Nondestructive and noncontact method for determining the spring constant of rectangular cantilevers

We present here an experimental setup and suggest an extension to the long existing added-mass method for the calibration of the spring constant of atomic force microscope cantilevers. Instead of measuring the resonance frequency shift that results from attaching particles of known masses to the end of cantilevers, we load them with water microdrops generated by a commercial inkjet dispenser. Such a device is capable of generating drops, and thus masses, of extremely reproducible size. This makes it an ideal tool for calibration tasks. Moreover, the major advantage of water microdrops is that they allow for a nearly contactless calibration: no mechanical micromanipulation of particles on cantilevers is required, neither for their deposition nor for removal. After some seconds the water drop is completely evaporated, and no residues are left on the cantilever surface or tip. We present two variants: we vary the size of the drops and deposit them at the free end of the cantilever, or we keep the size of the drops constant and vary their position along the cantilever. For the second variant, we implemented also numerical simulations. Spring constants measured by this method are comparable to results obtained by the thermal noise method, as we demonstrate for six different cantilevers.     

Electron energy loss spectroscopy for analysis of inhaled ultrafine particles in rat lungs

Epidemiologic studies have associated cardiovascular morbidity and mortality with ambient particulate air pollution. Particles smaller than 100 nm in diameter (ultrafine particles) are present in the urban atmosphere in very high numbers yet at very low mass concentration. Organs beyond the lungs are considered as targets for inhaled ultrafine particles, whereby the route of particle translocation deeper into the lungs is unclear. Five rats were exposed to aerosols of ultrafine titanium dioxide particles of a count median diameter of 22 nm (geometric standard deviation, GSD 1.7) for 1 hour. The lungs were fixed by intravascular perfusion of fixatives immediately thereafter. TiO(2) particles in probes of the aerosol as well as in systematic tissue samples were analyzed with a LEO 912 transmission electron microscope equipped with an energy filter for elemental microanalysis. The characteristic energy loss spectra were obtained by fast spectrum acquisition. Aerosol particles as well as those in the lung tissue were unambiguously identified by electron energy loss spectroscopy. Particles were mainly found as small clusters with a rounded shape. Seven percent of the particles in the lung tissue had a needle-like shape. The size distribution of the cluster profiles in the tissue had a count median diameter of 29 nm (GSD 1.7), which indicates no severe clustering or reshaping of the originally inhaled particles. Electron energy loss spectroscopy and related analytical methods were found to be suitable to identify and localize ultrafine titanium dioxide particles within chemically fixed and resin-embedded lung tissue.     

Non-uniformity issues and workarounds in bounded-size sampling

A variety of schemes have been proposed in the literature to speed up query processing and analytics by incrementally maintaining a bounded-size uniform sample from a dataset in the presence of a sequence of insertion, deletion, and update transactions. These algorithms vary according to whether the dataset is an ordinary set or a multiset and whether the transaction sequence consists only of insertions or can include deletions and updates. We report on subtle non-uniformity issues that we found in a number of these prior bounded-size sampling schemes, including some of our own. We provide workarounds that can avoid the non-uniformity problem; these workarounds are easy to implement and incur negligible additional cost. We also consider the impact of non-uniformity in practice and describe simple statistical tests that can help detect non-uniformity in new algorithms.     

Mikrostrukturielle Charakterisierung von ultra-hochfesten Schweißgütern

Welded steel structures are a crucial part of lightweight constructions in several industrial segments. The filler metal plays a vital role in optimizing the properties of welded joints. In this study different methods were used to characterize the microstructure of ultra-high strength all-weld metal samples with different chemical compositions. It was evaluated which method can be used to link the grain size of a sample to its toughness.     

