Synthesis of amphiphilic magnetic microspheres by dispersion copolymerization of styrene and poly(ethylene oxide) macromonomer

Amphiphilic magnetic microspheres ranging in diameter from 5 to 100 µm were prepared by dispersion copolymerization of styrene and poly(ethylene oxide) vinylbenzyl (PEO‐VB) macromonomer (MPEO) in the presence of Fe₃O₄ magnetic fluid. The effects of various polymerization parameters on the average particle size were systematically investigated. The average particle size was found to increase with increasing styrene concentration and initiator concentration. It also increased with decreasing stabilizer concentration and molecular weight of MPEO. The content of the hydroxyl groups localized in the microspheres ranged from 0.01 to 0.2 mmol g^?1. © 2003 Society of Chemical Industry     

Electrochemical synthesis and characterization of chloride doped polyaniline

Chloride doped polyaniline conducting polymer films have been prepared in a protic acid medium (HCl) by potentiodynamic method in an electrochemical cell and studied by cyclic voltammetry and FTIR techniques. The FTIR spectra confirmed Cl^- ion doping in the polymers. The polymerization rate was found to increase with increasing concentration of aniline monomer. But the films obtained at high monomer concentration were rough having a nonuniform flaky polyaniline distribution. Results showed that the polymerization rate did not increase beyond a critical HCl concentration. Cyclic voltammetry suggested that, the oxidation-reduction current increased with an increase in scan rate and that the undoped polyaniline films were not hygroscopic whereas chloride doped polyaniline films were found to be highly hygroscopic.     

钢塔架设计探讨

根据石油天然气工业中排气筒和火炬设计的特点，为了更好、更准确进行塔架设计。介绍了塔架设计中塔架结构几何尺寸和杆件截面的初选方法和经验数据；塔架结构受风荷载整体计算时体型系数的探讨；塔架基础在软土地基或基岩特殊条件下的处理方法。     

储层应力敏感性影响因素研究

全面分析储层应力敏感性产生的机理认为，外部因素的改变会引起储层产生应力敏感性．而储层岩石物性等内部因素对应力敏感性的强弱起决定性作用。室内岩心应力敏感性评价时．仪器与设备的精度、加载与卸载方式、实验用流体类型以及各种人为因素等都会对评价结果产生影响，其中岩心密封套在高压、高温条件下的密闭性会对实验结果产生较大影响。所以储层应力敏感性不应该从孔隙度和渗透率的高低进行简单评价，中、高渗储层和低渗储层在生产过程也都可能表现出较强的应力敏感性现象。     

溶剂脱沥青组合工艺生产重交通道路沥青

中国石化荆门分公司以江汉-阿曼混合原油和江汉-鲁宁混合原油为原料,分别采用减压蒸馏—丙烷脱沥青和减压蒸馏—添加催化裂化油浆—丙烷脱沥青工艺,生产出符合SH 0522—2000的100号道路沥青。结果表明,江汉-阿曼混合原油减压渣油中掺兑质量分数为30%的催化裂化油浆后,脱油沥青的各项性能均满足AH-70或AH-90重交通道路沥青的要求,而且薄膜烘箱试验表明,试样延度超过标准要求。     

五种恒虚警方法性能分析

比较了五种恒虚警方法在各种杂波背景下的检测性能,得出CMLD-CFAR是工程上可以实现且检测性能比较好的一种恒虚警处理方法.     

Study of Disk-Loaded Waveguide Filled with Plasma

Recently disk-loaded waveguide has been widely used in high-power traveling wave tubes (HPTWT). It has been shown in many experiments that the interaction efficiency and output power can be increased greatly by injecting plasma into the vacuum microwave device. Using field analysis, the dispersion characteristics and the interaction impedance of the disk-loaded waveguide filled with plasma are analyzed in a strong longitudinal magnetic field. In conclusion, the frequency of the TM₀₁ mode increases as the density of the plasma increases. It also can be found when the plasma density increases to a large scale, the TM₀₁ mode of the disk-loaded waveguide overlaps the TG mode, these two modes couple each other and form the new hybrid modes.     

大型结构试验和结构监测中的数据采集系统

结构试验和结构监测正在向大型化和复杂化发展,与之配套的数据采集系统也要能满足它们不断增长的需求。清华大学土木工程系开发了适用于土木工程结构试验与监测的集成数据采集系统 IMPDAS,它具有测点多,速度快,功能全等优点。它的任务,不仅仅是记录数据,而是集成并且管理数据,将各种数据信息有条理,有重点地反馈给试验者。本文将讨论计算机在大型结构试验和结构监测的数据采集及数据处理分析等方面的应用。     

西北低煤阶盆地生物成因煤层气成藏模拟研究

在美国粉河、澳大利亚苏拉特等低煤阶盆地煤层气勘探取得突破以前,一直认为具有商业价值的煤层气资源主要存在于中煤阶的煤层中,煤阶太低,一般含气量不高,不具有勘探价值。但是近几年来的发现证实,低煤阶盆地煤层厚度大,渗透率高,资源丰度大,含气饱和度高,同样可获得商业性气流,而且从其气体的成因来看,其中有很大一部分是生物成因的煤层气。利用煤层气成藏模拟装置对低煤阶含煤盆地的煤岩样品开展成藏模拟,从实验角度证明了中国西北地区虽然煤层煤阶较低,热成因气较少,但是却存在着具有商业价值的二次生物成因的甲烷气,再加上含煤层系众多,煤层厚度大,资源丰度极高,仍具有巨大的勘探潜力。