活性炭催化臭氧化处理含氰废水的试验研究

研究了活性炭催化臭氧化降解低质量浓度含氰废水,考察了臭氧投加量、活性炭用量、pH值等因素对处理效果的影响.试验结果表明:活性炭对臭氧有明显的催化作用,并可以提高臭氧的利用率;在CN-初始质量浓度150 mg/L、臭氧投加量30 mg/min、活性炭14 g/L、反应30 min条件下,CN-去除率为99.8%,相对于单...     

液晶聚合物分子设计研究进展

综述了液晶聚合(物LCP)分子设计的一般原则,着重介绍了主链型热致LCP、主链型溶致LCP及侧链LCP的分子结构和分子设计并,列举了国内外各类型LCP的分子设计实例。     

生物活性聚合物及其复合材料在骨组织工程中的应用进展

骨是世界上第二大需要移植的组织,每年至少有400万次手术使用骨移植物和骨代替材料.传统的治疗方法的局限性影响了当前的治疗选择,并且由于创伤、癌症、感染和关节炎引起的骨缺损现象不断增加,在临床治疗中对骨移植物的需求也持续上升.自体移植物和异体移植物是临床治疗骨缺损的常用方法,而慢性炎症、疾病传播和免疫排斥反应的发生阻碍了...     

视频业务的短期统计特性

利用动态图象序我研究了ＡＴＭ网络中视频业务和短期统计特性,对视频图象每个宏块经过ＭＰＥＧ压缩后所产生的比特数进行了分析,研究了量化比例因子及量化加权矩阵对业务短期统计特性的影响。统计结果表明,量化比例因子对每个宏块比特数的的概率分布影响最为明显,量化加权矩阵对统计特性的轮廓影响很小,当量化比较精细时图象内容对分布特性的低比特部分影响比较明显,而粗量化时它的影响较弱。     

消除块效应的迭代算法

介绍了在极低比特率的图象通信中消除块效应的迭代算法。这种方法的突出优点是既能消除块效应又能保持图象原有细节,为了检验算法的效果,还图象的块效应进行了定量计算,计算机仿真结果表明这种迭代方法对于消除块效应是有效的。     

Ag担载介孔Bi2WO6的制备及其太阳光催化性能

采用硬模板法及液相沉淀法制备了介孔Bi2WO6(m-Bi2WO6)光催化剂,通过光还原沉积贵金属的方法制备了银担载的m-Bi2WO6复合纳米粒子(Ag/m-Bi2WO6),并利用氮气吸附脱附、XRD、XPS、DRS等测试技术对样品进行了表征。以RhB染料为目标降解物,考察了样品的光催化活性。结果表明,介孔结构能够提高Bi2WO6光催化剂的光催化性能;担载金属银,使得m-Bi2WO6催化剂的光催化性能得到了提高。     

Mo—Al催化体系合成高乙烯基1,2—聚丁二烯的研究

以 MoCl_3(OOCC_7H_(15))_2-(i-Bu)_2AlO-■(Mo-Al)为催化剂,在加氢汽油中,对丁二烯(Bd)聚合活性进行了研究,考察了聚合条件对聚合活性、聚合物分子量以及微观结构的影响。结果表明,本体系催化活性较高,在酸/钼=6,Mo/Bd=2.0×10~(-4),Al/Mo=50(摩尔比),于50℃聚合5小时,丁二烯转化率达80%。最佳聚合活性条件:正辛酸/MoCl_5=3,聚合温度60℃,Al/Mo=60,(当 Mo/Bd=2.0×10~(-4)时)。Al/Mo 值适宜范围为20—90。制得的聚合物1,2—链节含量高于80%。     

Correlation between growth behavior,internal stress distribution and properties of ZnO:Zn crystals grown by carbon-assisted chemical vapor transport

Internal stress and stress-related defects are considered as the major obstacles that significantly hinder the growth of high-quality ZnO-based crystals. In this work, high-crystalline-quality ZnO:Zn bulk crystals were successfully grown by carbon-assisted chemical vapor transport (CVT). Internal stress in the crystal was directly measured by a neutron beam from a reactor, and stress distributions along the radial direction at different depths were obtained. The stress, temperature, and flow fields in the growth system were simulated by the finite element (FE) method, and the results agreed with the neutron stress analysis. The etch pit density (EPD), Hall properties, and optical transmittances of different crystal regions were studied in detail, and the distribution trend of the crystal properties was consistent with that of internal stress and stress-related defects in the crystal. It is found that the unique temperature filed in the growth system causes the crystal to bend to a slightly convex toward the growth direction and gives rise to a driving force for structural defect formation. The + c and –c faces of the crystal are subjected to tensile and compressive stress, respectively. The maximum stress values are about 280 MPa and -291 MPa near the central regions of ±c faces, while the crystal periphery is basically free of internal stress. The region near the center of +c face has an EPD of 7.5 × 10³ cm^-2 and a transmittance of 79.2% at 800 nm wavelength, while the corresponding carrier concentration and mobility are 2.27 × 10¹⁷ cm^?3 and 159 cm²/V·s, respectively. By comparison, the crystal periphery has an EPD of 10² cm^-2 with an 80.5% transmittance at 800 nm, while the carrier concentration and mobility are 1.85 × 10¹⁷ cm^?3 and 184 cm²/V·s, respectively.     

A comparative analysis of China and other countries in metabolic engineering: Output,impact and collaboration

In recent years, metabolic engineering has made great progress in both academic research and industrial applications. However, we have not found any articles that specifically analyze the current state of metabolic engineering in China in comparison with other countries. Here, we review the current development and future trends of global metabolic engineering, conduct an in-depth benchmarking analysis of the development situation of China’s metabolic engineering, and identify current problems as well as future trends. We searched publications in the Scopus database from 2015 to September 2020 in the field of metabolic engineering, and analyzed the output in general, including publication trends, research distribution, popular journals, hot topics and vital institutions, but also analyzed the share of citations, field-weighted citation impact, and production in collaboration with strategic countries in science and technology. This study aims to serve as a reference for later studies, offering a comprehensive view of China’s contribution to metabolic engineering, and as a tool for the elaboration of national public policy in science and technology.     

硅醚的选择性去保护

用硅烷试剂保护羟基,介绍了通过底物控制（保护基团立体效应和电效应,硅醚分子的结构环境与电子云密度、邻近官能团影响）和试剂控制两种手段,在有多个硅烷保护基存在下的选择性脱保护。