Synthesis and magnetic properties of novel fully conjugated polymeric complexes containing 1,10‐phenanthroline

A novel fully conjugated polymer containing 1,10‐phenanthroline (DAPcDOD) was first synthesized by the polycondensation of 2,7‐dimethyl‐2,4,6‐octatriene‐1,8‐dial with 5,6‐diamine‐1,10‐phenanthroline. Three polymeric complexes were first prepared by the reaction of DAPcDOD with NiSO₄, CoCl₂, and FeSO₄, respectively. The structures of the polymer and the complexes were characterized by IR, ¹H‐NMR, and elemental analysis. The magnetic behaviors of these complexes were measured as a function of magnetic field strength (0–50 kOe) at 5 K and as a function of temperature (5–300 K) at a magnetic field strength of 30 kOe. The results show that DAPcDOD–Ni²⁺ and DAPcDOD–Co²⁺ were soft ferromagnets, whereas DAPcDOD–Fe²⁺ exhibited the features of an antiferromagnet. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Influence of post‐treatments on the properties of porous poly(vinyl alcohol) membranes

Porous poly(vinyl alcohol) (PVA) membranes were prepared by a phase‐inversion method. The influence of chemical crosslinking and heat treatments on the swelling degree, resistance to compaction, mechanical strength, and morphology of porous PVA membranes was extensively studied. The crosslinking degree and crystallinity of the membranes, calculated from IR spectra, increased with the treatment time. The porosity, calculated on the basis of swelling experiments, showed a decreasing trend for heat‐treated membranes but remained almost at a constant value for crosslinked membranes. Such a change was further proved with scanning electron microscopy pictures. The behavior was explained by the rearrangement of PVA chains during the heat‐treatment process, which led to morphological changes in the membranes. The mechanical properties of the porous membranes in dry and wet states were measured, and a great difference was observed between crosslinked and heat‐treated membranes in the dry and wet states. The crosslinked membranes showed good mechanical properties in the dry state but became fragile in the wet state. On the contrary, the heat‐treated membranes were more flexible in the wet state than in the dry state. This change was explained by the turnaround of inner stress in the systems during the swelling process. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Structure and processability of iodinated poly(vinyl alcohol). IV. Drawability of the films iodinated at solution before casting

The drawability of iodinated at solution before casting (IBC) polyvinyl alcohol films prepared by casting aqueous solutions of 10 wt % PVA containing 15.2, 39.8, 83.2, 117.0, and 140.1% was examined with a tensile tester at 20–60°C. The tensile behavior of IBC films showed that the yield and breaking loads were much lower, and the breaking elongation was even higher than those of the unoriented iodinated after casting (IAC) films as well as the untreated PVA films. The maximum draw ratios of the films with the weight gain of 15.2, 39.8, 83.2, 117, and 140.1% were 4.5, 5.5, 8.5, 8.0, and 7.5, respectively, which were achieved at 20°C in all. The crystallinity of all films increased by the maximum draw, regardless of crystallinity before drawing. The crystalline structure was recovered to the original PVA crystalline lattice by deiodination. Amorphous orientation and initial moduli increased with the maximum draw ratio, while the orientation of crystals was constant. The orientation and moduli increased up to the weight gain of 83.2%, whose highest draw ratio and initial modulus were 8.5 and of 7.1 GPa, respectively, and then decreased. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2008     

The effect of ionic interaction on the miscibility and crystallization behaviors of poly(ethylene glycol)/poly(L‐lactic acid) blends

The effect of end groups (2NH₂) of poly(ethylene glycol) (PEG) on the miscibility and crystallization behaviors of binary crystalline blends of PEG/poly(L ‐lactic acid) (PLLA) were investigated. The results of conductivity meter and dielectric analyzer (DEA) implied the existence of ions, which could be explained by the amine groups of PEG gaining the protons from the carboxylic acid groups of PLLA. The miscibility of PEG(2NH₂)/PLLA blends was the best because of the ionic interaction as compared with PEG(2OH, 1OH‐1CH₃, and 2CH₃)/PLLA blends. Since the ionic interaction formed only at the chain ends of PEG(2NH₂) and PLLA, unlike hydrogen bonds forming at various sites along the chains in the other PEG/PLLA blend systems, the folding of PLLA blended with PEG(2NH₂) was affected in a different manner. Thus the fold surface free energy played an important role on the crystallization rate of PLLA for the PEG(2NH₂)/PLLA blend system. PLLA had the least fold surface free energy and the fast crystallization rate in the PEG(2NH₂)/PLLA blend system, among all the PEG/PLLA systems studied. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

二甲基乙醇胺在高回弹聚氨酯泡沫中的应用

分别采用二甲基乙醇胺(DMEA)和二月桂酸二丁基锡(DBTL) 2种催化剂制备了高回弹聚氨酯(HRPU)泡沫塑料.探讨了DMEA和DBTL对HRPU泡沫组合料反应活性、流动性及制品物理性能、热稳定性的影响.结果表明,以DMEA作催化剂的HRPU泡沫物理性能、热老化性及工艺稳定性优于DBTL催化剂,DMEA可以替代DBTL应用于HRPU泡沫塑料.     

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低渗气藏在已探明的天然气地质储量中占有相当大的比重。但低渗气藏的低产特征，使得这类气藏往往难以直接获得商业性开发利用，只有通过储层压裂改造才能达到经济开发要求。章根据气井压后流体渗流流动规律的变化，利用气藏的渗流理论，推导出气井压后稳态产能公式；并利用油藏数值模拟的方法，系统地分析了压裂缝长、导流能力、有效渗透率、有效厚度等对塔巴庙区块压裂初期产量大小和压后产量变化的影响，得到塔巴庙区块低渗气藏压裂井筛选原则和压裂设计参数。在做压裂选井时，应选择有效渗透率和有效厚度都较大的井进行压裂；在压裂设计时，应优选出合理的裂缝导流能力和裂缝缝长，从而为低渗气藏的高效开发提供科学决策。     

Numerical Study of Scale Effects of Ultra-Thin Nickel Beams

Recent experiments have shown that metallic materials display significant size effects when the characteristic length scale of non-uniform plastic deformation is close to a micron. Couple stress plasticity has been developed to explain such phenomena by Fleck and Hutchinson. The mechanical behaviors of ultra-thin nickel beams in different boundary conditions were studied with the hybrid element developed for couple stress plasticity before. Strong scale effects are found when the beam's thickness is close to the material characteristic length scale. Such phenomena will disappear if the beam' s thickness is greatly larger than the material characteristic length scale. The scale effect is the beams inherent property and it does not change with the change of support conditions.     

真空蒸馏脱硒的研究

本文从理论上分析了真空蒸馏脱Se的影响因素时间和温度,并通过实验给予验证,提出了最佳条件,对工业采用真空蒸馏脱出含Se物料中的Se具有一定的指导性。     

埋弧自动焊焊接H型钢柱的方法和注意事项

焊接十字形断面柱的结构特殊。对制作工艺及焊接变形控制要求较高。在实际生产中采用预先进行应力消除，组对时不加拘束，焊接时分段同向跳焊的方法成功地完成了对这一构件的制作。