全文获取类型
收费全文 | 56074篇 |
免费 | 4198篇 |
国内免费 | 1882篇 |
专业分类
电工技术 | 2913篇 |
技术理论 | 6篇 |
综合类 | 3005篇 |
化学工业 | 9552篇 |
金属工艺 | 3316篇 |
机械仪表 | 3412篇 |
建筑科学 | 3835篇 |
矿业工程 | 1765篇 |
能源动力 | 1850篇 |
轻工业 | 3926篇 |
水利工程 | 875篇 |
石油天然气 | 3801篇 |
武器工业 | 397篇 |
无线电 | 6277篇 |
一般工业技术 | 6880篇 |
冶金工业 | 3048篇 |
原子能技术 | 743篇 |
自动化技术 | 6553篇 |
出版年
2024年 | 1106篇 |
2023年 | 1067篇 |
2022年 | 1700篇 |
2021年 | 2451篇 |
2020年 | 1912篇 |
2019年 | 1699篇 |
2018年 | 1727篇 |
2017年 | 1859篇 |
2016年 | 1726篇 |
2015年 | 2151篇 |
2014年 | 2739篇 |
2013年 | 3143篇 |
2012年 | 3308篇 |
2011年 | 3619篇 |
2010年 | 3207篇 |
2009年 | 2874篇 |
2008年 | 2818篇 |
2007年 | 2738篇 |
2006年 | 2895篇 |
2005年 | 2474篇 |
2004年 | 1551篇 |
2003年 | 1353篇 |
2002年 | 1279篇 |
2001年 | 1003篇 |
2000年 | 1201篇 |
1999年 | 1483篇 |
1998年 | 1184篇 |
1997年 | 1014篇 |
1996年 | 1012篇 |
1995年 | 891篇 |
1994年 | 704篇 |
1993年 | 467篇 |
1992年 | 372篇 |
1991年 | 298篇 |
1990年 | 242篇 |
1989年 | 199篇 |
1988年 | 176篇 |
1987年 | 113篇 |
1986年 | 97篇 |
1985年 | 63篇 |
1984年 | 56篇 |
1983年 | 43篇 |
1982年 | 33篇 |
1981年 | 30篇 |
1980年 | 17篇 |
1979年 | 7篇 |
1978年 | 7篇 |
1977年 | 10篇 |
1976年 | 14篇 |
1975年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
991.
992.
The modulation of the yield distribution of intermediates formed in the photocatalytic degradation of organic pollutants is of extreme importance for the application of photocatalysis in environmental cleanup, as different intermediates usually exhibit distinct biological toxicity and secondary reactivity. In this paper, we report that the distribution of monohydroxylated intermediates (m-, p- and o-) formed during the photocatalytic oxidation of aromatic compounds changes with the variation of reaction conditions, such as O(2) partial pressure and substrate concentration. By detailed product analysis, theoretical calculation, and oxygen isotope labeling experiments, we show that these changes are due to the selective reduction of HO-adduct radicals (the precursors of hydroxylated intermediates) by conduction band electrons (e(cb)(-)) back to the original substrate, that is, p- and o-HO-adduct radicals are more susceptible to e(cb)(-) than the m- one. Our experiments give an example that, even under oxidative conditions, the yield distribution of isomeric intermediates can be modulated by e(cb)(-)-initiated reduction. This study also illustrates that the unique redox characteristics of photocatalysis, that is, both oxidation and reduction reactions take place on or near the surface of a single nanoparticle, can provide opportunities for the reaction control. 相似文献
993.
994.
