Magic Angle Spinning NMR of Macromolecular and Supramolecular Systems

Sideband patterns in single quantum and double quantum magic angle spinning NMR spectra are reviewed. Their use in elucidating non-covalent interactions, such as hydrogen bonds or pi-pi stacking, is demonstrated by studies of supramolecular systems of current interest. Moreover, the effects of local and collective motions are illustrated by examples from supramolecular and macromolecular science.     

Yield estimation and forecasting for winter wheat in Hungary using time series of MODIS data

Wheat is one of the most important crops in Hungary, which represents approximately 20% of the entire agricultural area of the country, and about 40% of cereals. A robust yield method has been improved for estimating and forecasting wheat yield in Hungary in the period of 2003–2015 using normalized difference vegetation index (NDVI) derived from the data of the Moderate Resolution Imaging Spectroradiometer. Estimation was made at the end of June – it is generally the beginning of harvest of winter wheat in Hungary – while the forecasts were performed 1–7 weeks earlier. General yield unified robust reference index (GYURRI) vegetation index was calculated each year using different curve-fitting methods to the NDVI time series. The correlation between GYURRI and country level yield data gave correlation coefficient (r) of 0.985 for the examined 13 years in the case of estimation. Simulating a quasi-operative yield estimation process, 10 years’ (2006–2015) yield data was estimated. The differences between the estimated and actual yield data provided by the Hungarian Central Statistical Office were less than 5%, the average difference was 2.5%. In the case of forecasting, these average differences calculated approximately 2 and 4 weeks before the beginning of harvest season were 4.5% and 6.8%, respectively. We also tested the yield estimation procedure for smaller areas, for the 19 counties (Nomenclature of Territorial Units for Statistics-3 level) of Hungary. We found that, the relationship between GYURRI and the county level yield data had r of 0.894 for the years 2003–2014, and by simulating the quasi-operative forecast for 2015, the resulting 19 county average yield values differed from the actual yield as much as 8.7% in average.     

The effect of ultra-thin graphite on the morphology and physical properties of thermoplastic polyurethane elastomer composites

Composites of thermoplastic polyurethane (TPU) and ultra-thin graphite (UTG) with concentrations ranging from 0.5 wt.% to 3 wt.% were prepared using a solution compounding strategy. Substantial reinforcing effects with increased loadings are achieved. Compared to neat TPU, values for storage modulus and shear viscosity are enhanced by 300% and 150%, respectively, for UTG concentrations of 3 wt.%. Additionally, an enhancement of thermal properties is accomplished. The crystallization temperature and thermal stability increased by 30 °C and 10 °C, respectively, compared to neat TPU. Furthermore, the use of oxidized UTG (UTGO) with its added functional oxygen groups suggests the presence of chemical interactions between UTG and TPU, which additionally impact on the thermal properties of the corresponding composites. Controlling the oxidation degree, thus offers further possibilities to obtain composites with tailored properties. The presented approach is straightforward, leads to homogeneous TPU-UTG composites with improved materials properties and is especially suitable for commercial UTG materials and further up-scaled production.     

Micro- and nanostructured Al2O3 surfaces for controlled vascular endothelial and smooth muscle cell adhesion and proliferation

The effect of the micro- and nanotopography on vascular cell-surface interaction is investigated using nano- and microstructured Al₂O₃ as model substrate. Two different nanostructured Al₂O₃ surfaces composed of low density (LD) and high density (HD) nanowires (NWs) were synthesized by chemical vapour deposition (CVD) and commercially available microstructured Al₂O₃ plates were used for comparison. A clear diverging response of human umbilical vein endothelial cells (HUVEC) and human umbilical vein smooth muscle cells (HUVSMC) was observed on these nano- and microstructured surfaces. LD Al₂O₃ NWs seem to enhance the proliferation of HUVECs selectively. This selective control of the cell-surface interaction by topography may represent a key issue for the future stent material design.     

Experimental parameters during optical floating zone crystal growth of rare earth silicides

Optical floating zone（FZ） crystal growth involving growth stability and as-grown crystal perfection is affected by experimental conditions and the specific material. Referring to rare earth silicides, high purity of raw rare earth elements and ambient argon atmosphere are crucial to grow high-quality crystals; the maximum zone height is determined by equating the capillary forces of the surface tension; and asymmetric counter rotation of crystal and feed rod with convex（toward the melt） interfaces are favored to reach single crystals. Influences of several other growth parameters were also discussed in detail in this paper.     

Testing Einstein's faux formula: fast computers+slow humans=creative brilliance

An experiment was designed for the purpose of testing the proposition that creative decision-making can be greatly improved by making use of the personal computer to solve a set of word anagrams serving as hints to a surprise phrase. The authors hypothesised that the experimental condition of students using various unscramble word jumble websites would significantly outperform the control group of students who attempted to unscramble the words and solve the surprise answer by hand. Results were mixed and the authors conclude that certain types of creative problem solving exercises might benefit more from the innate abilities and talents of the participants rather than the speed and accuracy of the computer.