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61.
Fatemeh Nasrollahi Gholamreza Bakeri Ahmad Fauzi Ismail Mostafa Rahimnejad Mahdi Imanian 《Korean Journal of Chemical Engineering》2013,30(10):1867-1875
The modeling of adiabatic and non-adiabatic reactors, using three cooling mediums in the shell side of a shell and tube reactor in cocurrent and countercurrent flow regimes has been conducted. The cooling mediums used in this research are saturated water and methanol feed gas to a reactor which is preheated in the shell side and a special type of oil. The results of adiabatic reactor modeling show good compatibility with the data received from a commercial plant. The results of non-adiabatic reactor modeling showed that more methanol conversion can be achieved in a lower length of reactor, even though in some cases the maximum temperature in the tube side of the reactor is more than the deactivation temperature of the catalyst. 相似文献
62.
Amin Manouchehrian Mostafa Sharifzadeh Rasoul Hamidzadeh Moghadam Tohid Nouri 《矿业科学技术学报(英文版)》2013,23(4):495-501
Recently, many regression models have been presented for prediction of mechanical parameters of rocks regarding to rock index properties. Although statistical analysis is a common method for developing regression models, but still selection of suitable transformation of the independent variables in a regression model is difficult. In this paper, a genetic algorithm (GA) has been employed as a heuristic search method for selection of best transformation of the independent variables (some index properties of rocks) in regression models for prediction of uniaxial compressive strength (UCS) and modulus of elasticity (E). Firstly, multiple linear regression (MLR) analysis was performed on a data set to establish predictive models. Then, two GA models were developed in which root mean squared error (RMSE) was defined as fitness function. Results have shown that GA models are more precise than MLR models and are able to explain the relation between the intrinsic strength/elasticity properties and index properties of rocks by simple formulation and accepted accuracy. 相似文献
63.
Mostafa Keshavarz Moraveji Mohamad Morovati Pasand Reza Davarnejad Yusuf Chisti 《加拿大化工杂志》2012,90(1):93-99
Effects of various concentrations (0–5 ppm) of anionic (sodium dodecyl sulfate, SDS) and non‐ionic (Tween‐80 and Triton X‐405) surfactants on gas hold‐up and gas–liquid mass transfer in a split‐cylinder airlift reactor are reported for air–water. Surfactants were found to strongly enhance gas hold‐up. Non‐ionic surfactants were more effective in enhancing gas hold‐up compared to the anionic surfactant SDS. An enhanced gas hold‐up and a visually reduced bubble size in the presence of surfactants implied an enhanced gas–liquid interfacial area for mass transfer. Nevertheless, the overall gas–liquid volumetric mass transfer coefficient was reduced in the presence of surfactants, suggesting that surfactants greatly reduced the true liquid film mass transfer coefficient and this reduction outweighed the interfacial area enhancing effect. Presence of surfactants did not substantially affect the induced liquid circulation rate in the airlift vessel. 相似文献
64.
For SCR of NO the study of Ir/Al2O3 solids shows the importance of the activation procedure under mixtures containing CO (NO–C3H6–CO–O2 or NO–CO–O2). The selective reductant remains C3H6, however. The activation goes with an iridium particles sintering without Ir loss. 相似文献
65.
Mehdi Ranjbar Masoud Salavati-Niasari S. Mostafa Hosseinpour-Mashkani 《Journal of Inorganic and Organometallic Polymers and Materials》2012,22(5):1093-1100
In the present work, ZnAl2O4 nanoparticles have been synthesized with the aid of Zn(OAc)2·2H2O and Al(NO3)3·9H2O as starting reagents in the presence of microwave irradiation. Besides, the effect of preparation parameters such as microwave power and irradiation time on the morphology and particle size of products was studied by SEM images. The as-prepared ZnAl2O4 nanoparticles were characterized extensively by techniques like XRD, TEM, SEM, FT-IR, PL, and EDS. Photoluminescence studies of the ZnAl2O4 nanoparticles displayed quantum confinement behavior with band gap of 3.2 eV. The XRD studies showed that pure orthorhombic ZnAl2O4 nanoparticles have been produced after calcination. 相似文献
66.
