N-溴丁二酰亚胺／吡啶氧化合成己二酰基双偶氮化合物

以己二酰二氯和不同取代基的苯肼合成了N,N'-二芳基己二酰二肼类中间体,然后在N-溴丁二酰亚胺(NBS)／吡啶氧化体系下室温合成了8种己二酰基双偶氮化合物。第一步反应条件为:n(己二酰二氯):n(取代苯肼)=1:2,反应温度0-5℃,反应时间4 h,收率80%-93％;第二步反应条件为:n(N,N’-二芳基己二酰二肼):n(NBs／吡啶)=1:2,氧化反应时间0．5-1．0 h,收率80%-94%。并用元素分析、IR、1H NMR对合成的中间产物及目标化合物进行了表征。     

Processor Utilization Bounds for Real-Time Systems With Precedence Constraints

This paper presents a novel approach to computing tight upper bounds on the processor utilization for general real-time systems where tasks are composed of subtasks and precedence constraints may exist among subtasks of the same task. By careful analysis of preemption effects among tasks, the problem is formulated as a set of linear programming (LP) problems. Observations are made to reduce the number of LP problem instances required to be solved, which greatly improves the computation time of the utilization bounds. Furthermore, additional constraints are allowed to be included under certain circumstances to improve the quality of the bounds.     

Na_2O－Al_2O_3－SiO_2系统霞石微晶玻璃机械强度的研究

霞石微晶玻璃是一种高强度的新型无机非金属材料．本文以Ｎａ２Ｏ－Ａｌ２Ｏ３－ＳｉＯ２系统为基础，引入晶核剂和复合澄清剂，经高温熔制和两步热处理制备的霞石微晶玻璃，具有较高的抗压和抗折强度．结果表明，霞石微晶玻璃的机械强度与霞石晶体及试样的结构有关，也与微晶化热处理的时间有关。     

Monolithic Catalysts with Low Noble-Metal Content for Exhaust Purification of Small Gasoline Engines

A series of low noble-metal coment monolithic catalysts for exhaust purification of small gasoline engines was investigated, and it was found that the Pt/Rh-OSM/Al2O3 （where OSM was oxygen storage material） catalyst with Ce0.5Zr0.5-MnOx（3%MnOx） OSM held low light-off temperature for CO, HC, and NO; quite wide three-way window, and outstanding thermal stability. The catalyst could efficiently comrol exhaust emission of small gasoline engines.     

A sequencing problem for a mixed-model assembly line in a JIT production system

In an assembly line of a just-in-time (JIT) production system, workers have the power and the responsibility to stop the line when they fail to complete their operations within their work zones. This paper deals with a sequencing problem for the mixed-model assembly conveyor line in the JIT production system. In some environment, the most important criterion is the line stoppage rather than the variation of production rates. The problem is to find an optimal sequence of units that minimizes the total line stoppage time. Lower and upper bounds of the total line stoppage time are derived and the branch-and-bound method is applied to the problem. A numerical example is given.     

海底电缆智能防锚损监视系统设计

根据系统的需求分析,设计了一种用于海底电缆智能防锚损监视系统;首先给出设计方案并叙述系统工作原理;然后通过DM73021通信套件实现射频信号的接收、解调及解码,得到NMEA-0183HS格式的ASCⅡ信息数据;最后采用LabVIEW完成ASCⅡ信息数据的采集、解码、监视及显示;实际测试表明,该系统响应时间＜1s,对有抛锚趋势的船舶能及时向海缆管理部门提出预警,满足系统功能要求.     

坦克炮控系统摩擦扰动补偿研究

针对坦克水平向炮控伺服系统中存在的摩擦不确定因素及未建模动态,首先建立水平向炮控伺服系统的数学模型,将摩擦扰动和未建模动态视为一个综合扰动项,然后利用扩张状态观测器对综合扰动项进行观测和补偿,并将扩张状态观测器(ESO)补偿回路作为经典PID控制方法的内回路,实现ESO-PID的复合控制;最后对所用方法进行仿真,结果表明,在原有控制方法的基础上设计控制器,集合了PID控制算法的"被动抗扰"和自抗扰控制方法中扩张状态观测器的"主动抗扰"特性,能够在保持控制系统原有特性的基础上大幅度提高炮控系统的稳定精度以及低速性能。     

Enhanced Photoelectrochemical Performance of Hematite Photoanode by Decorating NiCoP Nanoparticles Through a Facile Spin Coating Method

Catalysis Letters - Hematite (α-Fe2O3) is a potential photoanode material for photoelectrochemical (PEC) water splitting, but its short hole diffusion length and low water oxidation kinetics...     

N、S共掺杂碳基高效氧还原催化剂的制备

杂原子掺杂碳基氧还原（ORR）催化剂具有代替Pt基催化剂的巨大潜力。以硫掺杂g-C₃N₄（S-doped g-C₃N₄, S-g-C₃N₄）作为硫源和氮源,以三嵌段共聚物P123作为碳源,通过简单的高温热解法成功制备了N、S共掺杂碳（N, S co-doped carbon, NSC）催化剂,并考察了热解温度对制备的NSC催化剂ORR性能的影响。材料表征结果显示:温度为1 000 ℃时制备的催化剂NSC-1000具有较高的氮含量和硫含量及最大的比表面积;电化学测试结果显示:NSC-1000具有最佳的ORR性能,在0.1 mol/L KOH溶液中半波电位（half-wave potential, E1/2）高达0.888 V,且经10 000圈循环伏安扫描后E1/2仅负移12 mV,表现出极佳的活性和稳定性。此外,旋转环盘电极测试结果显示:NSC-1000催化剂主要以四电子反应路径催化ORR的发生。本实验为制备N、S共掺杂碳基高效ORR催化剂提供了新的思路。     

混流式水轮机叶道涡演化及压力脉动特性研究

水—风—光互补发电系统中的水轮机将由主要担任发电任务的常规水轮机逐渐转变为担任调节负荷任务的调能水轮机,其运行在部分负荷工况诱发的叶道涡严重制约着水轮机的运行稳定性.本文基于SST k-ω湍流模型与Zwart空化模型耦合的方法开展了混流式水轮机部分负荷工况下叶道涡不稳定流动特性研究.结果表明,转轮上冠处的流动分离对叶道涡的形成有重要贡献.叶道涡在转轮内为一个强度周期性改变的动态过程,其脉动主频为转频的1.1倍.叶道涡强度的变化可分为涡结构由展向中间位置向出水边迅速发展形成完整叶道涡和完整叶道涡强度缓慢增加的两个过程.叶道涡的动态演化会显著增强转轮叶片吸力面出水边一侧的压力脉动幅值,直接影响水轮机的水力稳定性.