Untersuchungen zur Sorptionsreversibilität von organischen Schadstoffen in Aktivkohle, Holzkohle und Zeolith Y-200

Numerous studies have shown that sorption of organic contaminants in soils is dominated by the natural organic carbon content (C _org) of the soil. However, it is still under discussion whether sorption processes are fully reversible or whether an irreversibly sorbed contaminant fraction remains in the soil. This is especially important when considering soil remediation measures and its targets. In multi-stage sorption-desorption batch experiments with TCE, PCE, ortho-xylene and para-xylene and with the sorbents activated carbon, charcoal and a hydrophobic zeolite Y-200, the reversibility of sorption was studied. It could be shown that the structural features of the sorbents are of ample importance for the occurrence of a desorption-resistant fraction. While sorption was mainly reversible for the micro-porous zeolite Y-200 with a rigid pore network, charcoal and the activated carbon showed significant desorption hysteresis. However, following a subsequent sorption step, this fraction eventually desorbs and is re-mobilized.     

Sport Stadia, Sporting Events and Urban Development: International Experience and the Ambitions of Durban

The paper considers the stadium construction and infrastructure projects underway for World Cup 2010. We ask whether and under which conditions hosting such an event (along with the new facilities and infrastructural development required) will have positive effects on urban development. By analysing the stadium project in Durban, the paper also presents evidence on whether such positive effects may be enhanced by the attempt to create an image effect by seeking outstanding architectural quality of the new stadia.

Reductive electrochemical remediation of emerging and regulated disinfection byproducts

Long-term exposure to low concentrations of disinfection byproducts (DBPs) in drinking water has been associated with increased human-health risks of bladder cancer and adverse reproductive outcomes. In this study, we investigated electrochemical reduction utilizing a resin-impregnated graphite cathode for the degradation of 17 DBPs (i.e. halomethanes, haloacetonitriles, halopropanones, chloral hydrate and trichloronitromethane) at low μg L⁻¹ concentration levels. The reduction experiments were potentiostatically controlled at cathode potentials −700, −800 and −900 mV vs Standard Hydrogen Electrode (SHE) during 24 h. At the lowest potential applied (i.e. −900 mV vs SHE), the disappearance of DBPs from the solution after 24 h of reduction was >70%, except for chloroform (32%), 1,1-dichloropropanone (48%), and chloral hydrate (31%). Due to the participation of several removal mechanisms (e.g. electrochemical reduction, adsorption, volatilization and/or hydrolysis) it was not possible to distinguish the removal efficiencies of electrochemical reduction of individual compounds. Adsorption of the more hydrophilic DBPs (i.e. haloacetonitriles, chloral hydrate, and 1,1-dichloropropanone) onto the electrode seems to be affected by the cathode polarization, as the removals observed in the open circuit experiments were significantly higher than the ones obtained in electrochemical reduction under the same conditions. The overall efficiency of reduction was estimated based on the analyses of the released Cl⁻, Br⁻ and I⁻ ions. Nearly complete C-I bond cleavage was achieved at all three potentials applied, and from the theoretically predicted release of I⁻ ions, calculated based on the removed DBPs, 86 ± 9 to 92 ± 1% was measured in the catholyte solution at −700 to −900 mV vs SHE. Debromination efficiencies obtained were 74 ± 3, 79 ± 6 and 68 ± 4% at −700, −800 and −900 mV vs SHE, while for C-Cl bond cleavage the obtained values were 69 ± 1, 72 ± 1 and 76 ± 4%, respectively. Nevertheless, dechlorination efficiencies are to be considered as approximate, since an increase in Cl⁻ concentration was observed in the open circuit experiments due to the hydrolysis of some of the chlorine-containing DBPs. Although the Coulombic efficiencies for DPBs dehalogenation were only 1.9 ± 0.3 (−900 mV vs SHE) -4.1 ± 0.2% (−700 mV vs SHE), relatively low energy consumption of the process was observed, estimated at 72 ± 2 Wh m⁻³ at −900 mV vs SHE for the concentration range of DBPs in this study (i.e. 65.3-129.7 μg L⁻¹). The study demonstrated that reductive electrochemical treatment has the potential to be a modern remediation technology for the removal of low concentrations of halogenated DBPs in water.     

