
34.
Yue-Jiao Lu Nan-Nan Dai Mu-Han Li Wen-Chan Tian Qiang Li Zheng-Jun Wang Keqi Tang Wen-Ting Wei 《Advanced Synthesis u0026amp; Catalysis》1953,366(19):4000-4016
The rapid development of photo-synergistic transition metal catalytic systems has provided a green paradigm to complement thermal transition metal catalytic methods. However, the most commonly used iridium or ruthenium complexes involve expensive in nature, in contrast to the abundant copper elements in the earth's crust, which are highly valued for their unique electronic structure and light-absorbing properties. Recently, the application of copper and photocatalytic synergistic strategies in radical cyclization reactions has progressed considerably, leading to a renaissance in the synthesis of functional natural products, drugs and their analogues, but summary work addressing this aspect has not been reported. In this review, we briefly analyze the effect of ligand choice on copper complexes and some inorganic copper salts and even on light sources. We then summarize the copper and photocatalytic synergistic strategies in radical cyclization reactions and classify them into three categories, C, N and O radicals, according to the class of the central atom of the radical in each work, and in each category will be elaborated in turn from coordination cyclization via Cu catalysts, direct radical cyclization and other cyclization mode. For individual more complex reactions, the mechanisms are explored and briefly discussed. 相似文献
35.
Wen-Chan Tian Nan-Nan Dai Yue-Jiao Lu Mu-Han Li Yiping Ruan Ting Li Wen-Ting Wei 《Advanced Synthesis u0026amp; Catalysis》1953,366(17):3524-3541
The radical difunctionalization of unsaturated hydrocarbons serves as an efficient means to rapidly construct molecular skeletons and synthesize-highly valuable compounds. In this transformational process, diverse positions within unsaturated hydrocarbons are sequentially functionalized by a single radical precursor reagent, thereby achieving highly efficient and selective transformations that promote atom economy. Furthermore, this approach minimizes the generation of numerous byproducts stemming from cross-coupling reactions between reactants, owing to the reduction of the number of participating components. Therefore, this review provides an in-depth analysis of the radical difunctionalization of unsaturated hydrocarbons utilizing a single functional reagent in recent decades. The discussion is based on eight different radical classes (carbon-, nitrogen-, phosphine-, oxygen-, sulfur-, selenium-, tellurium-, and chlorine-centered radicals), emphasizing the mechanism of specific radical difunctionalization. It also analyzes in detail the regulation of key factors such as regional selectivity, and provides unique insights into reaction transformations. 相似文献
36.
报道了HgCdTe长波离子注入n+-on-p型光电二极管列阵低能氢等离子体修饰的研究成果.基于采用分子束外延(MBE)技术生长的HgCdTe/CdTe薄膜材料,通过注入窗口的光刻与选择性腐蚀、注入阻挡层的生长、形成光电二极管的B+注入、光电二极管列阵的低能氢等离子体修饰、金属化和铟柱列阵的制备等工艺,得到了氢等离子体修饰的n+-on-p型HgCdTe长波光电二极管列阵.从温度为78 K的电流与电压(I-V)和动态阻抗与电压(R-V)特性曲线中,发现经过低能氢等离子体修饰的HgCdTe红外长波光电二极管列阵动态阻抗极大值比未经过修饰处理的提高了1~2倍,并在反向偏压大于动态阻抗极大值所处的偏压时动态阻抗得到更为明显的提升.这表明低能氢等离子体修饰可以抑制HgCdTe光电二极管列阵暗电流中的带带直接隧穿电流Ibbt和缺陷辅助隧穿电流Itat,从而能提高长波红外焦平面探测器工作的动态范围和探测性能的均匀性. 相似文献
37.
38.
Shou-Heng Liu Wen-Ting Tang Wei-Xing Lin 《International Journal of Hydrogen Energy》2017,42(38):24006-24013
Nitrogen-doped mesoporous TiO2 has been synthesized by a simple solvent evaporation-induced self-assembly method using a nitrogen-containing ionic liquid concurrently as a nitrogen source and mesoporous template. After being evaporated and subsequently calcined at various temperatures (300–900 °C), the synthesized samples were thoroughly characterized by X-ray diffraction (XRD), Raman, small-angle X-ray scattering patterns (SAXS), N2 adsorption-desorption isotherms, X-ray photoelectron (XPS) and UV–Vis diffuse reflectance (UV–Vis DR) spectroscopies. The obtained results suggest that the calcination temperature greatly influences the crystallization of TiO2, formation of mesoporous structure, specific surface area and N-doping amounts. Among the fabricated photocatalysts, the samples calcined at 600 °C exhibit superior photocatalytic performance for hydrogen production in water/methanol solution under visible light illumination if compared to other synthesized samples and commercial TiO2 (Degussa P25). The finding is possibly due to the synergy of more N-doping amounts on the well-defined mesoporous TiO2 with highly anatase crystal phase and moderate surface area in the catalysts. 相似文献
39.
Chi-Yuan Lee Fang-Bor WengChin-Hsien Cheng Huan-Ruei ShiuShiqah-Ping Jung Wen-Chen ChangPin-Cheng Chan Wen-Ting ChenChung-Ju Lee 《Journal of power sources》2011,196(1):228-234
In this work, a micro-temperature sensor on a 40 μm flexible stainless-steel substrate was fabricated using micro-electro-mechanical systems (MEMS). Embedding a micro-temperature sensor in a proton exchange membrane fuel cell (PEMFC) to monitor temperature will not damage the sensor during the experimental process. This investigation is the first to develop a micro-temperature sensor that can be placed anywhere between the membrane electrode assembly (MEA) and the flow-channel plate inside a PEMFC. The simulated temperature is consistent with the experimentally determined temperature. The performance curve is also consistent with experimental results, revealing the accuracy of the simulation and the effectiveness of monitoring temperature inside a PEMFC. 相似文献
40.
Machine learning algorithms are widely applied to extract useful information, but the sample size is often an important factor in determining their reliability. The key issue that makes small dataset learning tasks difficult is that the information that such datasets contain cannot fully represent the characteristics of the entire population. The principal approach of this study to overcome this problem is systematically adding artificial samples to fill the data gaps; this research employs the mega-trend-diffusion technique to generate virtual samples to extend the data size. In this paper, a real, small dataset learning task in the array process of a thin-film transistor liquid-crystal display (TFT-LCD) panel manufacturer is proposed, where there are only 20 samples used for learning the relationship between 15 inputs and 36 output attributes. The experiment results show that the approach is effective in building robust back-propagation neural network (BPN) and support vector regression (SVR) models. In addition, a sensitivity analysis is implemented with the 20 samples by using SVR to extract the relationship between the 15 factors and the 36 outputs to help engineers infer process knowledge. 相似文献