Enhancement of limited water supply network data for deterioration modelling and determination of rehabilitation rate

In the past decades, the main focus of water supply management has moved from construction of new water supply networks to rehabilitation and adaptation of the existing infrastructure. The decision-making process for the rehabilitation management relies heavily on the quality of the applied deterioration model. A recurring problem in the application of such models relates to the quality and availability of network data. These data are often incomplete or unreliable because building measures and damages are only documented properly recently and the recovery of older data is difficult and expensive. A key point in rehabilitation planning is therefore data collection and data reconstruction. Consequently, the aim of this paper is to present a methodology for the enhancement of the available data of water supply networks and the prognosis of the necessary rehabilitation rates under limited data availability. Results indicate that the presented data reconstruction technique has advantages as compared to traditional data extrapolation. It also allows the reconstruction of fragmentary data about existing water supply and wastewater collection systems for the operating utilities. However, it cannot be used for reconstructing failure types as well as the whole information on pipes (e.g. more than two missing information).     

Damage phenomena in lubricated rolling-sliding wear of a gas carburised 0.85%Mo low-alloyed sintered steel: theoretical analysis and experimental verification

The resistance to surface and subsurface damage during lubricated rolling-sliding wear of a carburised low-alloy sintered steel and the effect of shot peening were investigated. The formation of both contact fatigue cracks and of brittle tensile cracks may be predicted by a theoretical model that was experimentally validated. Carburising is effective in increasing the resistance to contact fatigue, but pores in a hard and brittle matrix may act as pre-existing cracks. Shot peening increases the contact fatigue resistance since compressive residual stresses oppose the nucleation of surface cracks.     

The Drop Weight Test Revisited: Characterization of the Crushability of Hot Sinter and Validation of the Approach with Natural Rocks

The crushing behaviour of sinter from blast furnace operations is known to depend on its temperature. In order to characterize it, hot sinter was subject to single particle tests in a very basic drop weight tester. Additionally, a laboratory jaw crusher was sacrificed to work the same feed material. As the results regarding net energy input were not consistent, two common rocks were tested in comparison with both the drop weight and the jaw crusher. Although some discrepancies remained, the results with the rocks can basically be considered as consistent. This investigation illustrates some of the difficulties that can arise when established test methods are applied on material with deviant properties.     

Increase in Generation of Poly-Crystalline Silicon by Atmospheric Pressure Plasma-Assisted Excimer Laser Annealing

In this work, a novel atmospheric pressure plasma-assisted excimer laser annealing method for increasing the generation efficiency of poly-crystalline silicon from amorphous silicon layers is presented. Here, both the plasma and the laser propagate coaxially in order to generate energetic synergies. The influence of different process gases and plasma discharge modes as well as the working distance were investigated. Depending on the particularly applied plasma, the crystalline area was increased by a factor of approx. 1.1 to 1.9, where the highest efficiency was observed when introducing an argon plasma beam to the annealing process.     

Fouling Detection in an Optically Accessible Microstructured Heat Exchanger

The application of highly effective microstructured devices in continuous production and industrial environments is frequently prone to fouling. A new method is presented to characterize fouling in these microstructures. Thermal fouling of aqueous solutions containing whey protein were used as a test system. Different fouling effects could be observed and distinguished. Integral fouling indicators, such as thermal fouling resistance and pressure drop, as conventional criteria for the occurrence of fouling were compared with direct local optical observation. Low thermal fouling resistances could be detected.     

Prozesskette zum stofflichen Recycling von Kunststoffabfällen

The material recycling rate for post-consumer plastic in Austria currently ranges around 25?%, because only post-consumer plastic fractions which are disposed as clean mono-materials are available for material recycling. A significant enhancement of the material recycling rate can be achieved with a process chain consisting of wet mechanical processing and thermochemical conversion. The wet mechanical process step enriches polyolefin and polystyrene from different waste sources, which are used as feedstock for a solvent-based, thermal depolymerisation. Via thermal cracking petrochemical intermediates (i.e. short- and long-chained, aromatic and paraffinic hydrocarbons) are produced, which can be appropriately fed into a conventional crude oil refinery and processed to marketable products. In this way, the material cycle can be closed economically feasible. Both the wet mechanical processing and the thermochemical conversion have been proofed in laboratory scale and are currently transferred to pilot scale.