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181.
Drug‐loaded microparticles prepared by the one‐step deposition of calcium carbonate/alginate onto cotton fabrics 下载免费PDF全文
Huan‐Ling Wu Xiao‐Xiao Hou Christopher Branford‐White Xiao‐Zhu Sun Lei Tao Syeda Um‐I‐Zahra Li‐Min Zhu 《应用聚合物科学杂志》2015,132(40)
Calcium carbonate (CaCO3)/alginate inorganic–organic hybrid particles were synthesized and deposited on to the surface of cotton fabrics with a novel one‐step procedure. The effects of the Ca2+/CO32?/alginate molar ratio on the cotton matrix were investigated. The optimization of the process resulted in a regular shaped hybrid microparticles, and scanning electron microscopy revealed that the particles were uniformly distributed on the surface of the fibers. Dynamic light scattering showed that the particles were about 2 μm in diameter. Moreover, transmission electron microscopy images demonstrated that the core–shell structure of the particles existed along with CaCO3 evenly enfolded into the alginate layer. An X‐ray diffraction pattern displayed that the alginate/CaCO3 hybrid microparticles were a mixture of calcite and vaterite crystal. Fourier transform infrared spectroscopy indicated that CaCO3/alginate hybrid particles formed in situ were the only deposited materials. The thermogravimetric analysis curve indicated a certain mass ratio of the alginate and CaCO3 in the hybrid particles. Furthermore, the drug‐loading and drug‐release properties of the hybrid microspheres were studied, and the results show that the water‐soluble diclofenac sodium could be effectively loaded in the hybrid microparticles and the drug release could be effectively sustained. Finally, both of the microparticles and modified fabrics had good cytocompatibility. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42618. 相似文献
182.
A commercial zeolite desiccant wheel is tested with atmospheric pressure superheated steam regeneration over a range of air inlet conditions, steam inlet temperatures, and wheel rotation speeds. Results are compared with those from high-temperature air regeneration experiments on the same wheel obtained from the literature. For both cases the air stream to be dried was relatively hot and moist with inlet temperature and absolute humidity values of 50°C and 25 g · kg?1 chosen to reduce heat carryover. Using steam at 160°C to regenerate the wheel leads to the same dehumidification as using hot air at approximately 90°C. The benefit of superheated steam drying is that a nearly closed-loop regeneration process can be used with potential energy savings on the order of 30%. 相似文献
183.
In Vivo Delivery and Activation of Masked Fluorogenic Hydrolase Substrates by Endogenous Hydrolases in C. elegans 下载免费PDF全文
Shataakshi Dube Hitesh Dube Nicole B. Green Erik M. Larsen Alex White R. Jeremy Johnson Jennifer R. Kowalski 《Chembiochem : a European journal of chemical biology》2017,18(18):1807-1813
Protein expression and localization are often studied in vivo by tagging molecules with green fluorescent protein (GFP), yet subtle changes in protein levels are not easily detected. To develop a sensitive in vivo method to amplify fluorescence signals and allow cell‐specific quantification of protein abundance changes, we sought to apply an enzyme‐activated cellular fluorescence system in vivo by delivering ester‐masked fluorophores to Caenorhabditis elegans neurons expressing porcine liver esterase (PLE). To aid uptake into sensory neuron membranes, we synthesized two novel fluorogenic hydrolase substrates with long hydrocarbon tails. Recombinant PLE activated these fluorophores in vitro. In vivo activation occurred in sensory neurons, along with potent activation in intestinal lysosomes quantifiable by imaging and microplate and partially attributable to gut esterase 1 (GES‐1) activity. These data demonstrate the promise of biorthogonal hydrolases and their fluorogenic substrates as in vivo neuronal imaging tools and for characterizing endogenous C. elegans hydrolase substrate specificities. 相似文献
184.
