天然肉桂油臭氧化制取苯甲醛

利用天然肉桂油中富含的肉桂醛，经过臭氧化反应和还原反应制得了苯甲醛。由该法制得的苯甲醛在国际上可作为天然苯甲醛使用。     

Nanosized silica‐supported metallocene/MAO catalyst for propylene polymerization

A nanosized silica particle was used as the support to prepare an Et[Ind]₂ZrCl₂/MAO catalyst for propylene polymerization of polypropylene. The catalyst and the polymer produced were characterized with nitrogen adsorption, ICP, DSC, SEM, TEM, XRD, solution viscometer, ¹³C NMR and optical microscopy. The effects of polymerization temperature and [Al]/[Zr] ratio on catalyst activity and polymer melting point were investigated. Under identical reaction conditions, nanosized catalyst exhibited better polymerization activity than the microsized catalyst (e.g., the former had 64% higher activity than the latter at the optimum polymerization temperature (50°C) and [Al]/[Zr] = 570). DSC results indicated that polymer melting point increased with the increase of [Al]/[Zr] ratio and with the decrease of polymerization temperature. XRD results showed that the percentage of γ crystals increased with decreasing [Al]/[Zr] ratio. Electron microscopic results showed that the polymer particle size increased with increasing polymerization temperature. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 2573–2580, 2006     

试论我国法律监督的范围

针对法律监督范围的理论和实践的现状,在对法律监督范围的应然状态和确定依据予以系统阐述的同时,提出重构我国检察机关法律监督范围的建议。     

浅议招标代理业务的开拓与发展

近年来,不少学者、行内人士在对招标代理市场、招标代理工作开展、企业发展等方面进行研究和探讨,我仅站在一个招标代理人员的角度,浅谈招标代理业务的开拓与发展。     

发动机润滑油理化指标与介电常数关系分析

通过实验检测电容传感器电容值的变化,验证了润滑油中水含量、铁含量和总酸值的变化量与润滑油介电常数增值之间的数量关系。结果表明:随着润滑油含水、总酸值、含铁的增加,润滑油介电常数变化趋势一致;对润滑油介电常数变化影响最大的是含水量;用介电常数作为评价润滑油衰变程度的综合指标在理论上是可行的。     

大港歧北斜坡三维地震深层目标精细处理及地质效果分析

歧北斜坡深层沙二、沙三段发育沿岸滩坝、辫状河水道及斜坡扇沉积体系。储层总体比较发育,但是横向变化大,单层厚度薄。现有地震资料横、纵向上地震分辨率低,无法满足砂体追踪和精细储层预测的要求。通过运用叠前反褶积、静校正、能量调整、叠后提高分辨率等技术,并实施处理解释一体化工作模式,处理质量过程控制等方法,使处理成果地震资料在保持地层波组特征不变的情况下,纵横向分辨率有了较大程度的提高,成像特征有了较大幅度的改善,基本上满足了地质需求。利用新处理的资料,通过井震结合,储层地球物理特征分析,在常规波阻抗反演的基础上,利用拟波阻抗反演的方法预测了沙二、三段各油组砂体的空间展布规律。取得了较好的地质效果。     

KINETICS AND MECHANISM OF THE REACTION BETWEEN OZONE AND O-CRESOL IN AQUEOUS SOLUTIONS

The stopped-flow spectrophotomctric method was applied to study the kinetics of the ozonation of o-cresol in aqueous solutions of pH values varying from 2 to 9 at 10 to 40°C. The fast reaction between o-cresol and ozone is second order overall with first order in each reactant. The ozonation rale increases with the temperature and pH value of the solution. In neutral solutions, the overall rate constant increases from 422,000 M^-1S^-1 at 10°C to 1,549,000 M^-1 S^-1 at 40°C. The activation energy is about 30 KJ/mol in the neutral solutions; it increases slightly with the acidity of the solution.

