Photo fermentative hydrogen production using dominant components (acetate, lactate, and butyrate) in dark fermentation effluents

Engineering strategies were applied to promote the phototrophic H₂ production of an indigenous purple nonsulfur bacterium Rhodopseudomonas palustris WP3-5 using major components (i.e., acetate, butyrate, and lactate) of dark fermentation effluents as carbon sources. First, performance of cell growth and photo-H₂ production on each carbon source was examined individually. It appeared that acetate was the most effective carbon source for photo-H₂ production, giving an overall H₂ production rate and H₂ yield of 12.68 ml/h/l and 67.1%, respectively. Next, the effect of substrate concentration of each carbon source on photo-hydrogen production was investigated. Kinetic models were developed to describe the correlation between maximum specific growth rate/specific H₂ production rate and the substrate concentration. The results show that using acetate and lactate as the carbon source, the kinetics for the cell growth and photo-hydrogen production can be described by Monod-type and Michaelis–Menten models, respectively, whereas substrate inhibition occurred when using butyrate as the carbon source. The continuous cultures were also conducted at a hydraulic retention time of 96 h using synthetic dark fermentation soluble metabolites (with a 5 and 10 fold dilution) as the influent. The phototrophic H₂ production efficiency was stably maintained for over 30 days with an overall H₂ yield 10.30 and 11.97 mol H₂/mol sucrose, when using 5-fold and 10-fold diluted dark fermentation effluent, respectively, as the substrate for dark fermentation. This demonstrates the feasibility of using the sequential dark and photo fermentation for high-yield biohydrogen production.     

Integration of a-Si:H solar cell with novel twist nematic liquid crystal cell for adjustable brightness and enhanced power characteristics

This study improves the output power and brightness characteristics of a translucent hydrogenated amorphous silicon (a-Si:H) solar cell by integrating the solar cell with a novel twist nematic (TN) liquid crystal (LC) cell incorporating a sub-wavelength metal grating polarization beam splitter (PBS). Although conventional TN-LC cells are widely used to adjust the brightness in many display applications, the sheet polarizers used in such cells decay when exposed to ultraviolet (UV) rays and have a low light efficiency. Accordingly, in this study, a sub-wavelength metal grating PBS is used to replace not only the sheet polarizers in the conventional TN-LC cell but also the upper and lower alignment layers and transparent electrodes. Therefore, a translucent a-Si:H solar cell integrating with the novel TN-LC cell with the sub-wavelength metal grating PBS could improve power efficiency and durability in UV ray environment. The experimental results show that the transmittance gap between the “on” and “off” states of the enhanced translucent a-Si:H solar cell/novel TN-LC cell is of the order of 26.6% (i.e. 4.3-30.9%) for incident light with a wavelength of 800 nm, 6.3% (i.e. 10.8-17.1%) for an incident wavelength of 400 nm and 2.7% (i.e. 0-2.7%) for an incident wavelength of 510 nm. Moreover, it is shown that the novel TN-LC cell increases the maximum electrical power developed by the translucent a-Si:H solar cell and improves its power conversion efficiency by 0.209% in the “off” state and 0.417% in the “on” state. As a result, the proposed device represents an ideal solution for building-integrated photovoltaic (BIPV) systems, automobile industry applications and many other adjustable brightness photovoltaic applications.     

Effects of solvent and alkaline earth metals on the heat-induced precipitation process of sodium caseinate

The precipitation temperatures of sodium caseinate in H₂O and D₂O in the presence of Mg²⁺, Ca²⁺, Sr²⁺ and Ba²⁺ were investigated through fluorescence, turbidity and conductivity experiments.     

The nanostructure and dewetting of block copolymer thin films annealed in different neutral solvents

The morphology of polystyrene‐b‐poly(2‐vinyl pyridine) thin films annealed under various neutral solvents was investigated. The morphological transition depends on the vapor pressure of the solvent, the quantity of the solvent in the film, and annealing time. We introduced the volume fraction of solvent in a film (Q) to correlate these factors to the morphology. At low Q, the amount of solvent that penetrates into the film is limited and it cannot induce enough chain mobility. Thus, thin film shows short stripes or a worm‐like structure. At high Q, the great diffusion of solvent into the film facilitates polymer mobility, leading to an ordered structure. Our results also suggested that the dewetting mechanism of thin film depends on Q. At low Q, dewetting develops via the nucleation and growth. At high Q, the condensation of solvent on the surface removes some polymer and dewetting is dominated by spinodal mechanism. POLYM. ENG. SCI., 2011. © 2011 Society of Plastics Engineers     

Nonlinear gain coefficients in semiconductor quantum-well lasers:effects of carrier diffusion, capture, and escape

Effective nonlinear gain coefficients due to the effects of carrier diffusion, capture, and escape are derived from the carrier transport equations. The quantum capture and escape processes between the confined states and the unconfined states are calculated from first principles by evaluating the carrier-polar longitudinal optical phonon interactions. The dc and ac capture times and escape times are derived from evaluating the net capture current of carriers. The differences in capture and escape times between dc and ac operating conditions are numerically investigated. We find that both dc and ac escape times are strongly dependent on the quantum well structure. This differs from the dc and ac capture times that are not sensitive to the quantum well structure. We also find that the dc escape time predicted by the classical thermionic emission theory will no longer be valid for narrow or shallow quantum wells. We show that both dc and ac capture and escape time ratios will increase as the carrier temperature and the carrier density in the quantum well increase. Therefore, we suggest that the possible cause of the resonant frequency degradation and dramatic increase in the damping rate results from the increase of the ac capture to escape time ratio by the effects of carrier heating. Two theoretical models (2N and 3N models) were used to study the effects of carrier diffusion-capture-escape on the modulation response of quantum-well lasers and a distributed model of carrier transport in quantum-well lasers is proposed. Their implications in designing high-speed quantum-well lasers are discussed     

