In Situ Formation of Hexaferrite Magnets within a 3Y-TZP Matrix: La2O3–ZnO–Fe2O3 and BaO–Fe2O3 Systems

The in situ formation of magnetoplumbite-type (M-type) hexaferrites within a 3Y-TZP matrix was examined for the La₂O₃–ZnO–Fe₂O₃ and BaO–Fe₂O₃ systems. The formation of barium hexaferrite (Ba-M) was rapid enough at a temperature of 1300°C for 2 h to result in a uniform dispersion of fine Ba-M particles in a tetragonal zirconia polycrystal (TZP) matrix. However, the formation of lanthanum-substituted hexaferrite (La-M) was rather sluggish, despite the existence of a charge-compensating divalent oxide. The 3Y-TZP/20-wt%-BaFe₁₂O₁₉ in situ composite possessed good magnetic properties, as well as moderately good mechanical properties.     

Multiwavelength all-optical TDM switching using a semiconductoroptical amplifier in a loop mirror

We report simultaneous all-optical switching of multiple wavelengths using an optical loop mirror with an asymmetrically placed semiconductor optical amplifier. Switching is shown for 14-wavelength channels (across 14-nm bandwidth) with switching contrast of 10-23 dB     

Mixed powder coating film using thermoplastic polyester and its alkaline resistance

To improve alkaline resistance, a newly mixed powder coating film using thermoplastic polyethylene terephthalate (PET) was investigated. Two kinds of polyvinyl butyral (PVB) and two kinds of polyamide (PA) were chosen as the secondary polymer. The melting temperatures (T _ms) of these materials were lower than that of primary PET polymer so the mixed powder coating was able to form a dual phase film through a fluidized bed coating process. Microscope and Fourier transform infrared spectroscopy (FTIR) observations revealed that the dual phase structure was indeed successfully formed and there was a secondary layer over the entire surface area of the film. This mixed powder coating film significantly enhanced the alkaline resistance to an environment filled with NaOH solution at 40°C in which a secondary material would be effective in protecting the film. With regard to both alkaline resistance and film formability, PET/PVB was superior to the PET/PA mixture.     

Chained aggregation model with minimum truncation error

A reduced–order model for a multi–input single–output or a single–input multi–output continuous system is proposed. The model is especially suitable for the case where accuracy in the high-frequency region is important. It also satisfies basic conditions for reduced-order models, such as uniqueness, stability, and a simple calculation requirement. Chained aggregation with the minimization of truncation errors introduces an internal system representation characterized by a system matrix of Hessenberg form and a diagonalized covariance matrix.     

Improvement of anode oxidation reaction of a fuel cell using ammonium formate with Pt‐Ir catalysis

We have attempted to develop high‐performance and safe fuel cells by using ammonium formate as a solid (powder) fuel. This solid fuel has the potential of safer transportability than liquid fuels such as methanol from the viewpoint of toxicity and flammability. In order to make use of some of the advantages of ammonium formate, we investigated the oxidation characteristics of ammonium formate with respect to a Pt electrode. Cyclic voltammograms indicate that ammonium formate has high oxidation activity with respect to a Pt electrode. We have also found that the oxidation of ammonium formate can be improved by the addition of Ir to Pt catalysts. It is highly likely that ammonium formate will be useful as a solid (powder) fuel for polymer electrolyte membrane (PEM) fuel cells. This new fuel will promote the development of safe fuel cells for PEM. © 2010 Wiley Periodicals, Inc. Electr Eng Jpn, 174(4): 45–50, 2011; Published online in Wiley Online Library ( wileyonlinelibrary.com ). DOI 10.1002/eej.21043     

ALIS method for high‐resolution color PDPs

This paper describes the Alternate Lighting of Surfaces (ALIS) method as a promising drive technology which can lead to high‐resolution plasma‐display panels (PDPs). This technology provides a resolution of more than 1000 scanning lines without lowering luminance, thus enabling the essential requirements of HDTV. Moreover, it allows the number of scanning electrodes to be halved in comparison with the conventional method, as well as the circuit scale to be minimized due to the use of the single scanning drive. The ALIS method is expected to be a key technology that will help PDPs penetrate the TV market.     

日本水坝的安全管理和地震安全评价

日本是一个地震多发的国家,而特殊的地形又决定了水坝在其经济社会发展中具有重要的地位,因此水坝的安全管理和地震安全评价就成为一个至关重要的方面.     

Growth and led evaluation ofN-type conductive lec gaas co-doped with in and si

Dislocation-free and low dislocation densityn-type conductive GaAs crystals, 50 mm in diameter, were grown by the In and Si co-doping LEC technique. Two-dimensional LED arrays were fabricated on substrates obtained from these crystals by the MOCVD technique and the influence of the In doping on the LED characteristics was examined. The light output power of LEDs fabricated on co-doped substrate with an In concentration of 1 ×10²⁰atoms/cm³ are low and are non-uniformly distributed, as compared with the boat-grown substrate, even though the co-doped substrate is dislocation-free. However, the LED properties of a substrate with an In concentration of 2 × 10¹⁸atoms/cm³ are the same as those of a boat-grown substrate. The light output power of the LEDs becomes higher as the In concentration in the substrate decreased.     

Palladium‐Catalyzed Three‐Component Reaction of 3‐(Tri‐n‐ butylstannyl)allyl Acetates,Aldehydes, and Triorganoboranes: An Alternative to the Carbonyl Allylation Using α,γ‐Substituted Allylic Tin Reagents

A three‐component reaction of 3‐(tri‐n‐butylstannyl)allyl acetates, aldehydes, and triorganoboranes in the presence of a palladium‐Xantphos catalyst system predominately gave (E)‐anti‐homoallylic alcohols with high diastereoselectivity and good to high levels of alkene stereocontrol. An efficient chirality transfer was observed when an enantioenriched substrate was employed. The reaction was initiated by the formation of an allylic gem‐palladium/stannyl intermediate, which subsequently underwent allylation of the aldehyde by an allyltributyltin followed by a coupling reaction of the in‐situ‐generated (E)‐vinylpalladium acetate with the triorganoborane.

     

Optical and acoustical investigation for plastic deformation of isotactic polypropylene/ethylene-1-hexene copolymer blends

The effects of morphology on mechanism of plastic deformation are investigated for binary blends of isotactic polypropylene and rubbery ethylene-1-hexene copolymers. In this work, plastic deformation developed during elongation is investigated by measuring light transmittance, electron microscopy, and ultrasonic propagation in the temperature region between 298 K and 353 K. It is found that the compatible blends hardly show stress-whitening at any temperature, whereas the incompatible blends show distinct stress-whitening below 333 K. Furthermore, microscopic defects such as microvoids and crystalline defects are found to be precursors for crazing which are origin of the stress-whitening.