Lc is the minimum length of carbon nanotubes (CNTs) required for efficient transfer of filler conductivity to polymer matrix in polymer CNT nanocomposites (PCNTs). In this work, Lc is correlated with the dimensions of the CNTs and the interphase thickness. Subsequently, the interfacial conductivity as well as the effective length and concentration of CNTs are expressed by CNT and interphase properties. Moreover, a simple model for the tunneling conductivity of PCNTs is developed with these effective terms. The impacts of all parameters on Lc, the interfacial conductivity, the fraction of CNTs in the networks and the conductivity of the PCNT are explained and justified. In addition, the predictions of the percolation threshold and conductivity are compared with the experimental results of several samples. The desirable values of interfacial conductivity are achieved by thin, short and super‐conductive CNTs, high waviness and a thick interphase. However, thin and long CNTs, low waviness, a thick interphase, poor tunneling resistivity due to the polymer matrix and a short tunneling distance advantageously affect the conductivity of PCNTs, because they produce large conductive networks. The predictions also show good agreement with the experimental measurements of percolation threshold and conductivity, which confirms the developed equations. © 2020 Society of Chemical Industry 相似文献
67.
Mehraneh Ghavami Mostafa Aghbolaghy Jafar Soltan Ning Chen 《Frontiers of Chemical Science and Engineering》2020,14(6):937
Volatile organic compounds (VOCs) are among the major sources of air pollution. Catalytic ozonation is an efficient process for removing VOCs at lower reaction temperature compared to catalytic oxidation. In this study, a series of alumina supported single and mixed manganese and cobalt oxides catalysts were used for ozonation of acetone at room temperature. The influence of augmenting the single Mn and Co catalysts were investigated on the performance and structure of the catalyst. The manganese and cobalt single and mixed oxides catalysts of the formula Mn10%-CoX and Co10%-MnX (where X= 0, 2.5%, 5%, or 10%) were prepared. It was found that addition of Mn and Co at lower loading levels (2.5% or 5%) to single metal oxide catalysts enhanced the catalytic activity. The mixed oxides catalysts of (Mn10%-Co2.5%) and (Mn10%-Co5%) led to acetone conversion of about 84%. It is concluded that lower oxidation state of the secondary metal improves ozone decomposition and oxidation of acetone. 相似文献
68.
Uzma Arif Nawaz M. Rana Shafia Qureshi Imran Haider Elmasry Yasser Hussain Shafiq 《Theoretical Foundations of Chemical Engineering》2020,54(6):1327-1339
Theoretical Foundations of Chemical Engineering - In this study, the simulations for first-order chemical reactions (constructive and destructive) in the flow of the Casson fluid with... 相似文献
69.
SPEEK/cSMM membrane for simultaneous electricity generation and wastewater treatment in microbial fuel cell 下载免费PDF全文
70.
Processing of High‐Density Magnesia Spinel Electro‐Conducting Ceramic Composite and its Oxidation at 1400°C 下载免费PDF全文
Zaki Zaki Nasser Mostafa Yasser Ahmed Emad Ewais Mohamed Rashad 《International Journal of Applied Ceramic Technology》2016,13(4):662-669
Dense conductive ceramic composites of MgAl2O4 and MoSi2 were processed using combustion synthesis under‐load methodology. The starting reactants were blends of MoO3, SiO2, MgO, and Al powders. The study revealed that to obtain dense composite with homogeneous microstructure, 30 wt. % of MoSi2, 18.5 μm Al average particle size, and 175 MPa load are required. The produced dense composite was found to have a low apparent porosity (<1.0 vol. %), moderate density 4.61 g/cm3, and low electrical resistivity 0.3 Ωcm. The dense composite exhibited excellent thermodynamic stability between its phases at 1400°C in open atmosphere. 相似文献