全文获取类型
收费全文 | 1151篇 |
免费 | 24篇 |
专业分类
电工技术 | 45篇 |
综合类 | 1篇 |
化学工业 | 321篇 |
金属工艺 | 25篇 |
机械仪表 | 28篇 |
建筑科学 | 13篇 |
能源动力 | 51篇 |
轻工业 | 58篇 |
水利工程 | 1篇 |
无线电 | 128篇 |
一般工业技术 | 198篇 |
冶金工业 | 230篇 |
原子能技术 | 23篇 |
自动化技术 | 53篇 |
出版年
2023年 | 6篇 |
2022年 | 10篇 |
2021年 | 18篇 |
2020年 | 7篇 |
2019年 | 8篇 |
2018年 | 15篇 |
2017年 | 8篇 |
2016年 | 14篇 |
2015年 | 14篇 |
2014年 | 25篇 |
2013年 | 52篇 |
2012年 | 29篇 |
2011年 | 40篇 |
2010年 | 43篇 |
2009年 | 43篇 |
2008年 | 33篇 |
2007年 | 37篇 |
2006年 | 38篇 |
2005年 | 37篇 |
2004年 | 40篇 |
2003年 | 42篇 |
2002年 | 28篇 |
2001年 | 24篇 |
2000年 | 25篇 |
1999年 | 35篇 |
1998年 | 92篇 |
1997年 | 71篇 |
1996年 | 56篇 |
1995年 | 23篇 |
1994年 | 26篇 |
1993年 | 30篇 |
1992年 | 15篇 |
1991年 | 14篇 |
1990年 | 18篇 |
1989年 | 16篇 |
1987年 | 5篇 |
1986年 | 7篇 |
1985年 | 8篇 |
1984年 | 9篇 |
1983年 | 7篇 |
1982年 | 7篇 |
1981年 | 12篇 |
1980年 | 7篇 |
1979年 | 10篇 |
1978年 | 10篇 |
1977年 | 7篇 |
1976年 | 11篇 |
1974年 | 5篇 |
1973年 | 6篇 |
1972年 | 13篇 |
排序方式: 共有1175条查询结果,搜索用时 0 毫秒
41.
Takashi Kojima Wataru Sakamoto Toshinobu Yogo Takashi Fujii Shin-ichi Hirano 《Journal of the American Ceramic Society》2002,85(9):2212-2216
An in situ composite composed of ceria-stabilized tetragonal zirconia polycrystals (Ce-TZP) and La{Co0.5 Fe0.5 (Fe0.9 Al0.1 )11 }O19 was synthesized from a powder mixture of Ce-TZP, La(Fe0.9 Al0.1 )O3 , Fe2 O3 , Al2 O3 , and CoO. The dense Ce-TZP dispersed with platelike La{Co0.5 Fe0.5 (Fe0.9 Al0.1 )11 }O19 crystals as a second phase were formed after sintering from 1250° to 1350°C. The saturation magnetization of the in situ composite Ce-TZP/La{Co0.5 Fe0.5 (Fe0.9 Al0.1 )11 }O19 was proportional to the mass fraction of the hexaferrite second phase in Ce-TZP. The coercivity of the composite with a 20 mass% of second phase decreased from 9.14 to 2.52 kOe (from 728 to 201 kA/m) after the pulverization of the composite. The susceptibility (χ) increased by 15%–25% under uniaxial stress on the composite. The change of the susceptibility (Δχ/χ) value increased with decreasing the mass fraction of the second phase in the composite. The Δχ was found to increase linearly with applied stress and abruptly change on cracking, which is expected for the application in fracture sensing of the composite. 相似文献
42.
Yukiko Hirano Ilde Guedes Marcus Grimsditch Chun-Keung Loong Nobuyoshi Wakabayashi Lynn A. Boatner 《Journal of the American Ceramic Society》2002,85(4):1001-1003
The room-temperature elastic constants of ErVO4 were considerably smaller than those of isostructural silicate and phosphate analogs. The generally "less-rigid" crystalline lattice and weaker metal-oxygen bond-strength in the RVO4 (R = rare earth elements) phases indicates that these materials are of interest for potential applications as an interphase component in toughened oxide ceramic composites. 相似文献
43.
