基于Motif参数的线边缘粗糙度评定方法研究

针对现有线边缘粗糙度（line edge roughhess,LER）表征参数的不足,提出采用基于Motif参数的LER表征方法。对Motif参数的基本概念和评定流程进行了介绍,并以多层薄膜沉积技术制备的纳米线宽样板的LER评定为例进行了实验。结果表明：Motif参数无需评定基准,可以在轮廓全域内表征LER的幅度和间距特性,评定结果具有一定的鲁棒性。     

Impact of required storage space on storage policy performance in a unit-load warehouse

The performance of a storage policy in a warehouse is usually evaluated on the basis of the average one-way travel distance/time needed to store/retrieve a load. Dividing the storage space into zones based on item turnover frequency can reduce the travel distance. However, for a given number of stored items, a larger number of storage zones also requires more storage space, because of reduced space sharing between the items, which increases travel time. This study considers the required space consumption by storage zoning in comparing the performance of random, full turnover-based and class-based storage policies for a unit-load warehouse operated by a forklift in single-command mode. A generalised travel distance model that considers the required space consumption is developed to compare the performance of these policies. Results show that the one-way travel distance of a random policy decreases with the increase in skewness of the demand curve. By considering the required space consumption, a class-based storage policy performs generally better than a full turnover-based policy. In addition, the optimal warehouse shape factor (ratio of warehouse width to depth) appears to decrease with the skewness of the demand curve. Warehouse managers are advised to adopt a wide-shallow warehouse layout when the item demands are approximately equal, whereas a narrow-deep layout is preferred when the demand curves are steep.     

光突发交换网络的区分服务混合信令协议

针对光突发交换(OBS)网络提出了一种新的信令--区分服务混合(DSH)信令协议.它根据电路仿真业务和非实时数据业务对QoS的不同要求分别采用TAW和JET信令协议,尤其是对TAW信令做了相应改进,使之更适合于OBS网络承载电路仿真业务.利用电路仿真业务发出的"呼叫请求",可以预先建立从源结点到目的结点的"虚通路",并在整个呼叫持续时间内保持该"虚通路"连接.这样,对于被接受的那些呼叫,可以显著减小数据突发的端到端传送时延和丢失率.     

链转移剂单体α-甲基丙烯酸-3-巯基己酯对支化聚苯乙烯悬浮聚合的影响

以α-甲基丙烯酸-3-巯基己酯(MHM)为链转移剂单体,偶氮二异丁腈(AIBN)为引发剂,采用悬浮聚合方法合成支化聚苯乙烯。考察了MHM和AIBN浓度对聚合反应的影响;采用核磁共振氢谱(1H-NMR)、三检测体积排除色谱(TD-SEC)和旋转流变仪对支化聚苯乙烯进行了表征分析。结果表明,当物质的量比n(AIBN)/n(MHM)>1时,可以避免交联制备相对分子质量分布相对较窄的高相对分子质量支化聚苯乙烯(-Mw.MALLS=1.03×106g/mol,PDI=7.76),其Zimm相对支化因子g′为0.51,表现出较高的支化程度;与同相对分子质量的线性聚合物相比较,合成的支化聚合物表现出很低的聚合物熔体黏度,同时未表现出明显的剪切变稀行为。     

2－氨基－4－氯苯酚的合成研究

提出了以对二氯苯为原料，经硝化，水解和还原三步合成２－氨基－４－氯苯酚的讨了影响反应的因素。产品总收率达７７％。     

The h-p version of the finite element method

The paper is the second in the series of two analyzing the h-p version of the finite element method. It generalizes the results of the first part (Guo, Babuska 1986) and presents computational results.Supported by the NSF Grant DMS-8315216Partially supported by ONR Contract N00014-85-K-0169     

Hydrothermal synthesis of ultrathin ZnO nanosheets and their gas-sensing properties

Gas-sensing performances can often be enhanced significantly once the size of sensing nanomaterials approaches a critical value of 15 nm. Here, we synthesize, by a simple hydrothermal method accompanied by the calcination process, ultrathin ZnO nanosheets with a thickness as thin as 10–13 nm. We find that the prepared zinc hydroxide carbonate precursor is largely agglomerated, yet transformed to the ultrathin ZnO nanosheets in a dispersive fashion after the calcination process. The as-prepared ultrathin nanosheets exhibit excellent gas-sensing functions to ethanol gas at the optimal temperature as low as 300 °C under the concentration of 50 ppm, rendering them a promising sensing material for the on-site detection of ethanol.     

Hydrothermal growth of whitlockite coating on β-tricalcium phosphate surfaces for enhancing bone repair potential

In this study, we developed a simple approach for the controllable growth of whitlockite(WH) on a β-tricalcium phosphate surface and investigated its cell viability via CCK-8, its live-dead staining and its alkaline phosphatase activity. Herein, WH with controllable morphologies was prepared by regulating the hydrothermal reaction conditions. The results of scanning electron microscopy, X-ray diffraction and Xray photoelectron spectroscopy indicated that pure hexagonal plates of WH were prepared successfully.In vitro cell experiments showed that WH possessed excellent biocompatibility and effectively promoted the adhesion and proliferation of mouse bone mesenchymal stem cells. The osteogenesis of the WH was also enhanced. The obtained WH was expected to be utilized for promising applications as implantable block materials for bone repair.     

稻草生物炭对铕的吸附行为及机理研究

以农业残留物为原料制备的生物炭被广泛应用于去除重金属, 这对于环境保护具有双重意义。本研究以稻草为原料制备了生物炭, 通过系列静态实验和光谱技术研究其对重金属铕(Eu)的吸附行为及机理。研究发现溶液pH显著影响生物炭对Eu(III)的吸附量, 但不改变吸附反应时间; 腐殖酸/富里酸(HA/FA)在pH<7.0的溶液中能促进生物炭对Eu(III)的吸附, 而在pH>7.0的溶液中则抑制Eu(III)的吸附; 吸附过程主要涉及共沉淀或内表面络合机制; 该吸附属于化学吸附, 且吸附速率受内颗粒扩散过程的限制。此外, Freundlich模型对该吸附拟合最好, Langmuir模型显示稻草生物炭对Eu(III)的最大吸附量为40.717 mg/kg, 这可能与生物炭的层状结构和丰富的官能团有关; 热力学分析表明该吸附是自发的吸热过程。这些发现有利于评估稻草生物炭在去除水中重金属方面潜在的应用价值。     

Direct growth of graphene on vertically standing glass by a metal-free chemical vapor deposition method

A new method to directly grow graphene on quartz glass substrate by atmospheric-pressure chemical vapor deposition (CVD) without using any catalyst was developed. The prime feature of this method is to build a vertical-glass model in the quartz tube to significantly increase the collision probability of the carbon precursors and reactive fragments between each other with the glass surface. The growth rate of high-quality graphene on glass remarkably increases compared with the conventional gas flow CVD technique. The optical transmittance and sheet resistance of the graphene glass can be readily adjusted by regulating growth time. When growth time is 35?min, the graphene glass presents an intriguing sheet resistance of about 1.48 kΩ sq^?1 at a transmittance of 93.08% and exhibits an excellent hydrophobic performance. The method is simple and scalable, and might stimulate various potential applications of transparent and conductive graphene glass in practical fields.