Interfacial adhesion is a major concern with respect to successful performance of thin polymer films in developing new thin-film processes. Micro-indentation was used to induce interfacial delamination of polytetrafluoroethylene (PTFE) films deposited on glass substrates using hot filament chemical vapour deposition (HFCVD). Film thickness (1, 2, 3, 5, 10 µm) and indentation load (0.5, 0.75, 1, 2, 3 N) effects on the delamination diameter were investigated. A three-dimensional finite element model using shear material failure criterion and cohesive zone model (CZM) was developed to simulate the delamination. A normalized load–delamination radius relationship was obtained to evaluate the interfacial fracture toughness. The experimental observations showed that the delamination diameter depends on film thickness and indentation load. The numerical simulation indicates the delamination diameter depends on film thickness, material properties, and indentation force. The predictions of interfacial fracture toughness for 5- and 10-µm PTFE films are much smaller than those values using Rosenfeld et al.’s equation, which excludes the energy spent during the penetration. 相似文献
185.
Pierre‐Marie Nigay Ange Nzihou Claire E. White Winston O. Soboyejo 《Journal of the American Ceramic Society》2017,100(10):4748-4759
In this paper, the structure‐property relationships of a clay ceramic with organic additives (biomass and biochar) are investigated to develop an alternative material for thermal energy storage. The firing transformations were elucidated using X‐ray pair distribution function analysis, differential scanning calorimetry, and scanning electron microscopy. It was found that the biomass increased the porosity, which resulted in a decrease of the specific heat capacity. On the other hand, the biochar remained in the clay ceramic without any interaction with the clay matrix up to 950°C. The specific heat capacity of the clay ceramic increased from 1.20 to 1.49 kJ/kg·K for a 30 wt% addition of biochar. The clay ceramic with a 30 wt% addition of biochar also conserved a high flexural strength of 11.1 MPa compared to that of the clay ceramic without organic additives (i.e., 18.9 MPa). Furthermore, the flexural strength only decreased by 23% after 100 thermal cycles. The crack growth associated with the thermal fatigue was limited by crack bridging and crack trapping. Hence, the current results suggest that clay/biochar ceramics can be as efficient as molten salts in thermal energy storage with the added benefit of an ease of use in the physical form of bricks. 相似文献
186.
Ryan M. White Jamie M. Kunkle Chris Haines Elizabeth C. Dickey 《Journal of the American Ceramic Society》2013,96(7):2050-2053
The production of a composite powder of eutectic B4C–TiB2 is demonstrated via an atmospheric plasma processing method. Feedstock material is prepared for plasma processing by mixing and spray drying monolithic B4C and TiB2 to produce a flowable precursor powder. These powders are fed through a plasma torch, where they are melted and actively quenched in flight with argon gas. Plasma processed powders are composed of crystalline B4C and TiB2, with some additional B2O3 oxide phase. The plasma processing method results in the production of monolithic B4C and TiB2 nanoparticles, but some larger particles (generally ≥10 μm in diameter) are shown to contain the traditional lamellar eutectic microstructure. The eutectic interphase spacing ranges from 100 to 650 nm, and the composite microstructure is present through the entire thickness of the eutectic particles. Future work on plasma processing of eutectic powders should focus on methods utilizing passive in‐flight quenching to increase the average particle size. 相似文献
187.
Kinetic studies of the esterification of glycerol (G) and sebacic acid (SA) at three molar ratios (0.6, 0.8, 1.0) and at three temperatures (120, 130, 140°C) to form poly(glycerol–sebacate) were performed and assessed using FT‐Raman spectroscopy. The quantitative changes in the concentrations of carboxylic acid and ester groups within the forming bioelastomer were measured and the chemical rate constants (k) determined from the kinetic scheme were first‐order, with respect to sebacic acid concentration. Increasing the reaction temperature by 20°C is noted to increase the chemical rate constant (k) by a factor of up to 4.5 and the total extent of conversion at early times for the molar ratios investigated. The activation energy (Ea) and the pre‐exponential factor (A0) for these three stoichiometric ratios were calculated, which varied in accordance with the average functionality of the system. Under isothermal conditions, the chemical rate constant remained unchanged with an increase in the extent of the reaction (α) until a spontaneous transition resulted in the shift in the mechanism from kinetics to diffusion controlled. The Young's moduli of the PGS polymers were found to depend primarily on the average functionality of the system and the curing period. This investigation confirms the reaction mechanism for PGS polymer synthesis and shows the flexibility afforded to PGS properties and reaction times through varying the stoichiometric ratios of glycerol to sebacic acid. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013 相似文献
188.
