城市中的滑动网——南京珠江路旅馆设计

该文论述了通过网络支架实现墙体的适时滑动,创造符合旅客需求的空间功能与规模,求得空间利用效率的最大化,以保持旅馆的良性运营.     

改良柱前荧光胺衍生化-高效液相色谱法测定猪肉中11种磺胺类药物残留

建立改良的磺胺类药物与荧光胺反应的衍生化方法,并应用于猪肉中11种磺胺类药物的高效液相色谱-荧光法测定.选用0.1 mol/L KH2PO4溶液(pH 3.0)0.8 mL、0.3 mg/mL荧光胺溶液0.2 mL与磺胺类药物发生衍生化反应,4℃避光反应40 min,得到磺胺-荧光胺衍生产物.该衍生化方法稳定、可靠,衍...     

水下航行器燃料流量调节阀动态特性仿真

简述了燃料流量调节阀的基本工作原理,建立了以燃料流量调节阀为主的动力系统数学模型,在不同工况下对其换速过程的动态特性进行了仿真,指出了存在的问题,并对今后的改进和试验提出了指导性意见.     

TBD620系列柴油机降低标定转速优化设计

根据市场需求,以TBD620V12柴油机为样机,开展了以1 200 r/min作为标定转速的优化设计研究.基于AVL-BOOST软件对该柴油机开展工作过程性能仿真计算;同时,对柴油机进排气系统、润滑系统、冷却系统做计算评估,选配适用的零部件.试验验证表明:优化设计后样机的排气温度、燃油消耗率、机油压力等各项参数指标均满足设计要求.     

菌菇复合多糖对秀丽线虫氧化胁迫抗性的影响

目的:研究菌菇复合多糖(FHP)的抗氧化效果及作用机制.方法:用化学方法评价FHP体外自由基清除效率,通过秀丽线虫的氧化胁迫存活率试验评价FHP体内抗氧化效果;通过线虫体内氧化胁迫水平检测,胁迫应激关键转录因子活性及其效应基因表达检测和抗氧化酶活性试验等研究FHP的抗氧化活性;通过线虫的寿命试验及脂褐素水平检测研究FH...     

CO_2、CH_4和N_2在不同硅铝比β沸石上的吸附分离性能

采用体积法在273 K和303 K温度下对CO_2,CH_4和N_2在不同硅/铝比的β沸石上的吸附分离性能进行了研究.实验结果表明,Langmuir-Freundlich模型能够较好地拟合吸附实验数据;同一样品上,CO_2的吸附量要大于CH_4和N_2的吸附量;随着硅铝比的减小CO_2的吸附量增加,而硅/铝比对CH_4和N_2的吸附量的影响较小.通过结合Virial方程计算CO_2、CH_4和N_2在不同硅/铝比β沸石上的亨利定律常数和吸附选择性,发现所研究样品对CO_2/CH_4和CO_2/N_2均具有很高的吸附选择性,随着样品硅/铝比的减小,CO_2/CH_4和CO_2/N_2的吸附选择性显著增加,说明较低硅/铝比β沸石有利于分离CO_2.用Clausius-Ciapeyron方程求得CO_2,CH_4和N_2在不同硅/铝比的β沸石上的吸附热与吸附量无关,表明β沸石是一种表面势场均匀的吸附剂.     

Synthesis, characterization and optical limiting property of covalently oligothiophene-functionalized graphene material

An organic solution-processable functionalized graphene hybrid material with oligothiophene (6THIOP-NH-SPFGraphene) has been synthesized. The thermogravimetry analysis data shows that the hybrid is more stable than its parent graphene oxide as observed with an increased onset temperature. Ultraviolet-visible absorption and fluorescence emission data show that the attachment of the electron-acceptor group (graphene oxide sheet) onto the oligothiophene molecules results in an improved absorption than its parent compound in the whole spectral region and an efficient quenching of photoluminescence. The optical limiting properties were studied by using the open-aperture Z-scan measures at 532 nm, and the results show that 6THIOP-NH-SPFGraphene demonstrated a superior optical limiting effect, better than that of the benchmark optical limiting material C₆₀.     

Decolorization of methylene blue by heterogeneous Fenton reaction using Fe3−xTixO4 (0 ≤ x ≤ 0.78) at neutral pH values

In this work, a series of Fe_3−xTi_xO₄ (0 ≤ x ≤ 0.78) was synthesized using a new soft chemical method. The synthetic Fe_3−xTi_xO₄ were characterized using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), Mössbauer spectroscopy, thermogravimetric and differential scanning calorimetry (TG–DSC) analyses. The results showed that they were spinel structures and Ti was introduced into their structures.Then, decolorization of methylene blue (MB) by Fe_3−xTi_xO₄ in the presence of H₂O₂ at neutral pH values was studied using UV–vis spectra, dissolved organic carbon (DOC) and element C analyses. Furthermore, the degradation products remained in reaction solution after the decolorization were identified using ionic chromatography (IC), ¹³C nuclear magnetic resonance spectra (NMR), liquid chromatography and mass spectrometry (LC–MS). Although small amounts of MB were mineralized, the aromatic rings in MB were destroyed completely after the decolorization. Decolorization of MB by Fe_3−xTi_xO₄ in the presence of H₂O₂ was promoted remarkably with the increase of Ti content in Fe_3−xTi_xO₄ due to the enhancement of both adsorption and degradation of MB on Fe_3−xTi_xO₄.     

CO_2超临界萃取技术提取中药有效成分

本文较系统地介绍了CO2 超临界萃取技术提取中药有效成分的优点 ,重点讲述了已工业化的几项提取过程 ,突出了该技术提取中药水溶性有效成分的应用前景     

冷轧厂废水回用处理方案设计及经济分析

根据天津市某冷轧厂废水实际情况,因地制宜,增设1套处理设施对其中部分废水进行处理,使处理出水回用于生产。该处理方案的实施既可减少原污水处理站的运行负荷,又能实现清洁生产,增加废水的回用率,从而实现经济效益和环境效益的统一。