两种具有电双稳态的全有机络合物

首次发现两种在室温下即具有电双稳态的全有机（有机-有机）络合物，分别称为MCA＋TCNQ和BBDN＋TCNQ。它们可在真空中制备成薄膜，在数伏电压的作用下，从高电阻至低电阻的跃迁时间小于100ns，因此可作为一次写入的存储器材料。根据我国目前最小刻线宽度的水平，可望在1．6cm2的SiO2平面上做出64Mb的存储器。     

PC/ABS合金研究进展

概述了PC/ABS合金国内外的开发应用现状,并综述了国内外近年来对PC/ABS合金的研究进展,其中包括:PC/ABS合金的相容性技术、相容剂的选用及影响合金性能的因素:原料、组分的配比、成型条件等,并对该合金的发展方向作了简要的分析,认为PC/ABS合金的开发研究在国内塑料合金的工业开发、应用中极其重要,开发的核心是相容化技术。     

Catalytic activities and properties of mesoporous sulfated Al2O3–ZrO2

Mesoporous sulfated Al₂O₃–ZrO₂ (MSAZ) catalysts with large surface areas and pore volumes after calcination at high temperature (650 °C) and with higher Al₂O₃ content than 20wt% were successfully prepared from a template of block copolymer (P84). The MSAZ catalysts were characterized by X-ray diffraction (XRD), N₂ adsorption, transmission electron microscopy (TEM), ²⁷Al magic-angle spinning nuclear magnetic resonance (MAS NMR), thermogravimetric analysis (TG–DTG), temperature-programmed desorption of ammonia (NH₃-TPD) and infrared spectra (IR) of adsorbed pyridine. It is shown that the resulting mesostructured sulfated Al₂O₃–ZrO₂ samples have a well-developed textural mesoporosity. The number of acid sites present on MSAZ catalysts is higher than that on conventional sulfated zirconia, and the former catalysts are more active than the latter one for various acid-catalyzed reactions.     

半刚性钢-混凝土组合节点受弯承载力的计算

在半刚性钢 -混凝土组合框架中 ,混凝土板中的纵向钢筋增加了节点的强度和刚度 ,但是 ,传统的设计方法往往忽略纵向钢筋的作用而采用简化的计算模型。因此 ,出于经济效益考虑 ,应该根据半刚性组合节点的实际受力性能建立更加准确的计算方法。这里详细介绍了考虑混凝土板纵向钢筋作用的半刚性组合节点受弯承载力的计算方法 ,计算结果表明 ,建议的公式与试验结果吻合良好 ,可供规范制定和工程应用参考。     

Effect of particle size on the surface oxidation and flotation behavior of galena particles in lime system

ABSTRACT

In this research, the effect of particle size on the surface oxidation and flotation behavior of galena in the lime system was studied. Coarse (?0.074 + 0.038 mm), intermediate (?0.038 + 0.025 mm) and fine (?0.025 mm) galena particles were used in the experiment. The dissolution tests, flotation tests, and sorption tests were accomplished. Through further analysis by XPS, the effect of particle size and lime was observed. The decrease of mineral particle sizes increased the adsorption ratio of collector and the dissolution of galena, while the hydrophilic product OH^?/Ca(OH)⁺ produced by dissolution occupied the dominant position, which led to the minerals hydrophilic.     

Studies on membrane formation mechanism by the light transmission technique. I

New parameters, light transmission rate and minimum light transmissions, are proposed. These two parameters reflect the characteristics of the membrane‐forming system and the formation process of the membranes by phase inversion. The relationship between the light transmission and the porous structure of the membrane can be explained by the geometrical optics principles. Variation of the two parameters combining Reuvers's phase separation theory provided a convenient analytical method to predict effectively membrane morphologies. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 87: 174–181, 2003     

X-Ray, Micro-Raman, Optical Absorption/Emission Studies of ErNbO4 Grown by Vapor Transport Equilibration

Vapor transport equilibration (VTE) treatments were performed on a Y-cut bulk Er (1.6 mol%)-doped congruent LiNbO₃ crystal and an X-cut pure congruent crystal, on one surface of which a 40 nm-thick film of erbium metal was coated before the VTE treatment. Scanning electron microscope, powder or single-crystal X-ray diffraction (XRD), polarized infrared absorption/emission of Er³⁺ as well as micro-Raman spectroscopy were used to study the two VTE crystals. The results are discussed in comparison with a corresponding as-grown bulk Er-doped crystal, calcined ErNbO₄ powder, and a locally Er-doped congruent LiNbO₃ crystal prepared by using the standard Er-diffusion technique. The experimental results show that the VTE treatment induces the formation of micrometer-sized ErNbO₄ precipitates with the crystallographic morphology of a flat polyhedron not only on the surfaces of both crystals but also in the bulk of the homogeneously Er-doped one. The optical absorption and emission studies show that the formation of the precipitates results in substantial spectral changes in both the 0.98 and 1.5 μm regions. The micro-Raman studies allow to resolve four additional Raman peaks around 800 cm⁻¹ in the E(TO) spectra of the two VTE crystals. These additional Raman peaks are associated with the characteristic vibrations with respect to the NbO₄³⁻ group. Characteristic XRD, optical absorption, and emission and Raman peaks for identifying the ErNbO₄ phase are proposed. Finally, the formation mechanism and light-scattering effect of the precipitates are discussed.     

Morphologies-Controlled Synthesis and Optical Properties of Bismuth Tungstate Nanocrystals by a Low-Temperature Molten Salt Method

Well-crystallized bismuth tungstate (Bi₂WO₆) powders with different morphologies were successfully synthesized via a low-temperature molten salt method. The powders were characterized by X-ray diffraction, transmission electron microscopy, and UV-Vis, respectively. It was found that the variation of morphology of the obtained Bi₂WO₆ powder mainly depends on the different reaction temperatures and the weight ratio of LiNO₃–NaNO₃ salt to precursor. In addition, the UV-Visible absorption spectra showed that the synthesized powders had strong light absorption properties not only in the ultraviolet light but also in the visible light region.     

降低循环流化床锅炉飞灰含碳量的因素分析

循环流化床锅炉的飞灰含碳量是锅炉燃烧工况好坏的直接反映 ,其对锅炉的热效率的影响是很大的 ,它还直接影响着粉煤灰的综合开发和利用 .在对云天化循环流化床锅炉的生产实验研究中 ,分析了影响循环流化床锅炉飞灰含碳量的各种因素 (床温、煤质煤粒、一次风、二次风、床压和旋风分离器效率等 ) ,通过实验研究找到了降低循环流化床锅炉飞灰含碳量的具体而又行之有效的操作方法 ,以指导实际生产 .     

GCr15轴承钢连铸过程中热物性参数的研究

借鉴前人实验数据,采用一定的数学方法,对轴承钢的热物性参数进行了研究.结果表明：GCr15轴承钢的液相线温度为1 465.7℃,固相线温度为1 328.4℃,零强度温度为1 380℃左右,零塑性温度为1 330℃左右;在固相区、液固两相区、液相区分别采用不同的公式进行处理,可使结果更加准确,还避免了奇异性.研究结果可为轴承钢连铸工艺有限元模拟提供基础.