Research on the comprehensive traffic state evaluation model linked with drivers’ perception under the vehicle networking

Unified judgment standards and methods are often adopted to identify traffic state in certain road network based on traffic flow parameters. However, drivers often have different perceptions about the traffic state on different road sections, since their expectations on traffic state vary more or less from each other on different road sections. In particular, under the vehicle networking, out of considerations for safety and other relevant factors, requirements for the correlation and coordination of running vehicles have also raised significantly. Therefore, it is necessary to take driver’s perception about the driving conditions of certain road sections into consideration to adjust the release of traffic state. This paper has provided a comprehensive traffic state evaluation model linked with driver’s perception under the vehicle networking. The authors first establish an ANFIS model based on the T–S model and then conduct statistical analysis on drivers’ perceptions about certain traffic state. At last, the authors use the results of statistical analysis as regulatory factors to amend the parameters input through ANFIS. Through simulation, this paper has demonstrated that the model established has a high rate of convergence, a high identification precision and the generalization ability to conduct researches on the identification of traffic state.     

基于贪婪路由协议的动态单/多链路故障恢复策略

针对现有的贪婪方法不能有效处理拓扑结构中链路故障的问题,提出单链路故障和多链路故障本地化恢复策略。首先,通过利用克莱因伯格的贪婪嵌入给出单链路故障恢复策略;然后,将其扩展到多链路故障的情况;最后,在基于Python/C++的仿真环境下对提出的技术进行评估。实验结果表明,该技术仅需要非常有限的资源,且造成的路由质量损耗也有限,可以实现快速切换,可依网络生成树中链路数目扩展。该技术的可扩展性、简单性和低开销使其适合于大型网络。     

基于BPEL的MDO流程建模与调度系统设计和实现

在分析多学科设计优化特点的基础上,充分集成Web services技术和BPEL技术,设计一个基于BPEL的多学科设计优化的流程建模与调度系统。重点介绍该系统的两个模块即可视化流程建模工具模块和流程调度监控平台模块的设计和实现方法。最后给出一个优化实例说明该系统的可行性。     

The influence of monomer types on the colloidal stability in the miniemulsion copolymerization involving alkoxysilane monomer

Unlike conventional emulsion polymerization, monomer droplet nucleation becomes dominant in miniemulsion polymerization, offering the miniemulsion polymerization a great advantage over conventional emulsion polymerization when incorporating alkoxysilane monomer, which can easily undergo premature hydrolysis and condensation reactions, into polymer latex. The extensive premature hydrolysis and condensation can lead to the issue of the colloidal instability. In this article, the influence of monomer types on the colloidal stability in the miniemulsion co-(or ter-)polymerization was investigated when incorporating alkoxysilane monomer into styrene or acrylate latex. In the cases of butyl acrylate (BA)/γ-methacryoxypropytrimethoxysilane (MPMS), BA/methyl methyacrlate (MMA)/MPMS, and BA/styrene (St)/MPMS miniemulsion polymerization, nearly no coagulum was observed. The obtained latex had a long shelf life. However, the coagulum was formed in the late stage of MMA/MPMS and St/MPMS miniemulsion copolymerization. The shelf life of the corresponding latex was short. The selection of the main monomer, which can fast consume alkoxysilane comonomer, was critical to obtain the stable latex. In this way, the alkoxysilane groups were completely buried in particles thus the coagulation caused by condensation reactions derived from the alkoxysilane hydrolysis among particles was suppressed.     

己内酰胺生产的绿色化

己内酰胺生产的绿色化关键是环己酮肟贝克曼重排工艺路线替代的开发。重点介绍了代替浓硫酸催化该反应的固体酸催化剂、催化剂的失活与再生、反应器工业化的方法的进展。提出采用多相催化剂取代发烟硫酸使环己酮肟转化为己内酰胺的工艺 ,该催化剂具有转化率和选择性高 ,易处理再生 ,且可用于连续化工业生产     

CAU9901的高效液相色谱分析

报道了新型植物生长调节剂CAU9901的高效液相色谱分析方法。该方法快速简捷,精密度变异系数为0.49%,相关系数为1.000 4,准确度回收率在98.89%~100.1%之间。     

[Zn(BDC)(H2O)2]n: a novel blue luminescent coordination polymer constructed from BDC-bridged 1-D chains via interchain hydrogen bonds (BDC = 1,4-benzenedicarboxylate)

A novel coordination polymer [Zn(BDC)(H₂O)₂]_n 1 (where BDC = 1,4-benzenedicarboxylate), has been synthesized and characterized by X-ray diffraction. 1 crystallizes in the monoclinic space group C2/c, a=15.09(2) Å, b=5.058(7) Å, c=12.196(16) Å, β=103.62(2)°, , Z=4. The most striking feature of 1 is that it consists of a high-dimensional network structure constructed from BDC-bridged 1-D chains via interchain hydrogen bonds. The coordination sphere of the zinc(II) ion is a distorted tetrahedron completed by four oxygen atoms from two water molecules and two BDC ligands. BDC adopts the bis-monodentated (syn–anti) coordination mode linking two adjacent zinc(II) ions. 1 shows strong blue photoluminescence as the result of the fluorescence from the intraligand emission excited state.     

高聚合度PVC／TPU共混物的制备与研究

本文研究了采用高聚合度聚氯乙烯(PVC)和热塑性聚氨酯(TPU)为主体材料制备高聚合度PVC/TPU共混物的过程,讨论了高聚合度PVC/TPU并用比、填料、增塑剂、共混工艺等因素对高聚合度PVC/TPU共混物性能的影响。     

甲缩醛空气氧化制甲醛催化剂的研制和工艺条件探讨

考察了铁钼催化剂对甲缩醛空气氧化制甲醛的催化性能。制备了多种不同钼铁比和第三、第四组分的催化剂,进行了活性评价和筛选,探讨了适宜的工艺条件范围。对于所选定的催化剂(钼铁比为1.82～1.88;铬铁比为0.1～0.38)在适宜的工艺条件(甲缩醛进料浓度4.5～5.5％;甲缩醛和氧气进料比1:2.0±0.2;空速12000～22000h~(-1);热点温度370～390℃)下,甲醛收率可达85％左右。     

直接甲醇燃料电池用碳气凝胶载铂催化剂的研究

利用溶胶—疑胶方法制备了高比表面积的碳气凝胶,利用浸渍还原法制备了Pt/碳气凝胶和Pt/C催化剂。采用BJH和TEM考察碳气凝胶的孔径分布和金属粒子的大小与分布,循环伏安曲线测试考察Pt/碳气凝胶对甲醇催化氧化性能的影响。结果表明,碳气凝胶的比表面积达到480 m2/g,孔径分布良好,催化剂金属颗粒较小,分散较好,循环伏安曲线图显示出Pt/碳气凝胶比传统的Pt/C对甲醇催化氧化性能高。