Growth and morphology of nanometer LiMn2O4 powder

The growth of Li_1+xMn₂O₄ via detonation reaction was investigated with respect to the presence of an energetic precursor, such as the metallic nitrate and the degree of confinement of the explosive charge. The detonation products were characterized by scanning electron microscopy. Powder X-ray diffraction and transmission electron microscopy were used to characterize the products. Li_1+xMn₂O₄ with 1-2 μm spherical morphology and more uniform secondary particles, but with smaller primary particles of diameters from 20 to 60 nm and a variety of morphologies were found. The oxides produced by this cheap method affirmed the validity of detonation synthesis of nano-size powders.     

沾化凹陷南斜坡油气运移条件及运移特征研究

油气运移的条件和油气运移的特征决定了油气藏的形成与分布。沾化凹陷南斜坡不整合面、断层以及各层系储集砂体的空间配置构成复杂的立体网络通道，决定了油气的运移，控制了油气分布。以断层为垂向运移通道的油气藏常在断层带附近多层叠置；以连通砂体为主要运移通道的油气藏常形成于距烃源层较近或相邻的层位；以不整合面作为运移通道往往可使油气长距离运移形成各种地层油气藏。沾化凹陷南斜坡的油气藏都是油气经过两种或多种输导层阶梯式运移而形成的。砂体、断层和不整合面组成的输导系统的末端和边缘是油气运移的重要指向区。     

Synthesis and properties of novel amphiphilic sulfated ionomers by the ring‐opening reaction of an epoxidized styrene–butadiene–styrene triblock copolymer

A method for the synthesis of novel sulfated ionomer of styrene–butadiene–styrene triblock copolymer (SBS) was developed. SBS was first epoxidized by performic acid in the presence of a phase‐transfer catalyst; this was followed by a ring‐opening reaction with an aqueous solution of alkali salt of bisulfate. The optimum conditions for the ring‐opening reaction of the epoxidized SBS with an aqueous solution of KHSO₄ were studied. During the ring‐opening reaction, both phase‐transfer catalyst and ring‐opening catalyst were necessary to enhance the conversion of epoxy groups to ionic groups. The products were characterized with Fourier transform infrared spectrophotometry and transmission electron microscopy (TEM). After the potassium ions of the ionomer were substituted with lead ions, the lead sulfated ionomer exhibited dark spots under TEM. Some properties of the sulfated ionomer were studied. With increasing ionic groups or ionic potential of the cations, the water absorbency and emulsifying volume of the ionomer and the intrinsic viscosity of the ionomer solution increased, whereas the oil absorbency decreased. The sulfated ionomer possessed excellent emulsifying properties compared with the sulfonated SBS ionomer. The sodium sulfated ionomers in the presence of 10% zinc stearate showed better mechanical properties than the original SBS. When the ionomer was blended with crystalline polypropylene, a synergistic effect occurred with respect to the tensile strength. The ionomer behaved as a compatibilizer for blending equal amounts of SBS and oil‐resistant chlorohydrin rubber. In the presence of 3% ionomer, the blend exhibited much better mechanical properties and solvent resistance than the blend without the ionomer. SEM photographs indicated improved compatibility between the two components of the blend in the presence of the ionomer. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

导向剂加入方式对Y型沸石合成的影响

以煤系高岭土为原料,采用液态补硅手段调节体系SiO2/Al2O3、导向剂两步加入法合成了Y型沸石.考察了导向剂不同加入方式对Y型沸石合成的影响.采用合理的导向剂两步加入法,特别是通过控制导向剂第二步加入的时间,可明显缩短Y型沸石的晶化时间,并有效地减少P型沸石的生成.     

Numerical Study of Scale Effects of Ultra-Thin Nickel Beams

Recent experiments have shown that metallic materials display significant size effects when the characteristic length scale of non-uniform plastic deformation is close to a micron. Couple stress plasticity has been developed to explain such phenomena by Fleck and Hutchinson. The mechanical behaviors of ultra-thin nickel beams in different boundary conditions were studied with the hybrid element developed for couple stress plasticity before. Strong scale effects are found when the beam's thickness is close to the material characteristic length scale. Such phenomena will disappear if the beam' s thickness is greatly larger than the material characteristic length scale. The scale effect is the beams inherent property and it does not change with the change of support conditions.     

冶金烧结强化盘式钻头齿圈的试验研究

在分析盘式钻头齿圈失效机理的基础上,提出了齿圈表面堆焊耐磨合金强化和镶嵌硬质合金齿圈强化两种方法。通过试验研究和对比分析,确定了采用冶金混合烧结固齿法镶嵌硬质合金齿圈强化盘式钻头。进一步的试验研究表明:采用冶金混合烧结固齿法镶嵌硬质合金齿圈来强化盘式钻头齿圈,其结合情况非常好;硬质合金齿圈的硬度、耐磨料磨损的能力和耐冲击磨料磨损的能力在烧结后都有进一步的提高,说明采用冶金混合烧结固齿法镶嵌硬质合金齿圈来强化盘式钻头齿圈是可行的。     

改性β沸石上合成1,4-二氧六环的研究

在真空条件下将改性 β沸石用于二甘醇合成 1,4 -二氧六环的反应 ,考察了反应温度、反应时间和催化剂用量对催化剂活性的影响 ,并对该催化剂的稳定性进行了考察。结果表明 ,在最佳反应条件下 ,二甘醇转化率达到 89 6 9% ,1,4 -二氧六环的选择性达到 95 0 1%。     

关于传统与现代设计理念的思考

中国传统的思维方式深深地影响了中国传统陶瓷艺术设计，中国传统陶瓷艺术设计的历史脉络清晰，深入到设计思维系统的深层，才有助于我们对当前的陶瓷设计作出有效的转化。现代陶瓷设计的观念是对传统陶瓷文化的延续和发展，深入挖掘传统思维方式的源头活水，才是发展中国现代陶瓷设计的关键。     

测尘仪原理与应用

本文介绍了测尘仪器的基本原理,着重阐述了透射法和散射法的基本原理和实际应用.     

数字分量电视图像的光纤传输实验

介绍了光纤传输数字电视的意义，电视信号分量数字化的标准和优点。利用自行研制的２７０Ｍｂ／ｓ光发射机和光接收机，建立了分量数字电视信号的光纤传输系统，直接传输了１００ｋｍ光纤，系统传输无误码，传输后图像质量不变。光接收机灵敏度达－２９．２４ｄＢｍ，动态范围为１３．５ｄＢ。无压缩电视图像的传输对于远程医疗和演播室间转输节目等有非常实际的意义。