Electrochemical corrosion behavior of 2A02 Al alloy under an accelerated simulation marine atmospheric environment

The corrosion behavior of 2A02 Al alloy under simulated marine atmospheric environment has been studied using mass-gain, scanning electron microscope/energy dispersive spectroscopy (SEM/EDS), laser scanning confocal microscopy, X-ray diffraction spectroscopy and localized electrochemical methods. The results demonstrate that the relationship between the corrosion induced mass-gain and the corrosion time is in accordance with the power rule. The mass-gain increases gradually during the corrosion time, while the corrosion rate decreases. With ongoing of the corrosion, corrosion products film changed from a porous to a compact structure. The various spectroscopic data show that the corrosion products films composed mainly of Al(OH)₃, Al₂O₃ and AlCl₃. The electrochemical corrosion behavior of the 2A02 Al alloy was studied by electrochemical impedance spectroscopy (EIS).     

DNA-Directed alkylating agents. 7. Synthesis, DNA interaction, and antitumor activity of bis(hydroxymethyl)- and bis(carbamate)-substituted pyrrolizines and imidazoles

A series of bis(hydroxymethyl)-substituted imidazoles, thioimidazoles, and pyrrolizines and related bis(carbamates), linked to either 9-anilinoacridine (intercalating) or 4-(4-quinolinylamino)benzamide (minor groove binding) carriers, were synthesized and evaluated for sequence-specific DNA alkylation and cytotoxicity. The imidazole and thioimidazole analogues were prepared by initial synthesis of [(4-aminophenyl)alkyl]imidazole-, thioimidazole-, or pyrrolizine dicarboxylates, coupling of these with the desired carrier, and reduction to give the required bis(hydroxymethyl) alkylating moiety. The pyrrolizines were the most reactive alkylators, followed by the thioimidazoles, while the imidazoles were unreactive. The pyrrolizines and some of the thioimidazoles cross-linked DNA, as measured by agarose gel electrophoresis. Strand cleavage assays showed that none of the compounds reacted at purine N7 or N3 sites in the gpt region of the plasmid gpt2Eco, but the polymerase stop assay showed patterns of G-alkylation in C-rich regions. The corresponding thioimidazole bis(carbamates) were more selective than the bis(hydroxymethyl) pyrrolizines, with high-intensity bands at 5'-NCCN, 5'-NGCN and 5'-NCGN sequences in the PCR stopping assay ( indicates block sites). The data suggest that these targeted compounds, like the known thioimidazole bis(carbamate) carmethizole, alkylate exclusively at guanine residues via the 2-amino group, with little or no alkylation at N3 and N7 guanine or adenine sites. The cytotoxicities of the compounds correlated broadly with their reactivities, with the bis(hydroxymethyl)imidazoles being the least cytotoxic (IC50s >1 microM; P388 leukemia) and with the intercalator-linked analogues being more cytotoxic than the corresponding minor-groove-targeted ones. This was true also for the more reactive thioimidazole bis(carbamates) (IC50s 0.8 and 11 microM, respectively), but both were more active than the analogous "untargeted" carmethizole (IC50 20 microM). The bis(hydroxymethyl)pyrrolizine analogues were the most cytotoxic, with IC50s as low as 0.03 microM.     

图的正交(g,f)-因子分解

设ｇ和ｆ分别是定义在图Ｇ的顶点集合Ｖ（Ｇ）上的整数值函数且对每一个ｘ∈Ｖ（Ｇ）有２≤ｇ（ｘ）≤ｆ（ｘ）．证明了若Ｇ是（ｍｇ＋ｍ－１,ｍｆ－ｍ＋１）—图,则对Ｇ中任意一个给定的有ｍ条边的子图Ｈ,Ｇ有一个（ｇ,ｆ）—因子分解与Ｈ正交．     

Sentiment-oriented contextual advertising

Web advertising (Online advertising), a form of advertising that uses the World Wide Web to attract customers, has become one of the world’s most important marketing channels. This paper addresses the mechanism of Content-based advertising (Contextual advertising), which refers to the assignment of relevant ads to a generic web page, e.g., a blog post. As blogs become a platform for expressing personal opinion, they naturally contain various kinds of expressions, including both facts and comments of both a positive and negative nature. Besides, in line with the major tenet of Web 2.0 (i.e., user-centric), we believe that the web-site owners would be willing to be in charge of the ads which are positively related to their contents. Hence, in this paper, we propose the utilization of sentiment detection to improve Web-based contextual advertising. The proposed sentiment-oriented contextual advertising (SOCA) framework aims to combine contextual advertising matching with sentiment analysis to select ads that are related to the positive (and neutral) aspects of a blog and rank them according to their relevance. We experimentally validate our approach using a set of data that includes both real ads and actual blog pages. The results indicate that our proposed method can effectively identify those ads that are positively correlated with the given blog pages.     

Dynamically modulated intensity interrogation scheme using waveguide coupled surface plasmon resonance sensors

An electro-optically modulated intensity interrogation method based on tunable waveguide coupled surface plasmon resonance sensors has been proposed. It has been theoretically and experimentally demonstrated that the proposed scheme can enable sensitive measurement of measurand variations. By modulating the refractive index in the waveguide layer, this interrogation method yields modulated signal whose amplitude is related to measurand's refractive index. This amplitude modulated signal offers a higher signal to noise ratio and eliminates additive noise in the sensor system. A preliminary investigation using saline buffers with different NaCl concentrations shows a resolution of 2.3 × 10^?6 refractive index unit by our approach. Resolution can be controlled by the amplitude of the applied modulation voltage and can be further enhanced by optimizing the device structure or improving the electro-optical (E-O) coefficient of the E-O material. This approach is simple, stable, and promising for low-cost or multi-channel SPR biosensor applications.     

变频器故障分析及处理

从参数设置、过电压、过电流、过负载等方面详细分析了变频器常见故障产生的原因及处理方法.     

一种实时可靠的移动无线传感器网络贪婪地理路由协议

随着定位装置和定位算法的成熟,基于地理位置信息的贪婪地理路由协议受到广泛的关注与研究.但是,在移动无线传感器网络贪婪地理路由协议中,周期性信标交换条件下采用贪婪转发策略会引起通信暂盲现象,造成数据的丢失.基于右手法则的面遍历算法,对路由空洞的形状不能进行感知,数据转发具有很大的盲目性,转发路径有时比最优路径长很多,造成数据传输时延的增加.针对上述问题提出一种实时可靠的QoS贪婪地理路由协议,该协议通过自适应信标交换算法、基于过渡带思想的贪婪转发策略和基于路标迭代提取和剔除的自适应空洞处理算法,使得数据分组能够实时可靠地传输.NS-2仿真结果表明该协议在不增加控制开销的情况下,能够有效减缓通信暂盲现象,高效地处理路由空洞问题,大大提高协议的实时性和可靠性,可应用于对实时性和可靠性有一定要求的大规模移动无线传感网络.     

WSN密钥预分配方案的安全弹性定量分析

介绍目前流行的同构型无线传感器网络的基本密钥预分配方案、q-composite密钥预分配方案和异构型无线传感器网络的密钥预分配方案,分析这3种密钥预分配方案的安全性。根据敌手对无线传感器网络的攻击能力,建立精确的敌手攻击模型,在该模型下提出一种安全弹性定量分析方法。概率分析和模拟实验结果表明,该方法可用于定量比较密钥预分配方案的安全性。