Design of Hierarchical NiCo@NiCo Layered Double Hydroxide Core–Shell Structured Nanotube Array for High‐Performance Flexible All‐Solid‐State Battery‐Type Supercapacitors

A novel hierarchical nanotube array (NTA) with a massive layered top and discretely separated nanotubes in a core–shell structure, that is, nickel–cobalt metallic core and nickel–cobalt layered double hydroxide shell (Ni?Co@Ni?Co LDH), is grown on carbon fiber cloth (CFC) by template‐assisted electrodeposition for high‐performance supercapacitor application. The synthesized Ni?Co@Ni?Co LDH NTAs/CFC shows high capacitance of 2200 F g^?1 at a current density of 5 A g^?1, while 98.8% of its initial capacitance is retained after 5000 cycles. When the current density is increased from 1 to 20 A g^?1, the capacitance loss is less than 20%, demonstrating excellent rate capability. A highly flexible all‐solid‐state battery‐type supercapacitor is successfully fabricated with Ni?Co LDH NTAs/CFC as the positive electrode and electrospun carbon fibers/CFC as the negative electrode, showing a maximum specific capacitance of 319 F g^?1, a high energy density of 100 W h kg^?1 at 1.5 kW kg^?1, and good cycling stability (98.6% after 3000 cycles). These fascinating electrochemical properties are resulted from the novel structure of electrode materials and synergistic contributions from the two electrodes, showing great potential for energy storage applications.     

Photo‐Induced Charge‐Variable Conjugated Polyelectrolyte Brushes Encapsulating Upconversion Nanoparticles for Promoted siRNA Release and Collaborative Photodynamic Therapy under NIR Light Irradiation

Combination of photodynamic therapy (PDT) with small interfering RNA (siRNA) therapy has become a major strategy in cancer treatment for enhancing anticancer efficacy. However, developing nanoplatform that can promote siRNA release and collaborate with efficient PDT under NIR light irradiation is still a big challenge. Photo‐induced charge‐variable conjugated polyelectrolyte brushes encapsulating upconversion nanoparticles (UCNP@CCPEB) as an efficient nanoplatform are reported. Cationic conjugated polyelectrolyte brush (CCPEB) is synthesized through quaternary ammoniation of N‐functionalized polyfluorene brush by photodegradable 2‐nitrobenzyl‐2‐bromoacetate. CCPEB with abundant positive charges and intrinsic photosensitizer (PS) performance is good for integrating siRNA carrier and PS into one molecule. The obtained CCPEB next encapsulates upconversion nanoparticle for realizing its NIR light excitation. Agarose gel electrophoresis experiments show that UCNP@CCPEB present good stability and excellent siRNA‐loading capacity (1 mol UCNP@CCPEB to at least 32.5 mol siRNA). Under 980 nm light irradiation, UCNP@CCPEB exhibit efficient single oxygen production for PDT. Concurrently, the photoresponsive cationic side‐chain of CCPEB turns into zwitterionic chain and thus accelerates its siRNA release to 80%. In vitro and in vivo experiments show that the successful A549 tumor suppression is achieved by UCNP@CCPEB/siPlk1 complex under 980 irradiation. It is envisioned that UCNP@CCPEB can serve as an efficient platform for combining various phototherapies together.     

仪表自动化中继电器型开关量的探讨

变电站仪表自动化是国家电网随着科技不断发展的成果.当下变电站自动化系统中一般选用的是继电器开关量,来作为开关型控制电器的主要结构,达到对高低压回路进行接通以及断开的作用,从而实现控制以及报警的目的.文章通过对变电站自动化系统中,固态继电器开关量供电回路进行分析,对目前站控程序不统一的问题进行了归纳分析,最终给出了更为合理的接线方式,改善了目前程序不统一的问题,为我市的仪表自动化优化给出了建设性意见.     

正向小注入脉冲下多子陷阱响应和两种载流子俘获率之比

正向小注入下分析了p+-n结的多子陷阱响应。指出了其中的少子注入俘获效应。当p-n结反向偏压足够小,以致其响虚区中尾区的作用不容忽视时,多子陷阱的少子注入俘获效应就在其DLTS中明显地表现出来。这种效应可用于在小注入条件下,测量多子陷阱两种载流子俘获率之比Cp/Cn。     

1.3μm钛扩散铌酸锂无间距方向耦合器

研制成功工作波长为1.3μm的钛扩散铌酸锂无间距方向耦合器,其ON/OFF比大于17dB,开关电压小于23V,器件电极电容6pf,理论带宽大于1GHz。     

激光诱导硅表面化学镀镍

利用激光诱导化学镀技术,首次在硅片上沉积出金属镍。研究了沉积速率与各实验参量的关系,并对积沉斑的形状进行了分析和讨论。     

有预脉冲条件的激光加热等离子体的效率

本文首先从理论上对强激光辐照下的等离子体密度线型进行计算,在这个基础上,仔细地分析了有预脉冲存在情况下的激光与等离子体相互作用效率,得到在预脉冲能量为主脉冲的30%、时间间隔为100ps时,等离子体对激光能量的最大吸收效率可达到与没有预脉冲情况下的9倍左右。     

An algorithm ofk-line location for BBL in LSI/VLSI

In this paper, aK-line location algorithm for building block cells in LSI/VLSI is presented. When the relative positions of rectangular cells are given, there are 2 states according to the two orientations of a cell. It is proved that to find the optimum solution from the 2^N states can be reduced to calculate theN states inK-line algorithm. So the algorithm is shown very effective and can be used with association for cluster method in BBL placement. Under certain conditions, this method can also be used to pesudo BBL placement directly.     

ON TWO-DIRECTION SPATIAL SMOOTHING FOR ESTIMATION ANGLE-OF-DIRECTION OF COHERENT SIGNALS

Based on Evans'spatial smoothing preprocessing scheme,a new approach calledtwo-direction spatial smoothing preprocessing method is presented.It is proved that the decorre-lation,the effective aperture and the maximum number of distinguishable coherent signals(whenarray size is given)of the new method are better than those of the Evans'method.Simulationresults give a comparison between the eigenvector spectrums produced by the two methods.     

Ka频段单脉冲多层微带阵列天线设计与优化

描述了多层微带阵列天线,辐射单元通过带状线一个地板耦合馈电。为获得好的旁瓣抑制能 力及加工容差,采用遗传算法优化,得到工程上实用的天线口径分布。制作了一个天线,获 得27.3 dB的增益,波束宽度4.2°。实测结果表明在Ka频段实现了100%的旁瓣抑制 。