Influence of maize kernel hardness on flour hydration and cooking properties

Knowledge of the association between cooking properties and endosperm hardness may help nutritionist and processors to select raw materials for preparing maize based food products, particularly those eaten as cooked dispersions. Seven commercial maize cultivars differing in hardness were selected to evaluate endosperm hardness on the kernels and some characteristics such as composition and hydration and cooking properties on the grits obtained from those maizes. Results show that the differences in endosperm hardness (directly related to grits protein content) can explain the differences in swelling and amylographic consistencies values. Cultivars with the hardest endosperm show the lowest values at high temperature. They also show the lowest amylographic consistencies. On the other hand softer endosperms present the highest swelling power and the highest amylographic consistencies. These differences are attributed to the restriction for starch swelling caused by the protein matrix. Endosperm hardness measurements and swelling power at 95 degrees C, can be useful to select cultivars that are going to be used to prepare maize based foods like atoles, polenta, etc.     

Thermal polymerization of methyl linolenate,alpha- and beta-eleostearates

Summary The rates of polymerization of alpha and beta eleostearates agree with second order kinetics, as would be expected for a bimolecular Diels-Alder addition. The all-trans, beta isomer reacts faster than thecis, trans, trans alpha isomer, in agreement with knowncis, trans effects on diene activity. The polymerization of normal linoleate follows an apparent first order reaction. It is suggested that conjugation is the slow rate determining monomolecular reaction, as has been proposed for the non-conjugated linoleate isomers. Paper No. 177, Journal Series, Research Laboratories, General Mills Inc. Presented at the 28th fall (Paul Bunyan) meeting of the American Oil Chemists’' Society, Oct. 12, 1954, Minneapolis, Minn.     

Effect of drop coalescence on mass transfer rate

Disperse-phase-controlled mass transfer rates from individual liquid drops suspended in a second liquid phase are measured optically immediately after the drop has been formed by coalescence of two smaller droplets. The net effect on mass transfer of the act of coalescence is determined by comparison to similar measurements made on the initial droplets in the absence of coalescence. The transfer rates immediately after coalescence are high rapidly fall to zero, rebound to an intermediate value and finally decay to the level expected for an undisturbed drop. The net effect on total mass transferred is detrimental in a clean system subject to interfacial instability but appears to be beneficial for contaminated systems or where no surface movements are spontaneously generated.     

Heat transfer efficiency in a fliuidized bed

The equilibrium stage concept used in staged contacting operations was adopted as a measure of heat transfer efficiency for a fluidized bed. A simple model was developed which postulates that solids flow through the bed can be by perfect mixing, plug flow and short-circuiting. Efficiencies were determined experimentally in a 150 mm diameter fluidized bed with air as the fluidizing medium and sand as the solid. Heat transfer efficiencies greater than 100% were obtained indicating that small diameter, low aspect ratio fluidized beds do not behave as perfect mixers. The results indicate that heat transfer measurements can be used to develop information on solids flow behavior.     

Electrical conductivity of concrete containing silica fume

The influence of silica fume on concrete properties represents an important technical research. In general, silica fume tends to improve both mechanical characteristics and durability of concrete. Thus the electrical properties of concrete containing silica fume can be studied to clarify its physical performance during hydration. The electrical conductivity of neat cement, mortar and concrete pastes was measured during setting and hardening. The ordinary Portland cement was partially replaced by different amounts of silica fume by weight. The changes in the electrical conductivity were reported during setting and hardening after gauging with water. The results of this study showed that the electrical conductivity can be used as an indication for the setting characteristics as well as the structural changes of the hardened pastes made with and without silica fume.     

Materials balance in a tung oil mill

Summary Weights were determined and analyses made of tung fruit milled and of all products leaving the mill for two runs of about 90 tons each in a commercial mill under normal operating conditions. Dry matter, oil, and nitrogen in the fruit were satisfactorily accounted for in products leaving the mill, 101% of the oil being accounted for in each run. This showed that the methods of analysis and sampling were accurate. Losses occurred principally in particles of kernels occluded with the hulls and in the screw-press cake. Seventy-eight and 82% of the oil in the fruit was recovered as filtered oil. Repressing the filter-press cake by adding it back to the stream of ground nuts just before they entered the screw-presses was not proven to be economical as at the end of the run just as much cake was on hand, and it had as high an oil content as if no filter cake had been fed back through the screw presses. Only about half as much oil could be filtered per filtration cycle, resulting in an increase in cost of labor and a decrease in filtering capacity. The apparent oil content of the screw-press cake decreases by about 2% after four to eight days as compared to its apparent oil content at the time of pressing because of polymerization. Thus, screw-press cake samples should be analyzed for oil as soon as possible after extrusion. Both of these laboratories are maintained by the Agricultural Research Service of the U. S. Department of Agriculture.     

Viscosity index. I. Evaluation of selected copolymers incorporating n-octadecyl acrylate as viscosity index improvers

Compositionally and structurally varied copolymers all containing n-octadecyl acrylate were prepared and evaluated as viscosity index improvers in a common base oil under conditions of low shear. Systems evaluated over a range of copolymer and blend composition were: copolymers of n-octadecyl acrylate with, respectively, methyl methacrylate, 2-ethylhexyl acrylate, and n-dodecyl acrylate; and homopolymers of poly(n-octadecyl acrylate), prepared with a wide range of molecular weights. Properties were compared with those of blends of commercial methacrylate copolymers (acryloids) which had been freed of their entraining liquid. Mixtures of base oil with copolymers of n-octadecyl acrylate and methyl methacrylate, compared at fixed SAE viscosities, were the most efficient of all blends studied. They had the smallest rate of change of viscosity with temperature (as measured by their ASTM slopes), particularly in the composition region of incipient polymer precipitation at room temperature. Efficiency of certain of these composition was somewhat greater than that of the acryloids. A parameter that related concentration and weight-average molecular weight was used to correlate all of the data for ASTM slope and viscosity. Empirical relations developed by using this parameter enabled rheological data to be estimated that agree within 6% of experimental values for the case of thermodynamically good base oil solvents. These data demonstrated the relatively small contributions of copolymer structure to viscosity index improvement.     

Investigation of fibres based on rigid-chain polyamides by the wide-line nmr and ultrasonic acoustics

Conclusions -- A dependence of the second moment of the NMR line on the angle between the fibre axis and the magnetic field has been given; the structural coefficient C ₀, C ₂, and C ₄ have been calculated for fibres based on poly-p-phenyleneterephthalamide and poly-p-benzamide at temperatures of –196 and +20°C and for Kevlar-49, from –196 to +400°C.-- The intramolecular structural coefficients C ₀ ^im, C ₂ ^im, and C ₄ ^im have been calculated theoretically, and the orientation parameters and and the acoustic orientation factor f have been obtained, values for which indicate a high degree of orientation of the macromolecules in fibres.-- The smaller values of the second moment of the NMR line for PABI as compared with fibres based on PPTA in the temperature region 250–380°C indicate a more mobile structure for the PABI.-- In the range from –196 to +20°C thermal action leads to a more important change in the coefficient C ₀ for Kevlar-29 and Kevlar-49 as compared with PABI; this is apparently connected with thermal expansion in planes having a predominant concentration of van der Waals bonds for Kevlar-29 and Kevlar-49.Translated from Khimicheskie Volokna, No. 4, pp. 23–26, July–August, 1990.