CENTUM-CS1000在离子膜制碱工艺中的应用

介绍了DCS在离子膜制碱工艺中的应用及常用控制方案的实现和运行效果。     

新型液晶PVDF合金的研究

本文系统地研究了液晶聚合物(LCP)与PVDF合金共混体系的组成及加工工艺条件对共混物制件性能的影响。并用SEM观察了合金的形态结构。结果表明:在液晶含量10%左右时,加工温度为210℃,合金的拉伸强度最高,磨耗量最低,体系分散均匀并形成了较多的微纤结构。     

我国化肥催化剂工业现状

全国48家化肥催化剂制造厂总能力为57Kt/a,产量近30kt/a,设备利用率不到50%。平均万吨氨耗催化剂10.36t,高于国外5.60t水平。现生产31个品种203个型号的催化剂中有103种经部级鉴定,但经常使用的约50种。目前化肥催化剂工业水平与国外相比还存在四方面差距。     

新型节能玻璃钢门窗的研究

本文主要围绕节能主题，从能耗方式、性能指标、结构形式、制作安装等方面论述了玻璃钢门窗在不同气候地区、不同环境和不同领域中的开发和应用。     

二次盐水精制采用5台树脂塔流程简介

介绍了国内首创的离子膜盐水二次精制塔工艺,运行6 a证明本工艺是投资省、见 效快,生产能力大,又切实可行的工艺方法。     

Catalytic activities and properties of mesoporous sulfated Al2O3–ZrO2

Mesoporous sulfated Al₂O₃–ZrO₂ (MSAZ) catalysts with large surface areas and pore volumes after calcination at high temperature (650 °C) and with higher Al₂O₃ content than 20wt% were successfully prepared from a template of block copolymer (P84). The MSAZ catalysts were characterized by X-ray diffraction (XRD), N₂ adsorption, transmission electron microscopy (TEM), ²⁷Al magic-angle spinning nuclear magnetic resonance (MAS NMR), thermogravimetric analysis (TG–DTG), temperature-programmed desorption of ammonia (NH₃-TPD) and infrared spectra (IR) of adsorbed pyridine. It is shown that the resulting mesostructured sulfated Al₂O₃–ZrO₂ samples have a well-developed textural mesoporosity. The number of acid sites present on MSAZ catalysts is higher than that on conventional sulfated zirconia, and the former catalysts are more active than the latter one for various acid-catalyzed reactions.     

熔融石英耐火材料

阐述了熔融石英耐火材料的主要性能与应用领域。     

The influence of F doping on the activity of PbO2 film electrodes in oxygen evolution reaction

The PbO₂ and F⁻-doped PbO₂ (F-PbO₂) film electrodes have been prepared by an electrodeposition process onto platinum substrate. The changes of their electrochemical activity for oxygen evolution (OE) reaction with accelerated electrolysis time have been studied. The results show that the activity of the electrodes decreases with increasing electrolysis time. This can be attributed to the conductivity variations, which are caused by the decrease of the oxygen vacancy concentration in PbO₂ films during OE. The mechanism of the decrease of the oxygen vacancies has been investigated. For F-PbO₂ film electrodes, though its electrochemical activity is somewhat lower than that of undoped one, its activity stability is much higher in comparison with that of PbO₂. The influence of F⁻ doping on the activity of PbO₂ film electrodes has been also discussed.     

基于CFD软件模拟精度与可信度影响因素分析

CFD软件广泛用于流体流动与传热的模拟。但CFD软件是一个黑盒子,良好的人机界面、众多参数基于经验值设定以及二次开发知识的相对薄弱,使得软件使用者对于数据流向并非完全清楚,导致模拟过程的盲目性以及模拟结果的差异。模拟结果的准确与否关系到软件的可信度以及软件的推广应用程度。针对如何有效利用当前模拟软件,如何最大限度地发挥其计算性能,并将计算结果精度及可信度进一步提高,提出了一些看法。     

应用WCA微扰理论推算非极性液体比热容的新方法

本文首次将统计热力学的Ｗｅｅｋｓ－Ｃｈａｎｄｌｅｒ－Ａｎｄｅｒｓｏｎ（简称ＷＣＡ）微扰理论应用于非极性液体定容比热容和定压比热容的推算，用一些液体的ｐ－ｖ－Ｔ实验数据拟合了理论中所用ＬＪ势能函数的势能参数，并提出一个通用关联式。本文方法具有通用性，在编制的计算程序中只需输入物质的临界温度、临界比容、偏心因子等就能算出相应的比热容，工程应用十分方便。