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121.
Yueling Dai Peng Yang Lianzang Chen Kejian Liao 《Petroleum Science and Technology》2002,20(5):621-632
The boron heteroatom zeolite catalyst has been modified with silicon compound by Chemical Surface Deposition of Liquid-phase (CLD) technique and the catalytic property of the modified catalyst is studied. Meanwhile, the acidity of the modified zeolite catalysts is characterized through TPD and IR technique, and the fluid adsorption method is used to determine its pore structure. The relationship between the catalytic property of the zeolite catalyst and its pore structure, its acidity has been found. The results of toluene-ethylene alkylation reaction indicate that the selectivity of p-ethyltoluene on the modified zeolite catalyst is higher than that on the zeolite catalyst before silanizated, reaching 94.14%. 相似文献
122.
123.
本文采用粉末冶金法制备了不同成分的PSZ/Mo复合材料。并对其密度、弹性模量和热膨胀系数进行了测量和分析 ,用XRD进行了物相分析。实验结果表明 :纳米氧化锆的烧结性能比金属钼好 ;弹性模量估算选用简单混合法则进行计算时应进行修正 ;钼和氧化锆在烧结时不发生化学反应。通过热压PSZ/Mo功能梯度材料的断口扫描分析发现 :虽然金属钼和纳米氧化锆具有一定增韧作用 ,但材料断裂方式仍以脆性断裂为主 相似文献
124.
The reduction of calcium sulfate to produce calcium sulfide is a part of the cyclic process for converting sulfur dioxide
to elemental sulfur that is described in Part I. The kinetics of the hydrogen reduction of nickel-catalyzed calcium-sulfate
pellets were investigated using a thermogravimetric analysis (TGA) technique at reaction temperatures between 1023 and 1088
K and hydrogen partial pressures between 12.9 and 86.1 kPa. The reactivity of nickel-catalyzed calcium-sulfate pellets was
demonstrated by the conversion of 70 pct fresh nickel-catalyzed calcium sulfate to calcium sulfide in 20 minutes at 1073 K
under a hydrogen partial pressure of 86.1 kPa. Furthermore, the reactivity remained relatively intact after ten cycles of
reactions and regenerations. This observed characteristic of the pellets is important because the solids must be reusable
for repeated cycles to avoid generating secondary pollutants. The nucleation and growth rate expression was found to be useful
in describing the kinetics of the reaction, which had an activation energy of about 167 kJ/mol (∼40 kcal/mol) in all reaction
cycles except for the first regenerated samples that were lower at 146 kJ/mol (35 kcal/mol). The reaction order with respect
to hydrogen partial pressure was 0.22 in all cycles with the exception of the first regenerated sample for which it was 0.37. 相似文献
125.
We have investigated the effect of extended dislocations (0.5-3 μm) on charge distribution in GaN epilayer grown by metalorganic chemical vapor deposition on (0001) sapphire using atomic force microscopy (AFM) and scanning surface potential microscopy (SSPM). It has been observed for the surface at the extended dislocations present in undoped GaN film to be negatively charged showing 0.04-0.2 V higher potential relative to regions that contain no dislocations. In addition to the higher potential at the dislocation core, the surrounding surfaces, including the edge of the dislocations, are also negatively charged in a symmetric way around the dislocations revealing crater-shaped higher potential regions (∼0.04 V) relative to surrounding dislocation-free area. The experimental results show that the protrusion-type of dislocation is also negatively charged and its potential is dependent on the size of dislocation. 相似文献
126.
基于公钥加密算法和PPCT动态图编码的软件指纹方案 总被引:1,自引:0,他引:1
提出了一种综合PPCT动态图编码方法和椭圆曲线加密算法的软件指纹方案,该方案将公钥加密技术和软件水印技术综合应用于软件版权的保护和验证过程中,充分利用两者的优势,具有安全性高和抗恶意篡改能力强的特点. 相似文献
127.
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129.
1960-1970年那段时间被称为立体声的黄金岁月 ,那时要调试并建立一套立体声系统是非常简单的,整个系统只包括一对音箱,一个功放(纯A/V功放或附带收音功能)或纯粹的无线电接收器以及诸如唱片机这类型的音源即可,而设置过程更是简单,只需要连接很少的几根线,再将扬声器放到一个合适的位置就可以了。[编者按] 相似文献
130.
C. Y. Liao S. N. Atluri 《International journal for numerical methods in engineering》1991,32(6):1339-1361
An efficient method, based on the Schwarz–Neumann alternating technique, is presented for computing weight functions of a general solid (3-D as well as 2-D), with embedded or surface-flaw configurations. The total rate of change of the crack-opening displacements, due to simple perturbations of crack-dimension characteristics, is conveniently decomposed into the infinite-domain and boundary-correction parts. The former is determined from available analytical solutions of ideal-shaped cracks, whereas the latter is computed numerically by imposing nil boundary-traction requirements for the displacement field corresponding to the weight functions. Numerical examples, with solutions for 3-D weighted-average and local stress intensity factors, indicate that the proposed method is very accurate and efficient. 相似文献