Seasonal variations of susceptibility to oxidative stress in Adamussium colbecki,a key bioindicator species for the Antarctic marine environment

The area of free radical biology is of increasing interest for marine organisms since the enhanced formation of reactive oxygen species (ROS) is a common pathway of toxicity induced by stressful environmental conditions. In polar environments responses of the antioxidant system could be useful as an early detection biomarkers of unforeseen effects of human activities which are progressively increasing in these remote areas. However, the characterization of antioxidant defences in appropriate sentinel species is of particular value also in terms of a possible adaptation to this extreme environment. The scallop, Adamussium colbecki, is a key species for monitoring the Antarctic environment and, besides single antioxidants, the total oxyradical scavenging capacity (TOSC) assay has been recently used for quantifying the overall ability of this organism to neutralize peroxyl radicals (ROO*), hydroxyl radicals (*OH) and peroxynitrite (HOONO). The aim of this work was to obtain a better characterization of these biological responses which can indicate the occurrence of biological disturbance; in this study the total oxyradical scavenging capacity was further analyzed to assess the presence of seasonal fluctuations in the susceptibility to oxidative stress in this species. The capability to neutralize peroxyl radicals and hydroxyl radicals increased at the end of December, while resistance towards peroxynitrite did not show any significant variations during the Antarctic summer. These results suggest the occurrence of metabolic changes which mainly influence intracellular formation of ROO* and *OH, with more limited effects on HOONO. Despite the limited time window analyzed, as a typical constraint in Antarctic research at Terra Nova Bay, an increased resistance to these specific oxyradicals might be related to the period of highest feeding activity, or to other intrinsic factors in the animals' physiology such as the phase of reproductive cycle.     

A multiple circular path convolution neural network system for detection of mammographic masses

A multiple circular path convolution neural network (MCPCNN) architecture specifically designed for the analysis of tumor and tumor-like structures has been constructed. We first divided each suspected tumor area into sectors and computed the defined mass features for each sector independently. These sector features were used on the input layer and were coordinated by convolution kernels of different sizes that propagated signals to the second layer in the neural network system. The convolution kernels were trained, as required, by presenting the training cases to the neural network. In this study, randomly selected mammograms were processed by a dual morphological enhancement technique. Radiodense areas were isolated and were delineated using a region growing algorithm. The boundary of each region of interest was then divided into 36 sectors using 36 equi-angular dividers radiated from the center of the region. A total of 144 Breast Imaging-Reporting and Data System-based features (i.e., four features per sector for 36 sectors) were computed as input values for the evaluation of this newly invented neural network system. The overall performance was 0.78-0.80 for the areas (Az) under the receiver operating characteristic curves using the conventional feed-forward neural network in the detection of mammographic masses. The performance was markedly improved with Az values ranging from 0.84 to 0.89 using the MCPCNN. This paper does not intend to claim the best mass detection system. Instead it reports a potentially better neural network structure for analyzing a set of the mass features defined by an investigator.     

Simulation of the effects of space charge and Schottky barriers on ferroelectric thin film capacitor using Landau Khalatnikov theory

The role of space charge induced in a ferroelectric thin film and the presence of Schottky barriers at the two electrode/film interfaces are studied by numerical simulation using Landau-Khalatnikov theory. In this work, the whole film is considered as the stacking of dipolar layers, each of which contains multilayers of perovskite cells. In the presence of a local electric field, the double-well thermodynamic potential of each layer is modified in an asymmetric manner. The local electric field distribution is determined both by the space charge and the boundary conditions imposed by the Schottky barrier heights. Asymmetric and skewed hysteresis loops are generated     

Building blocks for a two-frequency laser lidar-radar: a preliminary study

A new principle of lidar-radar is theoretically and experimentally investigated. The proposed architecture is based on the use of an rf modulation of the emitted light beam and a direct detection of the backscattered intensity. Use of a radar-processing chain allows one to obtain range and Doppler measurements with the advantages of lidar spatial resolution. We calculate the maximum range of this device, taking into account different possible improvements. In particular, we show that use of a pulsed two-frequency laser and a spatially multimode optical preamplification of the backscattered light leads to calculated ranges larger than 20 km, including the possibility of both range and Doppler measurements. The building blocks of this lidar-radar are tested experimentally: The radar processing of an rf-modulated backscattered cw laser beam is demonstrated at 532 nm, illustrating the Doppler and identification capabilities of the system. In addition, signal-to-noise ratio improvement by optical pre-amplification is demonstrated at 1.06 microm. Finally, a two-frequency passively Q-switched Nd:YAG laser is developed. This laser then permits two-frequency pulses with tunable pulse duration (from 18 to 240 ns) and beat frequency (from 0 to 2.65 GHz) to be obtained.     

Human Motion Planning Based on Recursive Dynamics and Optimal Control Techniques

This paper presents an efficient optimal control and recursive dynamics-based computer animation system for simulating and controlling themotion of articulated figures. A quasi-Newton nonlinear programmingtechnique (super-linear convergence) is implemented to solve minimumtorque-based human motion-planning problems. The explicit analyticalgradients needed in the dynamics are derived using a matrix exponentialformulation and Lie algebra. Cubic spline functions are used to make thesearch space for an optimal solution finite. Based on our formulations,our method is well conditioned and robust, in addition to beingcomputationally efficient. To better illustrate the efficiency of ourmethod, we present results of natural looking and physically correcthuman motions for a variety of human motion tasks involving open andclosed loop kinematic chains.