Preparation and antibacterial activity of novel fluoroalkyl end-capped oligomers/silica nanocomposites-encapsulated low molecular biocides

Fluoroalkyl end-capped N-(1,1-dimethyl-3-oxobutyl)acrylamide oligomer [R_F-(DOBAA) _n -R_F] reacted with tetraethoxysilane (TEOS) and silica nanoparticles in the presence of low-molecular weight biocides such as hibitane, hinokitiol, and hinokioil under alkaline conditions to afford R_F-(DOBAA) _n -R_F/silica nanocomposites-encapsulated these biocides in excellent to moderate isolated yields. Fluoroalkyl end-capped N,N-dimethylacrylamide oligomer [R_F-(DMAA) _n -R_F] and acrylic acid oligomer [R_F-(ACA) _n -R_F]/silica nanocomposites-encapsulated hibitane were obtained under similar conditions. Dynamic light scattering measurements showed that the size of these fluorinated nanocomposites-encapsulated biocides thus obtained is nanometer size-controlled. Additionally, these fluorinated nanocomposites were shown to have a good dispersibility and stability in methanol and water. Of particular interest, these fluorinated nanocomposites-encapsulated biocides were found to have a good antibacterial activity against Staphylococcus aureus, and these nanocomposites were applied to the surface modification of traditional organic polymers such as poly(methyl methacrylate).     

Preparation of gold nanoparticles (GNP) aqueous suspensions by a new method involving Tiron

A new method is proposed to produce gold nanoparticles (GNP) by in situ reduction of a gold salt dissolved in water. The reducing agent used is Tiron instead of the citrate anion most often mentioned in literature. The influence of various parameters has been investigated, such as the content of Tiron with respect to that of the precursor of gold HAuCl₄, or the initial pH of the solution after mixing of reactants. It is shown that Tiron also exerts a positive influence as a dispersant, which impedes agglomeration of gold nanoparticles. The typical average size of GNP synthesized in the present work is close to 7 nm.     

Electrical conductivity and gas sensitivity of Zn-Sb-O thick films

The thick film of Zn-Sb-O was prepared by coating the paste of nanoparticles mixture (Sb₂O₃:ZnO=1:3) on the alumina substrate, followed by sintering at 500-900 °C for 2 h in air. The electrical resistance and gas-sensing properties to benzene, alcohol and acetone of Zn-Sb-O films were found to be dependent on the change of phase structure caused by sintering temperature.     

上海外环隧道水下最终接头的施工技术

沉管隧道采用水下最终接头,可以大大缩短工期和减少成本,但施工难度较大,而且有一定风险。文章以上海外环隧道工程为例,对沉管隧道水下最终接头的施工工艺中管段轴线精度控制、安装保护罩、间隙间的安全排水和混凝土施工等四大难点进行探讨,并介绍了水密性施工和管内结构施工的具体工艺和步骤。指出其成果对今后类似工程具有较大的参考价值。     

MIMO系统中简单的扩展空时块编码分集技术研究

本文提出一种多输入多输出（MIMO）天线系统中简单的扩展空时块编码（SSTBC）分集技术，采用沃尔什码来区分各天线发送数据子流。采用这种方法，在系统带宽一定时，不降低发送信息速率，同时接收机简单。不同天线的发送信息经过了所有收一发天线对之间的空间子信道，获得了所有路径的部分空间分集增益，仿真结果表明，这种增益的获得不受限于接收分集阶数，并且随发射天线的增加以一定的线性关系增加。     

Ultra-wideband bandpass filter with hybrid microstrip/CPW structure

A novel ultra-wideband (UWB) bandpass filter (BPF) is presented using the hybrid microstrip and coplanar waveguide (CPW) structure. A CPW nonuniform resonator or multiple-mode resonator (MMR) is constructed to produce its first three resonant modes occurring around the lower end, center, and higher end of the UWB band. Then, a microstrip/CPW surface-to-surface coupled line is formed and modeled to allocate the enhanced coupling peak around the center of this UWB band, i.e., 6.85GHz. As such, a five-pole UWB BPF is built up and realized with the passband covering the entire UWB band (3.1-10.6GHz). A predicted frequency response is finally verified by the experiment. In addition, the designed UWB filter, with a single resonator, only occupies one full-wavelength in length or 16.9mm.     

Frequency notched printed slot antenna with parasitic open-circuit stub

A new frequency notched ultra-wideband microstrip slot antenna with a parasitic tuning stub is proposed. The antenna is similar in configuration to a conventional microstrip slot antenna; by introducing a parasitic open-circuit tuning stub, flexible frequency notched function is achieved. Several properties of the antenna, such as frequency notched function, antenna transfer function and gain, have been investigated. As is reported, the operation bandwidth of the antenna is 2.91-11.16 GHz, in which a frequency notched band of 5.10-5.85 GHz has been achieved. Furthermore, good ultra-wideband linear transmission performance over the entire operation frequency range has also been achieved.     

Stimulation of negative magnetoresistance by an electric field and light in silicon doped with boron and manganese

It is experimentally ascertained that light stimulates the negative magnetoresistance observed in a high electric field in silicon doped with boron and manganese. The optimum conditions (the electric field, temperature, illumination, and resistivity of the material) for observation of the largest magnitude of negative magnetoresistance in (Si:B):Mn are determined. The dependence of the negative magnetoresistance on the concentration of compensating impurity is established.