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991.
Preparation of dual‐layer acetylated methyl cellulose hollow fiber membranes via co‐extrusion using thermally induced phase separation and non‐solvent induced phase separation methods 下载免费PDF全文
Hanna Jang Du‐Hyun Song Hye‐Jin Lee Seong‐Han Lim In‐Chul Kim Young‐Nam Kwon 《应用聚合物科学杂志》2015,132(43)
Dual‐layer acetylated methyl cellulose (AMC) hollow fiber membranes were prepared by coupling the thermally induced phase separation (TIPS) and non‐solvent induced phase separation (NIPS) methods through a co‐extrusion process. The TIPS layer was optimized by investigating the effects of coagulant composition on morphology and tensile strength. The solvent in the aqueous coagulation bath caused both delayed liquid–liquid demixing and decreased polymer concentration at the membrane surface, leading to porous structure. The addition of an additive (triethylene glycol, (TEG)) to the NIPS solution resolved the adhesion instability problem of the TIPS and NIPS layers, which occurred due to the different phase separation rates. The dual‐layer AMC membrane showed good mechanical strength and performance. Comparison of the fouling resistance of the AMC membranes with dual‐layer polyvinylidene fluoride (PVDF) hollow fiber membranes fabricated with the same method revealed less fouling of the AMC than the PVDF hollow fiber membrane. This study demonstrated that a dual‐layer AMC membrane with good mechanical strength, performance, and fouling resistance can be successfully fabricated by a one‐step process of TIPS and NIPS. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42715. 相似文献
992.
Discharged Energy Properties of SrO–PbO–Na2O–Nb2O5–SiO2 Glass‐Ceramics with Different Crystallization Time 下载免费PDF全文
Qingmeng Zhang Chang Li Hongwei Liu Qun Tang Jinfeng Liu Hongtao Li Meng Wang Weiping Xie Jun Du 《Journal of the American Ceramic Society》2015,98(2):366-369
Discharged energy properties of PbO–SrO–Na2O–Nb2O5–SiO2 glass‐ceramics with crystallization time from 1 to 1000 min were investigated by measuring their hysteresis loops (described as quasi‐static measuring method) and pulse‐discharge current‐time curves (described as dynamic measuring method). The results show the same trend for both measuring methods: With the increment of crystallization time, the discharged energy density increases gradually, while the energy efficiency decreases. The highest energy efficiencies were obtained in the sample with crystallization time of 1 min, which are 96.3% and 82.4%, corresponding quasi‐static and dynamic measurement, respectively. The reduction of energy efficiency with crystallization time is attributed to combined effect of ferroelectric polarization and interfacial polarization, and part of the corresponding energy could not release in the pulse‐discharge process. 相似文献
993.
Bromate by-product formation during ozonation of bromide-containing potable water has aroused widespread concern. In this study, cetylpyridinium chloride was selected to modify two different kinds of granular activated carbon (GAC) to improve their bromate adsorption capacity. The adsorption characteristics of modified GAC were studied by batch and column tests, with results suggesting greatly improved bromate adsorption ability: the saturation capacities for bromate were >7 times for modified GAC than for GAC under the experimental conditions used. This enhancement in adsorptive capacity is likely due to an increase in basic functional groups, because the saturated adsorption capacity of bromate on the GAC is positively correlated with the basic functional groups. The increase of the basic functional groups accelerates OH- dissociation from the GAC surface and protonation of the GAC surface, thus resulting in the enhancement in adsorptive capacity. The modified GAC was relatively immune to the impact of pH change over a broad range. Both the Yoon-Nelson model and the Thomas model fit well the breakthrough curves of bromate adsorbed by modified and unmodified GAC under different conditions. Our results provide insight into the sorption process of bromate onto modified GAC. 相似文献
994.