Hydrothermal Synthesis and Low-Temperature Sintering of Zinc Gallate Spinel Fine Particles 总被引:1,自引:0,他引:1
Nanosized powders of single-phase zinc gallate (ZnGa2 O4 ) spinel were hydrothermally synthesized from solutions in the presence of NaOH over the pH range of 1.9 to 7.0 and from solutions above pH 7.0, i.e., the very basic medium (pH of 13.85), by removing the residual ZnO phase by washing with aqueous H2 SO4 from the precipitate mixtures of zinc gallate spinel particles and ZnO. A very wide compositional range (Zn/2Ga = 0.705–1.157) of zinc gallate spinel solid solutions could be hydrothermally synthesized in the form of nanosized particles from acid and very basic mediums (pH of 2.4–13.85) in the presence of NaOH. These hydrothermally synthesized spinel powders showed good sinterability and almost full densification at 1100°C for 1 h. Dense sintered bodies consisting of single-phase zinc gallate spinel were fabricated at 1100°C using zinc gallate spinel powders having almost stoichiometric composition formed from the solution at pH 9.95 in the presence of aqueous ammonia. 相似文献
44.
The radical polymerization of N‐isopropylacrylamide was carried out in toluene at low temperatures in the presence of silyl alcohols, such as triethylsilanol. Poly(N‐isopropylacrylamide) with a racemo dyad content of 75% was obtained at ? 80 °C with a 4:1 triethylsilanol to monomer ratio loading. NMR analysis suggests that the mechanism for syndiotactic induction, in the presence of silyl alcohols, may be similar to that observed with alkyl alcohols. In this case, a 1:2 complex formation, via hydrogen bonding interactions, leads to the induction of syndiotactic specificity. Copyright © 2012 Society of Chemical Industry 相似文献
45.
Satomi Ono Yasuo Nishi Shin-ichi Hirano 《Journal of the American Ceramic Society》2001,84(12):3054-3056
Metal surfaces can be improved in terms of thermal, mechanical, and chemical properties by a ceramic coating. The chromium-free corrosion resistance of stainless steel was achieved using a chemical solution method. Precursor solutions were prepared from metal alkoxides and were deposited on stainless-steel surfaces by dip coating and heat-treating at temperatures <500°C. The stainless steel was coated by silica, zirconia, and titania single-layer coating films, and/or coated by silica/zirconia and silica/titania double-layer coating films. The corrosion resistance was improved remarkably by a submicrometer silica-based coating on the stainless steel. 相似文献
46.
Takahiro Matsumoto Tetsuro Nose Yasuaki Nagata Katsuhiro Kawashima Tastuya Yamada Hidetoshi Nakano Satoshi Nagai 《Journal of the American Ceramic Society》2001,84(7):1521-1525
Young's modulus and Poisson's ratio of SiC ceramics at temperatures >1400°C were obtained using a laser ultrasonics method that included a Fabry-Pérot interferometer (LUFP). At temperatures <1000°C, Young's modulus and Poisson's ratio measured using the LUFP method agreed well with those measured using standard contact methods, such as the resonance method and the ultrasonic pulse method. These results showed that the LUFP method is a powerful tool for measuring high-temperature elastic properties of advanced ceramics in a noncontact manner. 相似文献
47.
Tomoko Okuyama Jun Shirakawa Kazuki Tajima Yoko Ino Heidrun Vethe Yu Togashi Mayu Kyohara Ryota Inoue Daisuke Miyashita Jinghe Li Nozomi Goto Taiga Ichikawa Shingo Yamasaki Haruka Ohnuma Rie Takayanagi Yayoi Kimura Hisashi Hirano Yasuo Terauchi 《International journal of molecular sciences》2020,21(21)
48.
