Novel nitrogen‐containing epoxy resin. II. Cure kinetics by differential scanning calorimetry

The isothermal and nonisothermal cure behaviors of a novel nitrogen‐containing epoxy resin (XT resin) were studied by differential scanning calorimetry (DSC). Various kinetic parameters and details of cure process were obtained based on the Avrami theory. The results indicated that Avrami method is suitable for calculating the kinetic parameters up to the gel point at least. The apparent activation energy (E_a) for isothermal cure process was in agreement with that for nonisothermal cure process. E_a value in the early stage (78.5–81.0 KJ mol^?1) was about three times than that in the later stage (23.3–26.5 KJ mol^?1). The kinetic results from Avrami theory may present a combined effect of all factors, and which is helpful to understand the cure technique for XT–DDS system. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 3483–3489, 2006     

Oil absorbents based on styrene–butadiene rubber

Four oil absorbents based on styrene–butadiene (SBR)—pure SBR (PS), 4‐tert‐butylstyrene–SBR (PBS), EPDM–SBR network (PES), and 4‐tert‐butylstyrene‐EPDM‐SBR (PBES)—were produced from crosslinking polymerization of uncured styrene–butadiene rubber (SBR), 4‐tert‐butylstyrene (tBS), and ethylene–propylene–diene terpolymer (EPDM). The reaction took place in toluene using benzoyl peroxide (BPO) as an initiator. Uncured SBR was used as both a prepolymer and a crosslink agent in this work, and the crosslinked polymer was identified by IR spectroscopy. The oil absorbency of the crosslinked polymer was evaluated with ASTM method F726‐81. The order of maximum oil absorbency was PBES > PBS > PES > PS. The maximum values of oil absorbency of PBES and PBS were 74.0 and 69.5 g/g, respectively. Gel fractions and swelling kinetic constants, however, had opposite sequences. The swelling kinetic constant of PS evaluated by an experimental equation was 49.97 × 10^?2 h^?1. The gel strength parameter, S, the relaxation exponent, n, and the fractal dimension, d_f, of the crosslinked polymer at the pseudo‐critical gel state were determined from oscillatory shear measurements by a dynamic rheometer. The morphologies and light resistance properties of the crosslinked polymers were observed, respectively, with a scanning electron microscope (SEM) and a color difference meter.     

基于语类结构的大学英语教学模式探讨

探讨语类理论指导下的大学英语教学模式,提出了该教学模式的五个阶段:判断语篇归类,输入语境知识,形成语类结构范式,独立创作语篇和评价学生语篇。这五个阶段循环往复,能够把阅读和写作教学有效地结合起来,使两者相互促进。     

高校法律基础教学研究

分析了我国高校的法律基础教学目前存在的问题和不足.认为高校法律基础教学的目标重点是培养大学生的法治信仰.高校应加强法律基础教学师资队伍建设,提高师资队伍专业化水平.教学过程中应该实行理论教学与实践教学相结合、教师讲授与学生自学相结合、学校与家庭和社会相结合,切实提高教学实效.     

限定领域的自动问答系统研究

目前,自然语言处理系统由于缺乏语义信息及知识理解和推理能力,因此存在很多缺陷,在自动问答领域中很难分清用户表达的真正意图,并给出用户满意的答案.本文就此给出基于句法语义的问句分析方法,采用本体构建技术构建答案库,在此基础上进行领域知识语义推理,实现智能问答.本研究以黄山旅游为限定领域建立问答系统,试验结果表明多策略的方法是有效的.     

基于随机移动模型的移动sinks无线移动传感器网络性能分析与改进*

引入移动sinks节点是解决网络连通性、能耗平衡、提高网络生命周期和网络容量的有效方法。针对移动sinks节点的移动机制直接与网络性能相关,结合mWSNs体系结构,分析了基于随机移动模型的网络性能,提出了零数据包分片率的随机移动模型。理论分析与仿真结果表明,该模型能够保证数据零分片,提高了网络的时延性能和数据包传输成功率。     

超宽带传输参考接收机性能分析

在确定超宽带传输参考接收机模型的基础上,分析了基本TR接收机的误码性能,并在AWGN信道下进行了系统建模。仿真分析的结果表明,接收机的性能与脉冲对的重复数Ns、码元的积分时间以及接收机输入噪声带宽的大小之间均有规律可循,其适宜条件：Ns取3～5,标称积分时间等于脉冲宽度,噪声带宽应在保持正常接收时误码率为10-4或更低的水平选取。     

十二重准晶中负折射的研究

周期性的光子晶体中存在电磁波的负折射现象．然而,这些研究主要集中在周期性结构中,对非周期结构的研究还没有相关的报道．研究从实验和理论两个方面证明了非周期性十二重准晶光子结构同样存在负折射,并且可以实现超透镜的远场成像．利用楔形结构来验证这些条件：在频率为11．82GHz时,准周期光子晶体可以实现负折射,并且对应的有效折射率接近于-1．与周期性光子晶体相比准晶更接近于各向同性．     

基于样本分析的试题难度系数修正算法

针对当前题库试题难度系数的确定和评价标准不明确,提出一种以考试结果为样本获得难度系数并自我修正的算法:将样本数据序列{dk}构造到希尔伯特空间上,利用空间的完备性,从理论上确保序列{dk}收敛于常量D。基于该算法构造机器学习模型,它具有快速收敛和对历史数据进行学习和修正的特点。     

煤层气压裂技术研究

煤层气与常规天然气有较大差异,采用压裂施工可达到煤层气开发的理想效果。根据煤层气的特性,在施工中应注意压裂液、煤粉、压实性等因素所造成的伤害。