Chuantao Gu Zhengkun Du Wenfei Shen Xichang Bao Shuguang Wen Dangqiang Zhu Ting Wang Ning Wang Renqiang Yang 《应用聚合物科学杂志》2015,132(8)
Three conjugated polymers, P1–P3, with dithiafulvalene (DTF) as side chains have been synthesized. All polymers have good thermal stabilities. The DTF unit could be oxidized to DTF?+ which was observed from cyclic voltammetry and ultraviolet–visible (UV–vis) spectra, and the oxidation process was independent of the conjugated backbone of the polymer. The strong π–π* transition absorbing band of the three polymers decreases gradually as increasing oxidation, and the resulting DTF?+ species give rise to an additional band at 750–1100 nm, which can be assigned to a distinguishing feature of the cation radical species. Photovoltaic device based on the blend of P2 and [6,6]‐phenyl‐C61‐butyric acid methyl ester (PC61BM) showed the power conversion efficiency of 1.05% with a fill factor of 42.8%. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41508. 相似文献
995.
Smoke and toxicity suppression by zinc salts in flame‐retardant polyurethane‐polyisocyanurate foams filled with phosphonate and chlorinated phosphate 下载免费PDF全文
Three types of zinc salts, ZnAl2O4, ZnFe2O4, and Zn2SiO4, were prepared by coprecipitation. Potential smoke and toxicity suppression by zinc salts in flame‐retardant polyurethane‐polyisocyanurate foams (FPUR‐PIR) with dimethylmethylphosphonate (DMMP) and tris (2‐chloropropyl) phosphate (TCPP) were investigated. The crystal structure and dispersity of zinc salts in FPUR‐PIR were characterized by X‐ray diffraction (XRD) and scanning electron microscopy (SEM). Smoke density, flame retardancy, and thermal degradation were studied using smoke density rating (SDR), limiting oxygen index (LOI), the cone calorimeter test, and thermogravimetry coupled with FTIR spectrophotometry (TGA‐FTIR). The results indicated that pure zinc salts were obtained and evenly dispersed on the cell wall of FPUR‐PIR. SDR and the specific extinction area (SEA) were significantly decreased, the time to second heat release rate peak (pk‐HRR) of FRUP‐PIR was delayed after incorporation of the zinc salts; zinc salts partially inhibited phosphorus oxide release into the gas phase, enhanced the condensed phase effect of phosphorus, reduced, and prolonged the release of isocyanate compound and hydrogen cyanide from FRUP‐PIR; due to an increase in the amount of char residues, which indicated the suppression of smoke and toxicity volatiles. ZnFe2O4 resulted in better char formation at the initial degradation stage of FPUR‐PIR, and ZnAl2O4 retained more phosphorus in the solid phase at higher temperature. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41846. 相似文献
996.
介绍了煤制天然气的技术路线,分析了市场需求、生产成本。煤制天然气与进口SNG、进口增量LNG和进口LPG相比,具有价格优势。按照全生命周期评价方法,分析煤制天然气项目的碳排放和能耗,燃煤发电路线优于常规煤制天然气,应加快研发一步法煤制天然气工艺,提高综合能效。 相似文献
997.
PP改性汽车轮罩专用料的研制 总被引:3,自引:0,他引:3
通过在聚丙烯中加入EPDM(三元乙丙橡胶)、LDPE,形成三元共混体系,并在体系中加入交联剂、助交联剂、流动性调节剂等助剂及一种较新型的无机填料硅土,可明显改善聚丙烯的冲击性能、加工流动性和尺寸稳定性,使其能够满足生产及性能要求并降低了成本。 相似文献
998.
999.
1000.
Bao‐Xin Du Zheng‐Jun Quan Yu‐Xia Da Zhang Zhang Xi‐Cun Wang 《Advanced Synthesis \u0026amp; Catalysis》2015,357(6):1270-1276
A general protocol for the chemoselectivity‐controlled C C and C S coupling reactions of di(hetero)aryl disulfides with Grignard reagents catalyzed by ferrocene and palladium acetate has been developed. Ferrocene favored the formation of C S coupled products at low temperature, whereas C C bond couplings were favored when palladium acetate was used. All the reactions proceeded with excellent chemoselectivity and in good yields under mild conditions, and a library of molecules with pyridine and pyrimidine scaffolds was produced.