Effect of Ga2O3 on Sintering and Phase Stability of Sc2O3‐Doped Tetragonal Zirconia Prepared via Aqueous Solution Route 下载免费PDF全文
Masanori Hirano Hideo Kojima Hideaki Minami 《Journal of the American Ceramic Society》2015,98(1):44-49
The effects of the presence of Ga2O3 on low‐temperature sintering and the phase stability of 4, 5, and 6 mol% Sc2O3‐doped tetragonal zirconia ceramics (4ScSZ, 5ScSZ, and 6ScSZ, respectively) were investigated. A series of zirconia sintered bodies with compositions (ZrO2)0.99?x(Sc2O3)x(Ga2O3)0.01, x = 0.04, 0.05, and 0.06 was fabricated by sintering at 1000°C to 1500°C for 1 h using fine powders that were prepared via the combination of homogeneous precipitation method and hydrolysis technique using monoclinic zirconia sols synthesized through the forced hydrolysis of an aqueous solution of zirconium oxychloride at 100°C for 168 h. The presence of 1 mol% Ga2O3 was effective in reducing sintering temperature necessary to fabricate dense bodies and enabled to obtain dense sintered bodies via sintering at 1100°C for 1 h. The phase stability, that is, low‐temperature degradation behavior of the resultant zirconia ceramics was determined under hydrothermal condition. The zirconia ceramics codoped with 1 mol% Ga2O3 and 6 mol% Sc2O3 (1Ga6ScZ) fabricated via sintering at 1300°C for 1 h showed high phase stability without the appearance of monoclinic zirconia phase, that is the tetragonal‐to‐monoclinic phase transformation was not observed in the 1Ga6ScZ after treatment under hydrothermal condition at 150°C for 30 h. 相似文献
49.
Dr. Tomoya Hirano Dr. Takashi Fujiwara Dr. Hideaki Niwa Michitake Hirano Kasumi Ohira Yusuke Okazaki Shin Sato Dr. Takashi Umehara Dr. Yuki Maemoto Prof. Akihiro Ito Prof. Minoru Yoshida Prof. Hiroyuki Kagechika 《ChemMedChem》2018,13(15):1530-1540
The histone methyltransferase SET7/9 methylates not only histone but also non‐histone proteins as substrates, and therefore, SET7/9 inhibitors are considered candidates for the treatment of diseases. Previously, our group identified cyproheptadine, used clinically as a serotonin receptor antagonist and histamine receptor (H1) antagonist, as a novel scaffold of the SET7/9 inhibitor. In this work, we focused on dibenzosuberene as a substructure of cyproheptadine and synthesized derivatives with various functional groups. Among them, the compound bearing a 2‐hydroxy group showed the most potent activity. On the other hand, a 3‐hydroxy group or another hydrophilic functional group such as acetamide decreased the activity. Structural analysis clarified a rationale for the improved potency only by tightly restricted location and type of the hydrophilic group. In addition, a SET7/9 loop, which was only partially visible in the complex with cyproheptadine, became more clearly visible in the complex with 2‐hydroxycyproheptadine. These results are expected to be helpful for further structure‐based development of SET7/9 inhibitors. 相似文献
50.
Taninaka A Hirano Y Takeuchi O Shigekawa H 《International journal of molecular sciences》2012,13(1):453-465
Dynamic force spectroscopy (DFS) makes it possible to investigate specific interactions between two molecules such as ligand-receptor pairs at the single-molecule level. In the DFS method based on the Bell-Evans model, the unbinding force applied to a molecular bond is increased at a constant rate, and the force required to rupture the molecular bond is measured. By analyzing the relationship between the modal rupture force and the logarithm of the loading rate, microscopic potential barrier landscapes and the lifetimes of bonds can be obtained. However, the results obtained, for example, in the case of streptavidin/biotin complexes, have differed among previous studies and some results have been inconsistent with theoretical predictions. In this study, using an atomic force microscopy technique that enables the precise analysis of molecular interactions on the basis of DFS, we investigated the effect of the sampling rate on DFS analysis. The shape of rupture force histograms, for example, was significantly deformed at a sampling rate of 1 kHz in comparison with that of histograms obtained at 100 kHz, indicating the fundamental importance of ensuring suitable experimental conditions for further advances in the DFS method. 相似文献