Non-linear behavior in advanced materials

<正>The 17th IUMRS International Conference in Asia was held in Qingdao from October 20th to 24th,2016.This conference contained 28international symposia.One of symposia,titled as Serration and Noise Behavior in Advanced Materials,was well organized,which provided an effective platform to discuss the non-linear behavior in advanced materials including high-entropy alloys,bulk metallic glasses,and lightweight alloys,etc.Generally speaking,serration and noise phenomenon exist everywhere,such as,the crackling noise     

Robust control of switch-mode rectifier considering nonlinear behaviour

This work presents the disturbance observer-based robust current and voltage controls for a digital signal processor (DSP)-based boost-type switch-mode rectifier (SMR) considering nonlinear behaviour. First, a robust current control scheme is developed to let the SMR inductor current waveform closely track its command around zero-crossing points, and hence the SMR possesses improved line drawn power quality. Then a robust voltage two-degrees-of-freedom control (2DOFC) scheme and its systematic design approach are proposed. In determining the power circuit components and the key parameters of the proposed robust control schemes, the compromise between the desired performance and the nonlinear behaviours is considered. Specifically, the adaptation of voltage robust compensation control is made according to the observed nonlinear phenomena. Experimental results confirm that robust and good voltage tracking and regulation responses are obtained by the developed SMR. Furthermore, the developed SMR is successfully applied to serve as a front-end converter of a switched reluctance motor drive, and its effectiveness in vibration reduction and power quality improvement is demonstrated experimentally     

Cationic cyclization of purified natural rubber in latex form with a trimethylsilyl triflate as a novel catalyst

Cyclization of deproteinized natural rubber (DPNR) or purified natural rubber latex was effectively performed in latex phase by using trimethylsilyl‐trifluoromethane sulfonate or trimethylsilyl triflate (TMSOTF) as a novel catalyst, which is still not reported in the case of natural rubber latex. Various cyclization conditions affecting the degree of cyclization were studied, such as dry rubber contents, temperature, TMSOTF concentrations, and time. The cyclized products were characterized by FTIR, Raman, ¹H‐, and ¹³C‐NMR spectroscopies, as well as DSC and TGA. The degree of cyclization was estimated by ¹H‐NMR spectrum. It was found that the degree of cyclization in NR was a function of cyclization conditions. The thermal stability of cyclized DPNR increased with the degree of cyclization. Solubility of the obtained rubber was good in chloroform, toluene, cyclohexanone, and cyclohexane, and bad in tetrahydrofuran. The average number molecular weight of cyclized DPNR with 76% degree of cyclization was about 4.2 × 10⁴ g/mol. On the basis of FTIR, Raman, ¹H‐, and ¹³C‐NMR, the C?C of cyclized DPNR dramatically decreased after prolonged reaction time. In addition, the topology of cyclization DPNR particles was rough on its rubber particle as analyzed by TEM. The mechanism for this reaction will also be discussed. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2007.     

Optimizing rainwater harvesting systems as an innovative approach to saving energy in hilly communities

Rapid urbanization is increasing the amount of hilly communities around many large cities; therefore, saving water pumping energy deserves significant priority. This work proposes optimized rooftop rainwater harvesting systems (RRWHSs) and provides an energy-saving approach for hilly communities. The most cost-effective rainwater tank volumes for different dwelling types are calculated using marginal analysis. The case study at Hua-Chan Community in northern Taiwan indicates that the optimum rainwater tank volumes range from 5 m³ to 10 m³ according to the type of dwelling. The results also reveal that rainwater harvesting becomes economically feasible when both energy and water savings are addressed together. Furthermore, the cost of unit energy saving from RRWHSs is lower than that from solar PV systems. Hence, RRWHSs provide not only water savings, but also as an alternative renewable energy-saving approach to address the water–energy dilemma caused by the ever-growing hilly communities.     

