Experimental Study on Phosphorus Partitions Between Liquid Iron and Liquid Slags Based on DRI

Metallurgical and Materials Transactions B - Phosphorus partition between liquid iron and CaO-SiO2-MgO-FeOx slags have been investigated experimentally. Fe doped with Fe3P was equilibrated, at 1873...     

Phytochrome‐Based Extracellular Matrix with Reversibly Tunable Mechanical Properties

Interrogation and control of cellular fate and function using optogenetics is providing revolutionary insights into biology. Optogenetic control of cells is achieved by coupling genetically encoded photoreceptors to cellular effectors and enables unprecedented spatiotemporal control of signaling processes. Here, a fast and reversibly switchable photoreceptor is used to tune the mechanical properties of polymer materials in a fully reversible, wavelength‐specific, and dose‐ and space‐controlled manner. By integrating engineered cyanobacterial phytochrome 1 into a poly(ethylene glycol) matrix, hydrogel materials responsive to light in the cell‐compatible red/far‐red spectrum are synthesized. These materials are applied to study in human mesenchymal stem cells how different mechanosignaling pathways respond to changing mechanical environments and to control the migration of primary immune cells in 3D. This optogenetics‐inspired matrix allows fundamental questions of how cells react to dynamic mechanical environments to be addressed. Further, remote control of such matrices can create new opportunities for tissue engineering or provide a basis for optically stimulated drug depots.     

Chemistry of Leichhardt's Grasshopper, Petasida ephippigera, and its Host Plants, Pityrodia jamesii, P. ternifolia, and P. pungens

Investigation of the strikingly aposematic Leichhardt's grasshopper revealed a number of host-plant-derived components. Chemical study of the three known host plants revealed a diverse array of components. Pityrodia ternifolia and P. pungens contain predominantly sesquiterpenes and sesquiterpene glycosides and P. jamesii is rich in cineole, dihydrochalcones, chalcones, and monoterpene glycosides. Feces from grasshoppers feeding on P. jamesii contain a mixture of hydroxycineoles, of which 3-hydroxycineole is the predominant isomer (68%). No evidence for previously suspected "alkaloidal" toxins was found in either the insect or host plant.     

Synthesis and characterisation of poly(distyrylbenzene-block-hexa(ethylene oxide)) and its fluorinated analogue—two new block copolymers and their application in electroluminescent devices

Two new soluble block copolymers are reported in which chromophores and hexa(ethylene oxide) units alternate along the polymer backbone. In polymer 1 the chromophore was the distyrylbenzene unit. The polymer was synthesised via the Wittig reaction and the ionisation potential of 5.4±0.2 eV was measured by cyclic voltammetry and photoelectron spectroscopy. Polymer 1 showed a high solid-state photoluminescence efficiency (34%) and was used to make efficient (0.5 cd/A) light emitting diodes (LEDs). Polymer 1 was also used in light emitting cells; these showed luminescence in reverse bias and a reduced turn-on voltage compared to the LEDs. Polymer 2, in which the chromophore was dodecafluoro-distryrylbenzene, was prepared via the Horner-Wittig reaction and showed an ionisation potential of 6.25±0.15 eV and a solid-state photoluminescence efficiency of 17%. It was used as electron-conducting layer in a LED but failed to give significant electroluminescence. The optical energy gap for both polymers was 3.0 eV.     

SkaSim – Skalierbare HPC‐Software für molekulare Simulationen in der chemischen Industrie

This article outlines advances in molecular modeling and simulation using massively parallel high‐performance computers (HPC). In the SkaSim project, partners from the HPC community collaborated with users from science and industry. The aim was to optimize the prediction of thermodynamic property data in terms of efficiency, quality and reliability using HPC methods. In this context, various topics were dealt with: atomistic simulation of homogeneous gas bubble formation, surface tension of classical fluids and ionic liquids, multicriteria optimization of molecular models, the development of the molecular simulation codes ls1 mardyn and ms2, atomistic simulation of gas separation processes, molecular membrane structure generators, transport resistors and the evaluation of predictive property data models based on specific mixture types.     

绿色种植屋面在德国

介绍了德国推广种植屋面制定的法规条例，同时介绍了德国的种植屋面系统构造、各层作用及FLL的根阻试验，推介了威达公司的两种根阻防水材料和公司施作的工程实例。     

On Taylor series expansions for waiting times in tandem queues: an algorithm for calculating the coefficients and an investigation of the approximation error

Recently, a Taylor series expansion was developed for expected stationary waiting times in open (max,+)-linear stochastic systems with Poisson input process; these systems cover various instances of queueing networks.As an application, we present an algorithm for calculating the coefficients for infinite capacity tandem queueing networks with discrete service-time distributions. The algorithm works quite efficiently if the random vector of the service times of all servers is concentrated at a small number of atoms. We investigate the relative error of the Taylor approximation by simulation; in many cases, it follows very well a simple expression which holds exactly for independent, exponentially distributed servers.     

CFD in der chemischen Verfahrenstechnik aus industrieller Sicht

Computational fluid dynamics (CFD) is increasingly becoming established as a tool for analysis and design in the chemical industry. Several projects from various areas are introduced as examples of CFD projects from the perspective of the CFD user in chemical industry. The areas chosen are based on those in a process chain: transportation, mixing, reaction, and separation of materials. The most important steps and decisions in the use of CFD are presented from the perspective of the process engineer. This paper attempts to convey an appreciation for the possibilities and opportunities, but also for the limits of computational fluid dynamics.