碘仿调节通用型氯丁橡胶的合成

以碘仿为相对分子质量调节剂,按照国内传统通用型氯丁橡胶(CR)(牌号为CR - 232)的生产配方及工艺条件,对氯丁二烯进行乳液聚合制得CR,考察了碘仿用量对CR综合性能及数均分子量、分子量分布的影响,并与传统调丁型CR - 232的性能加以对比.结果表明,当碘仿质量分数为0.38％,0.40％,0.42％时,除门尼焦...     

聚丙烯保压注射成型冷却过程温度场的研究

采用数值模拟结合实验验证的方法,对聚丙稀（PP）注射成型（保压和不保压）冷却过程实验和数值模拟进行分析。用数据采集器对不同共混物注射冷却过程中的温度变化进行数据采集,并将采集所得温度的实验值与根据改进焓法用Matlab软件对聚丙烯冷却过程中温度分布进行数值模拟计算所得的值进行了比较分析,结果表明聚丙烯在液体冷却段温度分布的实验值与理论值几乎完全吻合,在结晶段和固体冷却段实验值略有不同。     

海豚充电器产品与模具开发制造

以海豚充电器上壳模具开发制造为例,重点探讨运用数字化建模制造技术、模流分析理论以及现代成型技术设计制造模具的过程,包括产品造型、成型零件的加工、型腔数量及模架确定、浇注系统设计、推出方式确定、以及冷却系统设计.     

Functionalization of reduced graphene oxide nanosheets via stacking interactions with the fluorescent and water-soluble perylene bisimide-containing polymers

Reduced graphene oxide (RGO)-polymer composites were prepared via π-π stacking interactions of RGO with the perylene bisimide-containing poly(glyceryl acrylate) (PBIPGA). PBIPGA was synthesized via atom transfer radical polymerization (ATRP) of solketal acrylate (SA), using bifunctional N,N′-bis{2-[2-[(2-bromo-2-methylpropanoyl)oxy]ethoxy]ethyl}perylene-3,4,9,10-tetracarboxylic acid bisimide (PBI-Br) as the initiator, and subsequent hydrolysis of the acetal-protecting group. PBIPGA was characterized by ¹H NMR spectroscopy, gel permeation chromatography (GPC), UV-visible absorption spectroscopy and fluorescence spectroscopy. The presence of π-π stacking interactions between PBI and the RGO surface was suggested by fluorescence and UV-visible absorption spectroscopy results. The chemical states and π-π stacking interaction, morphology, and composition of RGO-PBIPGA composites were characterized, respectively, by X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM) and thermogravimetric analysis (TGA). The low cytotoxicity level of the RGO-PBIPGA composites was revealed by incubation with 3T3 fibroblasts in 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyl tetrazolium bromide (MTT) assays in vitro.     

多巯基水性EP低温固化剂的制备及性能研究

首先制备了PUD-SH[多巯基封端的PU(聚氨酯)水分散体]和水性EP(环氧树脂),然后将两者按n(巯基)∶n(环氧基)=1∶1复合,并在不同温度时成膜,制得厚度约100μm的复合固化涂层。研究结果表明:PUD-SH和水性EP之间发生了环氧基开环反应,固化后复合涂层透明柔韧,其凝胶量接近100%,涂层的吸水率<17.50%,硬度>6H,耐甲乙酮擦拭次数>1 600次;固化时叔胺促进剂的存在可有效提高复合固化涂层的固化度,缩短其固化时间,但对其他性能影响甚微。     

具有串联补偿的大型电力系统中次同步谐振（SSR）的分析

介绍一个专门研究具有串联补偿的大型电力系统中次同步谐振问题的仿真程序ＳＯＦＲＥＳＰ。该程序采用复转矩系数法，在这一方法的基础上引进了机网接口技术，使其在分析大型电力系统ＳＳＲ问题时，不仅概念清楚，而且无需对原网络作任何简化。本文将ＳＯＦＲＥＳＰ成功地应用于３３９个节点和４５台发电机（包括等值机）的大型电力系统中。     

Facile synthesis and catalytic properties of single crystalline β-MnO2 nanorods

Single-crystalline β-MnO₂ nanorods were successfully synthesized through facile reflux treatment of KMnO₄ and MnSO₄ in HNO₃ solution. TEM and SEM images show that the synthesized β-MnO₂ nanorods exhibited diameters of 20–50 nm, and lengths that ranged from approximately 0.5 to 2.0 μm with decreasing HNO₃ concentrations from 0.8 to 0.1 mol/L. The β-MnO₂ nanorods underwent three primary evolutionary stages over time. They exhibited excellent catalytic properties for the degradation of methylene blue (MB) by a Fenton-like reaction.     

Kinetic and structural studies of the polymerization of N,N′‐bismaleimide‐4,4′‐diphenylmethane with barbituric acid

Both the isothermal and non‐isothermal polymerizations of N,N′‐bismaleimide‐4,4′‐diphenylmethane (BMI) with barbituric acid (BTA) were investigated by the differential scanning calorimeter. The experimental results showed that the polymerizations of BMI with BTA were governed by the competitive Michael addition reaction and free radical polymerization mechanisms. Furthermore, the contribution of free radical polymerization becomes more important when the mole fraction of BTA decreases. ¹H NMR and ¹³C NMR measurements further support the coexistence of the Michael addition reaction and free radical polymerization mechanisms. A preliminary kinetic model that took into account the competitive Michael addition reaction and free radical polymerization mechanisms was developed. POLYM. ENG. SCI., 2011. © 2011 Society of Plastics Engineers     

Green process for methacrolein separation with ionic liquids in the production of methyl methacrylate

Separation of methacrolein (MAL) is a critical technique for the production of methyl methacrylate, which is an important raw material for the preparation of acrylic resins applied in a variety of end‐uses. In this work, an azeotropic distillation process and an ionic liquid (IL) green process were developed for the separation of MAL with BmimBF₄. The two processes were simulated with Aspen plus. The simulated results are in good agreement with the experimental results which were attained in a pilot plant. Also the economic and green degree analysis of these two processes was investigated. When compared with the azeotropic distillation process, the IL green process exhibits economic superiority and green degree superiority. © 2010 American Institute of Chemical Engineers AIChE J, 2011     

Preparation and application of sulfonated poly(1‐octene‐co‐styrene)

In this article, 1‐octene and styrene was copolymerized by the supported catalyst (TiCl₄/ID/MgCl₂). Subsequently, by sulfonation reaction, sulfonated poly(1‐octene‐co‐styrene)s which were amphiphilic copolymers were prepared. The copolymerization behavior between 1‐octene and styrene is moderate ideal behavior. Copolymers prepared by this catalyst contain appreciable amounts of both 1‐octene and styrene. Increase in the feed ratio of styrene/1‐octene leads to increase in styrene content in copolymer and decrease in molecular weight. As the polymerization temperature increases, the styrene content in the copolymers increases, however, the molecular weight decreases. Hydrogen is an efficient regulator to lower the molecular weights of poly(1‐octene‐co‐styrene)s. The sulfonation degree of the sulfonated poly(1‐octene‐co‐styrene)s increased as the styrene content in copolymer increased or the molecular weight decreased. Thirty‐six hour is long enough for sulfonation reaction. The sulfonated poly(1‐octene‐co‐styrene)s can be used as effective and durable modifying agent to improve the wettability of polyethylene film and have potential application in emulsified fuels and for the stabilization of dispersions. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2011