Three experimental techniques were used to characterize the cure state of an epoxy resin system of DGEBA epoxide and DDS diamine curing agent. Samples were prepared from non‐stoichiometric monomer mixtures designed so as to simulate various stages of cure of a stoichiometrically prepared epoxy. Such an approach allows for variable temperature characterization of specimens without concern for ongoing chemical reactions that would cloud interpretation of results. Additional experiments were performed on stoichiometric samples that were isothermally cured. Differential scanning calorimetry (DSC) was used to measure the heat of reaction and glass transition temperature. Dynamic mechanical analysis (DMA) was used to measure complex modulus, while ultrasonic cure monitoring (UCM) was used to measure longitudinal velocity throughout cure. DSC analysis was found to be insensitive to changes occurring at the latter stage of polymer network development, especially after vitrification. DMA characterization, however, was found to be quite sensitive to the rubbery modulus (and as such, the cure state), but is limited to cure states above gelation. Only the UCM technique was robust enough to accommodate all cure states while providing highly sensitive measurements of mechanical property development. 相似文献
189.
The processability of single bubble polyamide 11 and polyamide 12 films was investigated. The development of crystalline structure and chain orientation of polyamide 11 and polyamide 12 films in single bubble film blowing was studied by differential scanning calorimetry (DSC), wide angle X‐ray diffraction (WAXS), infrared (IR) spectroscopy, and birefringence. DSC measurements of both films revealed a spontaneous increase in glass transition temperature (Tg) and cold crystallization temperature (Tc) during aging at room conditions, with crystallinity and melting point remaining constant. Single bubble polyamide 11 and polyamide 12 films exhibited triclinic α and monoclinic γ crystals, respectively. The level of biaxial orientation was evaluated by calculating White‐Spruiell biaxial orientation factors with pole figure data. We were not able to produce biaxially oriented double bubble films with either polyamide 11 or polyamide 12. 相似文献
190.
Anna H. Wolna Aaron M. Fleming Na An Lidong He Henry S. White Cynthia J. Burrows 《Israel journal of chemistry》2013,53(6-7):417-430
Nanopore technology holds high potential for next-generation DNA sequencing. This method operates by drawing an individual single-stranded DNA molecule through a nanoscale pore, while monitoring the current deflections that occur as the DNA passes through. Individual current levels for the four DNA nucleotides have been established by immobilization of an end biotinylated strand in the pore, in which the nucleotide of interest is suspended at the most sensitive region of the ion channel. Due to the inherent reactivity of DNA bases, many modified nucleotides in the genome exist as a result of oxidative and UV insults, among others. Herein, the current levels for common DNA damage lesions 8-oxo-7,8-dihydroguanine, spiroiminodihydantoin, guanidinohydantoin, uridine, abasic sites, thymine dimers, thymine glycol, and 5-iodocytosine were assessed through immobilization experiments. In some cases, the current difference between the damaged and canonical nucleotides was not well resolved; therefore, we took advantage of the chemical reactivity of the new functional groups present to make amine adducts that shifted the current levels outside the range of the native nucleotides. Among the adducts studied, only the 2-aminomethyl-18-crown-6 adduct was able to give a large current shift in the immobilization experiment, as well as being observed in a translocation experiment. The results show potential in providing current-level modulators for identification of some types of DNA damage. In principle, any DNA base modification that can be converted chemically or enzymatically into an abasic site could be identified in this way. 相似文献