Lattice-Distortion-Enhanced Yield Strength in a Refractory High-Entropy Alloy

Severe distortion is one of the four core effects in single-phase high-entropy alloys (HEAs) and contributes significantly to the yield strength. However, the connection between the atomic-scale lattice distortion and macro-scale mechanical properties through experimental verification has yet to be fully achieved, owing to two critical challenges: 1) the difficulty in the development of homogeneous single-phase solid-solution HEAs and 2) the ambiguity in describing the lattice distortion and related measurements and calculations. A single-phase body-centered-cubic (BCC) refractory HEA, NbTaTiVZr, using thermodynamic modeling coupled with experimental verifications, is developed. Compared to the previously developed single-phase NbTaTiV HEA, the NbTaTiVZr HEA shows a higher yield strength and comparable plasticity. The increase in yield strength is systematically and quantitatively studied in terms of lattice distortion using a theoretical model, first-principles calculations, synchrotron X-ray/neutron diffraction, atom-probe tomography, and scanning transmission electron microscopy techniques. These results demonstrate that severe lattice distortion is a core factor for developing high strengths in refractory HEAs.     

Variable structure control scheme for landing on a celestial object

This paper considers the landing of a space vehicle on a celestial object. By assuming the air drag in two specific forms and the uncertainty in matching type, their effects are studied. Through the construction of a time-varying boundary layer, a new guidance control law for landing on a celestial object is proposed via the variable structure control (VSC) technique to guarantee that tracking performance is achieved at an exponential convergence rate. The proposed guidance law is continuous and alleviates chattering drawback by classic VSC design. Finally, simulation results are presented to illustrate the use of the main design.     

Aluminum Alloying Effects on Lattice Types, Microstructures, and Mechanical Behavior of High-Entropy Alloys Systems

The crystal lattice type is one of the dominant factors for controlling the mechanical behavior of high-entropy alloys (HEAs). For example, the yield strength at room temperature varies from 300 MPa for the face-centered-cubic (fcc) structured alloys, such as the CoCrCuFeNiTi _x system, to about 3,000 MPa for the body-centered-cubic (bcc) structured alloys, such as the AlCoCrFeNiTi _x system. The values of Vickers hardness range from 100 to 900, depending on lattice types and microstructures. As in conventional alloys with one or two principal elements, the addition of minor alloying elements to HEAs can further alter their mechanical properties, such as strength, plasticity, hardness, etc. Excessive alloying may even result in the change of lattice types of HEAs. In this report, we first review alloying effects on lattice types and properties of HEAs in five Al-containing HEA systems: Al _x CoCrCuFeNi, Al _x CoCrFeNi, Al _x CrFe_1.5MnNi_0.5, Al _x CoCrFeNiTi, and Al _x CrCuFeNi₂. It is found that Al acts as a strong bcc stabilizer, and its addition enhances the strength of the alloy at the cost of reduced ductility. The origins of such effects are then qualitatively discussed from the viewpoints of lattice-strain energies and electronic bonds. Quantification of the interaction between Al and 3d transition metals in fcc, bcc, and intermetallic compounds is illustrated in the thermodynamic modeling using the CALculation of PHAse Diagram method.     

Effects of Cooling Rates on Glass Formation and Magnetic Behavior for the Fe73.0C7.0Si3.3B5.0P8.7Mo3.0 Bulk Metallic Glass

In this paper, effects of cooling rates on glass formation and magnetic behavior of the Fe_73.0C_7.0Si_3.3B_5.0P_8.7Mo_3.0 (at. pct) alloy were investigated via different purging gases (i.e., helium and argon) during suction casting. X-ray diffraction patterns and transmission electron microscopy characterization confirmed that the maximum attainable diameter for glass formation is increased from 5 to 7 mm with the helium as the purging gas, relative to the argon. Meanwhile, the coercivity value (H _c) of the sample cast in helium is almost 5 times larger than that fabricated in argon, although the magnetization saturation in these two alloys is similar. Our pair distribution function analysis, density, and positron annihilation lifetime spectroscopy measurements indicated that the sample cast in helium possesses more free volume; however, the difference between them is insubstantial. Further, experimental results revealed that the residual stress in the samples cast under helium is much larger than that in those prepared in Argon, which could be responsible for the abrupt change in the coercivity.