硫化锌纳米粒子的微乳液合成

介绍了微乳液制备纳米粒子的基本原理。对影响微乳液体系形成的主要因素如油相、水相、表面活性剂种类及用量等进行了研究，以表面活性剂TWEEN80和SPAN80作乳化剂，通过调整其比例控制乳化剂的HLB值，制备了乳化剂浓度为0.3mol/L、水/乳化剂比为6：1的W/O型庚烷/ST80/水微乳液体系。在此微乳液中制备了ZnS纳米粒子，采用TEM和XRD对超细样品的结构进行表征，表明得到的样品为β型立方晶系ZnS粒子、粒子粒径10-30nm。     

Formation of C4 species in the deactivation of a Pd/SiO2 catalyst during the selective hydrogenation of acetylene

The deactivation characteristics of Pd/SiO₂ in the selective hydrogenation of acetylene were correlated with changes in the amount of the C4 species produced. The amounts of butenes produced changed in parallel with the catalyst activity, indicating that the rate limiting step for butene production was the same as that for acetylene hydrogenation. On the other hand, the amount of 1,3-butadiene produced changed, showing a maximum with catalyst deactivation because 1,3-butadiene is an intermediate in the sequential reaction process which involves both the production and consumption of 1,3-butadiene. This was verified by a simultaneous TG/reaction experiment showing that 1,3-butadiene was a precursor of green oil. The catalyst showed a self-regenerative behavior in its activity and the amounts of C4 species produced during the early stage of deactivation because two opposite factors, which contributed to either the lowering or the promotion of activity, were involved in the process. A specific type of polymer species, produced during the initial period of deactivation, is proposed to be responsible for the promotion of catalyst activity.     

A hybrid extended finite element/level set method for modeling phase transformations

A hybrid numerical method for modelling the evolution of sharp phase interfaces on fixed grids is presented. We focus attention on two‐dimensional solidification problems, where the temperature field evolves according to classical heat conduction in two subdomains separated by a moving freezing front. The enrichment strategies of the eXtended Finite Element Method (X‐FEM) are employed to represent the jump in the temperature gradient that governs the velocity of the phase boundary. A new approach with the X‐FEM is suggested for this class of problems whereby the partition of unity is constructed with C¹(Ω) polynomials and enriched with a C⁰(Ω) function. This approach leads to jumps in temperature gradient occurring only at the phase boundary, and is shown to significantly improve estimates for the front velocity. Temporal derivatives of the temperature field in the vicinity of the phase front are obtained with a projection that employs discontinuous enrichment. In conjunction with a finer finite difference grid, the Level Set method is used to represent the evolution of the phase interface. An iterative procedure is adopted to satisfy the constraints on the temperature field on the phase boundary. The robustness and utility of the method is demonstrated with several benchmark problems of phase transformation. Copyright © 2002 John Wiley & Sons, Ltd.     

188Re-HEDP注射液药物代谢动力学研究

将药物静脉注射到动物体内 ,以观察188Re -HEDP注射液在动物体内代谢动力学的特征。结果表明 ,滞留在荷瘤大鼠患骨中的放射性比在正常骨中的多 (P <0 .0 5 ) ;小鼠 72h内排泄放射性累积百分率约为 82 %(其中尿液排泄为 80 %) ;体外血浆蛋白结合率为 86 .4 %± 0 .30 %。说明该药物是亲骨药物 ,血清除快符合药物代谢动力学二室模型 ,大部分的药物以原形从肾排出。     

城市环境的影响与作用

揭示了城市环境的基本性质的基本特征，研究了城市环境对人的心理影响和生理影响。指出城市环境建设不公要满足人的物质需要，还要满足人的精神需要。     

利用高酸值餐饮废油脂制备生物柴油

以高酸值餐饮废油脂为原料,在酯化反应后再经两步酯交换反应制备生物柴油。在酯化反应中添加吸水剂可降低油脂的酸值,经一次酯化反应即可将油脂的酸值降至2m g/g左右,满足酯交换反应的要求。考察了酯化反应中吸水剂的添加方式、种类及其用量对酯化反应的影响,以及酯交换催化剂的种类及用量对脂肪酸甲酯(FAME)收率和产物组成的影响。实验结果表明,以凹凸棒土为吸水剂(用量为餐饮废油脂中游离脂肪酸质量的3%),且在酯化反应30m in时加入,酯化效果较好;以质量比为1∶1的NaOH和KOH混合物为催化剂进行两步酯交换反应时,催化剂的最佳用量依次为1.00%和0.75%(质量分数,基于油脂的质量),FAME收率最高达到96.33%。     

EILog-05成套测井装备在长庆油田的应用

EILog-05成套测井装备是中国石油集团测井有限公司研发的具有完全自主知识产权的集成测井系统。集成化设计提高了测井仪器性能,综合化设计实现了地面系统网络化,成像测井仪器的配接成功丰富了测井项目,配套使用的一体化LEAD处理解释软件能更好地实现测井资料的现场综合解释。20井次现场试验、与ECLIPS-5700测井系统5口井的对比试验以及累计300多井次的现场应用表明,EILog-05成套测井装备的可靠性、稳定性、重复性以及与国外同类仪器测井结果的一致性均满足油田生产需要,能很好地判断长庆油田的“三低一高”复杂地层,对认识岩石三性关系和评价油气显示具有重要的作用。     

潜孔锤冲击作用下土体变形的有限元分析

潜孔锤冲击挤密钻进过程中周围土体的变形机理是一个高度非线性问题。针对潜孔锤在土中的面-面接触问题,运用Drucker-Prager屈服准则为判据,将土体视为DP材料,通过钻具与土之间的接触及施加冲击载荷来模拟钻进过程,从而建立了潜孔锤在土中冲击挤密钻进的有限元模型。利用非线性瞬态动力学有限元分析手段,对钻进过程中冲击力对土的作用加以研究,分析了钻具周围土体的应力、应变以及钻具与土体的摩擦情况。结果表明,在冲击载荷作用下,锥形钻头前端土体应力集中,并形成应力泡,冲击功主要用于竖向压缩土体,而水平方向的挤压作用相对较小,摩擦应力在钻头锥面附近出现峰值,是影响钻进速度的主要原因之一。     

浅谈火灾调查的边缘化趋势

从火灾调查实际工作状态出发,提出火灾调查存在地位边缘化的趋势,并在分析边缘化趋势原因的基础上提出了相应的对策,供火灾调查同仁探讨。     

大型电除尘器的设计、安装及操作要点

探讨了硫酸生产用大型电除尘器的要求、设计参数的选择及结构设计.指出要重视大型电除尘器的设计、制造和安装质量,并精心操作和维护,以实现长周期稳定运行.生产实践表明,只有在各个环节都做到精益求精,才能使国产大型电除尘器的质量和性能尽快达到当今世界先进水平.