Europäische Dämmstoffnormen der 2. Generation: Prüfmethoden zur Ermittlung flüchtiger organischer Komponenten (VOC)

2nd generation European Standards for insulating materials and products: test methods for the determination of emissions of volatile organic compounds (VOC) In October 2001 ten “first generation” standards (EN 13162 through EN 13171) were introduced in Europe dealing with insulating materials and products. The new standards now in effect had to be based on the European Construction Products Directive (CPD) and conceptual details had been mandated by the European Commission to the standardization body CEN. Among other properties like thermal conductivity and fire performance the mandate requested to standardize a so called “initial type test (ITT)” for the release of dangerous substances (also called “regulated substances”) to be performed by an independent testing laboratory on behalf of the manufacturer before placing the product onto the market. However, due to the lack of experience and due to a non‐existing European harmonized common method for testing and classification, this property could not be included in the standards in due time and reference was only made to national regulations. Because of this shortcoming, a research project, started in 2003, developed a cost effective and very practical test method based on the emission cell device with a subunit that proved suitable for an initial type test (ITT) for the determination of emissions from thermal insulation materials and products – in particular volatile organic compounds (VOC).     

Zur Neufassung der DIN 4178 “Glockentürme”

To the introduction of the revised German Code DIN 4178 “Bell towers“. The new German Code DIN 4178 replaces the version validated since 1978 for calculation and design of bell towers under bell ringing forces. It contains further aspects of maintenance and restoration especially of historical buildings and gives indications to measurement of oscillation.     

Event driven algorithms applied to a high energy ball mill simulation

In the physics community, event driven molecular dynamics simulations have been successfully applied to typical physical topics, such as granular gases. In contrast, in the engineering sciences, event driven algorithms have not become as popular, even though they can be far more efficient for special systems. In this paper, we present an event driven simulation of a high energy ball mill, where the motion and energy transfer of the grinding balls during operation are simulated. Stable numerical algorithms for collision detection and collision response are developed and several possible pitfalls are discussed. Furthermore, an improved event list handling technique and a specialized space subdivision method is presented. The performance of the partitioning is demonstrated by experiments. It is shown that the scaling rules usually applied are oversimplified. A new way of scaling the process parameters to obtain a higher production yield using iso-impact diagrams is presented.     

Nonlinearity in the rotational dynamics of Haidinger's brushes

Haidinger's brushes are an entoptic effect of the human visual system that enables us to detect polarized light. However, individual perceptions of Haidinger's brushes can vary significantly. We find that the birefringence of the cornea influences the rotational motion and the contrast of Haidinger's brushes and may offer an explanation for individual differences. We have devised an experimental setup to simulate various phase shifts of the cornea and found a switching effect in the rotational dynamics of Haidinger's brushes. In addition, age related macular degeneration reduces the polarization effect of the macula and thus also leads to changes in the brush pattern.     

Vectorial thin-element approximation: a semirigorous determination of Kirchhoff's boundary conditions

A semirigorous model is presented that bridges the gap between classical scalar diffraction theory on the one hand and fully rigorous simulation models on the other. It falls back on the basic ideas of scalar diffraction theory, especially the Kirchhoff approximation. In contrast to classical techniques, however, the boundary values are determined by rigorous methods of the stratified medium theory in the scope of a fully vectorial formulation. By this means the proposed approach takes vertical rigorous coupling effects inside the grating into account while neglecting the lateral ones. We therefore call this method semirigorous and use the name vectorial thin-element approximation. A direct comparison with rigorous coupled-wave analysis as a fully rigorous simulation model allows a detailed discussion of its range of validity and demonstrates a reduction of computation time of the order of 3 magnitudes. In addition, it also reveals deeper insight into the details of the electrodynamics inside diffracting structures. Some examples will demonstrate this benefit.