Huiping Hu Jianxiong Hao Yongqiang Cheng Lijun Yin Yanli Ma Zhenwei Yu Lite Li 《International Journal of Food Science & Technology》2012,47(4):689-695
A low‐salt (4% NaCl, w/w) douchi supplemented with different concentration of fermented rice culture (FRC) of 0%, 5%, 10%, 15% and 20% (v/w) was produced, and the effect of FRC on microbiology, biochemistry and sensory quantity was investigated. Results indicated that FRC had a significant effect on low‐salt douchi. Compared with the control (added 0% FRC), in the other treatments, the counts of yeast and lactic acid bacteria increased by about 50%, whereas the moulds decreased by about 30%; the pH reduction was close to 4.7; total acid increased to about 1.300 g per 100 g; reducing sugar maintained a decrease to 21.07 mg per g; amino nitrogen increased to about 0.900 g per 100 g, but not above the control (1.013 g per 100 g). In general terms, total free amino acid contents and three organic acids were higher in low‐salt products than four commercial products. Sensory evaluation of products supplemented with 10% and 15% FRC revealed better overall acceptability compared with other treatments and a commercial product. 相似文献
995.
996.
Chenjie Wang Yanting Chen Yanru Cui Tianqi Zhang Dongliang Zhang Chengye Ma Shanfeng Chen Hongjun Li 《International Journal of Food Science & Technology》2021,56(9):4780-4788
Camellia oil (CO) microcapsules were developed using chitosan–soybean protein isolate (CS-SPI) complexes as wall materials and transglutaminase (TGase) as the cross-linking agent. Results indicated that CO/SPI under the ratio of 1:2 exhibited the highest microencapsulation efficiency and yield, possessing the best encapsulation effect. Morphology observation showed that CO microcapsules were intact, compact and nearly spherical. The microencapsulated CO exhibited the improved thermal resistance and significantly lower peroxide values after 3 days storage, demonstrating that the produced microcapsule was a promising way to maintain the thermal and oxidative stability of camellia oil. It could be found evidence from FTIR, which indicated that covalent cross-linking and hydrogen bonding might be involved among wall materials, and physical interactions between the core and wall materials. Therefore, the produced CO microcapsules could be an effective way to protect camellia oil, which was helpful for improving the processing and storage qualities of camellia oil. 相似文献
997.
Huifan Liu Sufen Li Yuming Zhong Siqi Lan Charles Stephen Brennan Qin Wang Lukai Ma 《International Journal of Food Science & Technology》2021,56(11):5629-5638
We characterised the formation and dynamic changes in the main aroma compounds produced during the manufacturing process of Jinxuan and Qingxin oolong tea. Thirty-five aroma compounds were investigated. Subsequent principal component and cluster analyses showed that the fresh leaves, spread leaves and rocked leaves of the two varieties of tea were distinguished from each other. Particularly, the aldehyde and ‘other’ compounds showed the highest correlation coefficients (0.71 and −0.70) among the principal. The heat map showed that the proportions of acetic acid, 3-methylbutanal and 2-methylbutanal significantly changed during the manufacturing process of the two tea varieties. The key amino acids (isoleucine, leucine, valine and aspartic acid) and enzymes (branched-chain amino acid aminotransferase, aspartate aminotransferase and acetaldehyde dehydrogenase) involved in the synthesis of 3-methylbutanal and 2-methylbutanal differed between the two varieties during manufacture. Our study reveals the characteristics of different varieties of oolong tea and their aroma formation after manufacture using the same process. 相似文献
998.
999.
为研究山梨醇酐单棕榈酸酯的防雾效果,以山梨醇酐单棕榈酸酯为主要防雾材料,通过造粒得到防雾母料,三层吹塑共挤得到防雾聚烯烃薄膜,并对防雾母料造粒加工性能、薄膜防雾性能、光学性能、力学性能进行测试。结果表明,随着防雾剂在母料中含量的增加,母料熔点降低,融熔指数提高,流动性得到提升,利于母料的加工;当防雾剂在薄膜中含量为时,水滴在薄膜表面接触角为9.72°,薄膜的防雾等级在水浴热雾与急速热雾法测试条件下可到达1级;防雾剂含量在薄膜中含量为1.5%高温测试环境下的持久性达到168 h;随着防雾剂含量继续增加,薄膜的力学性能与光学性能均不同程度的下降,防雾剂在薄膜中的含量在达到防雾要求时应控制在适当水平。 相似文献
1000.