Effect of structural and electrochemical properties of different Cr-doped contents of Li[Ni1/3Mn1/3Co1/3]O2

Layered Li[Ni_(1−x)/3Mn_(1−x)/3Co_(1−x)/3Cr_x]O₂ materials with x = 0, 0.01, 0.02, 0.03, 0.05 are prepared by a solid-state pyrolysis method. The oxide compounds were calcined with various Cr-doped contents, which result in greater difference in morphological (shape, particle size and specific surface area) and the electrochemical (first charge profile, reversible capacity and rate capability) differences. The Li[Ni_(1−x)/3Mn_(1−x)/3Co_(1−x)/3Cr_x]O₂ powders were characterized by means of X-ray diffraction (XRD), charge/discharge cycling, cyclic voltammetry, and SEM. XRD experiment revealed that the Li[Ni_(1−x)/3Mn_(1−x)/3Co_(1−x)/3Cr_x]O₂ (x = 0, 0.01, 0.02, 0.03, 0.05) were crystallized to well layered -NaFeO₂ structure. The first specific discharge capacity and coulombic efficiency of the electrode of Cr-doped materials were higher than that of pristine material. When x = 0.02, the sample showed the highest first discharge capacity of 241.9 mAh g⁻¹ at a current density of 30 mA g⁻¹ in the voltage range 2.3–4.6 V, and the Cr-doped samples exhibited higher discharge capacity and better cycleability under medium and high current densities at room temperature.     

孤岛油田馆陶组湖相沉积认识及应用

济阳拗陷新近系馆陶组普遍发育河流相的观念由来已久,研究中重点通过连续取芯井的岩芯观察,以及综合利用录井、测井、古生物及相关分析化验资料,运用沉积学理论,丰富和发展了原有孤岛油田馆陶组仅仅普遍发育河流相的沉积观点,认为馆陶组下段不仅发育砾质辫状河沉积,还发育辫状河三角洲-充填型浅水湖泊沉积体系;馆陶组上段初期发育辫状河、曲流河等河流相沉积,中晚期发育浅水三角洲-氧化型浅水湖泊以及浅水振荡湖泊沉积体系.湖相沉积模式在与油田生产密切相关的小层对比和油气勘探中的应用广泛.     

基于STC单片机的焊接摆动器控制系统的设计

介绍了基于STC单片机焊接摆动器控制系统的设计,包括电源模块、单片机控制模块、直流电机脉宽调制(PWM)调速模块、红外线二极管检测与放大电路模块、人机交互模块等系统硬件设计,以及用C语言实现的系统软件设计.该系统能够控制焊枪以特定的预置参数进行摆动并配合一台小车进行流水线操作,从而达到自动焊接过程中的特殊要求.通过现场运行,系统稳定,可靠性高,满足工业现场要求.     

基于模拟退火的AVO无井约束反演

AVO(振幅随入射角变化)反演是一个非线性的组合最优化过程,运用弹性介质模型参数正演生成合成记录,以拟合观测数据。对于没有井资料的地区,结合勘探区域的地质情况对地震数据进行反演,最终得到勘探区域岩石物性参数。采用模拟退火算法进行AVO无井约束反演,对理论模型进行了试算,证明了模拟退火算法在AVO无井约束反演中的可行性。在模拟退火过程中,控制参数选择是重要的一步,要针对所要处理数据进行试验来确定这些参数的合理范围,如果参数选择不当,容易陷入局部极值,得到不理想的结果。     

发展低碳经济对旅游业的要求和影响

阐述了低碳经济和低碳旅游的内涵,认为旅游业作为低污染行业,可在发展低碳经济方面起到引领和示范的作用。分析了低碳经济对旅游主体、旅游客体、旅游媒体的影响。     

基于MATLAB/Simulink的染料敏化太阳能电池输出特性仿真

根据染料敏化太阳能电池(DSSC)的等效电路,应用MATLAB/Simulink工具建立仿真模型,对DSSC的输出伏安特性及输出功率进行仿真,讨论串联电阻和分流电阻对DSSC性能的影响.仿真结果表明,随着串联电阻的增加,开路电压不变,短路电流密度、最大输出功率及填充因子降低;随着分流电阻的增加,开路电压、短路电流密度、...     

具有核壳相反转特性的丙烯酸酯/硅氧烷共聚乳液的合成

以丙烯酸丁酯，甲基丙烯酸甲酯，八甲基环四硅氧烷和适量γ－甲基丙烯酰氧丙基三甲氧基硅烷为原料，以过硫酸铵和十二烷基苯磺酸为复合引发催化剂，采用一步乳液聚合法（即自由基共聚与缩聚反应同步进行），制成了涂料用，具有核壳结构的丙烯酸酯（核）／硅氧烷（壳）共聚乳液，考察了聚合温度，硅氧烷用量，乳化剂种类，乳液放置时间对共聚物乳胶粒形态及其粒径的影响，结果表明，乳液放置一定时间后，乳胶粒结构发生相反转，最终变成以聚硅氧烷为核，聚丙烯酯酯为壳的热力学稳定结构。     

A low‐profile antenna with circularly polarized reconfigurable and omnidirectional radiation patterns

A low profile circularly polarized (CP) antenna with reconfigurable polarization is designed and presented, which can radiate omnidirectional patterns that can be switched between left‐hand circularly polarized (LHCP) and right‐hand circularly polarized (RHCP). A pair of arc‐shaped complementary dipoles is acted as reconfigurable elements by bridging four pin diodes at the dipole arced arms. A meander phase shift line is employed to connected the arc dipole arms and plate cavity to adjust the phase relationship of two sources. The proposed antenna exhibits the omnidirectional radiation pattern by combining six identical elements placed in a circular array configuration. 24 p‐i‐n diodes are exploited to six elements, by manipulating the dc bias voltage across the diodes, the polarization state of the antenna can be switched. The patterns of the antenna are similar to that of a dipole, but its size is only about Φ0.87 × 0.029λ₀ at 5.8 GHz. The overlapped bandwidth of measured 3‐dB axial ratio (AR) and 10‐dB return loss is 5.724‐5.87 and 5.738‐5.91 GHz for two polarization states, which are right on the target of ISM band. It can be well adapted to medical diagnosis systems.     

基于MEMS电容式加速度计的闭环读出电路设计

设计了面向圆片级封装的一种闭环加速度计读出电路.在基于电容式微加速度计结构的读出电路设计中考虑了寄生电容对整个系统的影响.用MATLAB SIMULINK对所设计的读出电路进行了建模仿真.在仿真过程中分析了噪声、圆片级封装与普通封装的寄生参数及实际工艺中流水结构的不对称性的影响并进行了比较.结果表明,所设计传感器及读出电路的非线性误差在量程±20 gn范围内小于0.5％;圆片级封装的稳定时间在2 ms,小于普通封装的稳定时间;基于圆片级封装的对称性梳齿结构的输出电压灵敏度为328 mV/gn.     

一种面向水下传感器网络的监测系统设计方法

当前水下监测系统缺乏统一的开发规范,软件可复用性低,难以快速、高效地进行系统设计与实现;提出了基于水下传感器网络的监测系统设计方法,将系统结构分为观测平台、本地观测服务器、数据服务器,从数据获取、数据管理、数据展示方面给出了软件的总体开发流程,并提出了统一的软件数据模型和软件开发模型;在数据模型中,对监测元数据以及监测数据进行规范化描述;在软件开发模型中,构建了可扩展的功能组件库,通过对组件进行配置,可快速生成满足用户需求的监测系统;通过在不同的应用开发中进行验证,证明该方法能够在保证系统质量的前提下,显著提高开发效率.