A mechanism based on the initial attack of ozone moleculesat the ortho and para positions of o-cresol is proposed for the ozonation reaction. According to this mechanism, three moles of ozone are required to react with each mole of o-cresol resulting in the rupture of the aromatic ring and production of various acids. The oxidation products were identified by these and other investigators. The proposed mechanism yields a second order kinetics for the overall reaction, as confirmed by the kinetic experiments.     

Solid polymer electrolytes. XI. Preparation,characterization and ionic conductivity of new plasticized polymer electrolytes based on chemical‐covalent polyether–siloxane hybrids

A new hybrid polymer electrolyte system based on chemical‐covalent polyether and siloxane phases is designed and prepared via the sol–gel approach and epoxide crosslinking. FT‐IR, ¹³C solid‐state NMR, and thermal analysis (differential scanning calorimetry (DSC) and TGA) are used to characterize the structure of these hybrids. These hybrid films are immersed into the liquid electrolyte (1M LiClO₄/propylene carbonate) to form plasticized polymer electrolytes. The effects of hybrid composition, liquid electrolyte content, and temperature on the ionic conductivity of hybrid electrolytes are investigated and discussed. DSC traces demonstrate the presence of two second‐order transitions for all the samples and show a significant change in the thermal events with the amount of absorbed LiClO₄/PC content. TGA results indicate these hybrid networks with excellent thermal stability. The EDS‐0.5 sample with a 75 wt % liquid electrolyte exhibits the ionic conductivity of 5.3 × 10^?3 S cm^?1 at 95°C and 1.4 × 10^?3 S cm^?1 at 15°C, in which the film shows homogenous and good mechanical strength as well as good chemical stability. In the plot of ionic conductivity and composition for these hybrids containing 45 wt % liquid electrolyte, the conductivity shows a maximum value corresponding to the sample with the weight ratio of GPTMS/PEGDE of 0.1. These obtained results are correlated and used to interpret the ion conduction behavior within the hybrid networks. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 1000–1007, 2006     

Ozonation of Humic Substances: Effects on Molecular Weight Distributions of Organic Carbon and Trihalomethane Formation Potential

Four different sources of humic substances were studied to determine the effects of ozonation on molecular weight-distributions, based on dissolved organic carbon (DOC) and trihalomethane formation potential (THMFP). Solutions of two soil-derived fulvic acids and a one soil-derived humic acid, as well as dissolved organic matter (DOM) associated with a natural water source were studied. Both gel permeation chromatography (GPC) and ultrafiltration (UF) were employed to define apparent molecular weight (AMW). Applied ozone doses ranged from 2.0 to 2.5 mg O₃/mg DOC. Overall samples of untreated and ozonated waters, as well as individual molecular weight fractions, were characterized according to DOC, UV absorbance, and THMFP. Ozonation resulted in a significant disappearance of higher AMW material with a corresponding increase in lower AMW material. Although little overall reduction in DOC concentration was observed, significant overall reductions in UV absorbance and THMFP levels were observed.     

基于矢量传感器的无人驾驶车辆信号远程监测系统

传统无人驾驶车辆远程检测系统,由于信号传输距离的影响,在信号波传输过程中在电路耦合率衰减下出现监测信号清晰度降低,信号整体监测效果无法满足实际检测系统应用要求的问题;对此设计系统通过采用矢量传感器对系统变量、模量与定量数据进行矢量统一计算,提出基于矢量传感器的无人驾驶车辆信号远程监测系统;首先完成基于矢量传感器的系统总体框架设计;然后根据设计框架建立无人驾驶车辆监控信号交互硬件单元,通过不同矢量传感器构成监控信号数据矢量转换计算平台;最后通过对硬件平台的矢量化软件适配,完成硬件与软件监控信号统一,提升信号传输强度,增强信号清晰度,从而满足无人驾驶车辆信号远程监测要求,完成系统的设计;通过对比实验数据表明,设计的基于矢量传感器的无人驾驶车辆信号远程监测系统,能够在50～100 km范围内稳定监测车辆状态,车辆状态数据监测实时性与连续性明显优于传统检测系统.