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41.
42.
For multi-step heterogeneous consecutive reactions affected entirely by interphase diffusion under isothermal condition, the
equations for the effectiveness factors, the surface concentrations and the point yields were derived in terms of the Damkoehler
numbers or the measurables from the mass balances set up on the assumption that the mass-transfer rate balances the surface-reaction
rate at steady state.
From the analyses of the equations derived, the effectiveness factors for the intermediate steps and the surface concentrations
of intermediates were understood to be enhanced by the measurables inclusive of the concentrations and the mass-transfer coefficients.
Then the effect of the concentrations was concluded to be most significant. The effects of these measurables to the effectiveness
factors and the surface concentrations were qualitatively discussed for simple consecutive reactions and also for additive
consecutive reactions. Especially, as for two-step additive consecutive reactions, the effects of measurables η Da and the
concentrations to the effectiveness factors were examined with graphical presentations.
Finally, the brief discussion of the dependency of the Damkoehler number upon reaction time and the effect of the Renolds
number and diffusivity to the extent of the mass-transfer resistance were presented. 相似文献
43.
以Bi(NO3)3·5H2O和Ti(OC4H9)4为原料,NaOH为矿化剂,采用水热法制备了形貌规则的单晶Bi4Ti3O12纳米片。X射线衍射(XRD)结果表明,所合成的产物为正交相层状钙钛矿结构的Bi4Ti3O12。场发射扫描电子显微镜(FESEM)研究显示:样品是由大量边缘尺寸接近200nm,厚度约为15nm的片状结构组成。利用X射线光电子能谱(XPS)研究产物的化学组分和价态分布。室温拉曼光谱研究表明,Bi4Ti3O12纳米片的声子寿命和热稳定性低于相应的块体材料。 相似文献
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45.
以构造层序、层序地层分析和基准面分析原理为手段,利用高分辨率地震剖面、测井、岩相等资料,重点研究了东营凹陷胜北断裂带深断陷型湖盆层序中的低位体系域砂体沉积特征、发育规律及其石油地质意义.研究表明,沙三期胜北断裂带的活动形成了断裂坡折带,该坡折带控制沙三段层序低位体系域冲积扇、扇三角洲、浊积扇和小型三角洲等砂体的发育及时空展布.断裂坡折带控制的低位体系域砂体位于层序底部、最大湖泛面之下,成藏条件优良,是隐蔽油气藏勘探的主要方向. 相似文献
46.
模拟我国南方沿海浪溅区和水位变动区的海工钢筋混凝土结构物的腐蚀环境,对掺入粉煤灰和矿渣的混凝土抗氯离子侵蚀性进行了试验。结果表明,在水灰比相同的条件下,加掺和料的混凝土抗氯离子侵蚀性高于普通混凝土。 相似文献
47.
Polyester‐based polyurethane/nano‐silica composites were obtained via in situ polymerization and investigated by Fourier‐transform infrared spectroscopy (FTIR), or FTIR coupled with attenuated total reflectance (FTIR‐ATR), Transmission electron microscopy (TEM), atomic force microscopy (AFM), an Instron testing machine, dynamic mechanical analysis (DMA) and ultraviolet‐visible spectrophotometry (UV‐vis). FTIR analysis showed that in situ polymerization provoked some chemical reactions between polyester molecules and nano‐silica particles. FTIR‐ATR, TEM and AFM analyses showed that both surface and interface contained nano‐silica particles. Instron testing and DMA data showed that introducing nano‐silica particles into polyurethane enhanced the hardness, glass temperature and adhesion strength of polyurethane to the substrate, but also increased the resin viscosity. UV‐vis spectrophotometry showed that nano‐silica obtained by the fumed method did not shield UV radiation in polyurethane films. Copyright © 2003 Society of Chemical Industry 相似文献
48.
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50.
In many automatic face recognition systems,posture constraining is a key factor preventing them from application.In this paper a series of strategies will be described to achieve a system which enables face recognition under varying pose.These approaches include the multi-view face modeling,the threschold image based face feature detection,the affine transformation based face posture normalization and the template matching based face identification.Combining all of these strategies,a face recognition system with the pose invariance is designed successfully,Using a 75MHZ Pentium PC and with a database of 75 individuals,15 images for each person,and 225 test images with various postures,a very good recognition rate of 96.89% is obtained. 相似文献