Functionalization of Tailored Porous Carbon Monolith for Decontamination of Radioactive Substances

As the control over radioactive species becomes critical for the contemporary human life, the development of functional materials for decontamination of radioactive substances has also become important. In this work, a three-dimensional (3D) porous carbon monolith functionalized with Prussian blue particles was prepared through removal of colloidal silica particles from exfoliated graphene/silica composite precursors. The colloidal silica particles with a narrow size distribution were used to act a role of hard template and provide a sufficient surface area that could accommodate potentially hazardous radioactive substances by adsorption. The unique surface and pore structure of the functionalized porous carbon monolith was examined using electron microscopy and energy-dispersive X-ray analysis (EDS). The effective incorporation of PB nanoparticles was confirmed using diverse instrumentations such as X-ray diffraction (XRD), Fourier-transform infrared (FT-IR), and X-ray photoelectron spectroscopy (XPS). A nitrogen adsorption/desorption study showed that surface area and pore volume increased significantly compared with the starting precursor. Adsorption tests were performed with ¹³³Cs ions to examine adsorption isotherms using both Langmuir and Freundlich isotherms. In addition, adsorption kinetics were also investigated and parameters were calculated. The functionalized porous carbon monolith showed a relatively higher adsorption capacity than that of pristine porous carbon monolith and the bulk PB to most radioactive ions such as ¹³³Cs, ⁸⁵Rb, ¹³⁸Ba, ⁸⁸Sr, ¹⁴⁰Ce, and ²⁰⁵Tl. This material can be used for decontamination in expanded application fields.     

In Situ Fully Light‐Driven Switching of Superhydrophobic Adhesion

An in situ fully light‐driven switching of superhydrophobic adhesion is demonstrated based on simply spin‐coating a hydrophobic azo‐polymer on an optimized micro‐nanopost arrayed silicon substrate. Furthermore, the detailed designing principles are discussed, which might shed light on efficient exploitation of superhydrophobic liquid/solid interfaces for smart microfluidic control.     

Using frames to disambiguate prepositions

In natural language processing (NLP), disambiguation is the procedure used to solve name conflicts of polysemic concepts (different meanings); in fact, phrase disambiguation is a problem not totally solved in NLP. Several disambiguation types exist; for instance, noun disambiguation (bank is a word with several meanings) or when a word is both used as a noun and as a preposition. Work herein reported describes an algorithm and its implementation to disambiguate prepositions in Spanish phrases; some of them are: a {to} (Translation to English are in bold for explanation purposes; they give only one of the senses of the Spanish word, which usually have multiple meanings.), ante {before}, bajo {under}, cabe {fits}, desde {from}, contra {against}, en {in}, por {by}, según {according to}, sin {without}, entre {between}, so {under}, con {with}, hacia {towards}, sobre {about}, hasta {until}, de {of}, tras {after}, para {for}. This tool will be used in a text analyzer (being built) that converts a text document to its corresponding ontology representation, with the goal of allowing another program to use the information to answer non trivial questions (**).     

EDGE技术在电力设备远程监控系统中的应用

阐述了EDGE无线路由通信系统的性能优越性,对系统硬件设计和软件设计进行了分析。将EDGE技术应用于电力系统监控中,保证了现场对实时性和可靠性的要求。     

Synthesis and characterization of La2Ti2O7 employed for photocatalytic degradation of reactive red 22 dyestuff in aqueous solution

Perovskite structured La₂Ti₂O₇ catalyst prepared by polymerized complex method was characterized and examined the photocatalytic activity by decomposing an azo dyestuff, Reactive Red 22, in aqueous solutions under UV irradiation. La₂Ti₂O₇ powders prepared by polymerized complex method exhibit higher surface areas, better homogeneity and are more sensitive to solution than those prepared by solid-state method. The first derivatives of UV–vis DRS patterns confirmed the complete crystallization of La₂Ti₂O₇ sintered at temperatures higher than 900 °C. The effects of sintering temperature of catalyst and solution pH of photocatalytic reaction were studied. The photocatalytic decomposition of Reactive Red 22 per unit surface area was found to be higher for experiments using La₂Ti₂O₇ than using TiO₂. However, the electron–hole recombination was found to be more obvious for La₂Ti₂O₇ than for TiO₂ because the network of metal cations constructed within La₂Ti₂O₇ enhances the mobility of photogenerated electrons and holes.     

Multifinality in implicit choice.

This research examines the possibility that people's choices in the service of an explicit focal goal may also reflect their tendency to fulfill implicit background goals and in that sense are multifinal. We carried out 5 experimental studies to investigate this notion. In Experiment 1, a primed implicit goal affected individuals' choices even when those avowedly served an explicit “focal” goal. Experiment 2 replicated this finding with a different type of implicit goals. Experiment 3 found that primed implicit goals had no effect on choices where the options that served them undermined the explicit goal. Experiment 4 found that a primed implicit goal served by a multifinal option does not privilege it over a unifinal option if that goal had been already attained by a different means. Finally, Experiment 5, via 3 types of control groups, showed that choices were affected by both the explicit and implicit goals in isolation, and they shifted toward multifinality when these goals were conjointly present. The discussion considers the integrative potential of the multifinality framework and its implications for a variety of phenomena in the domain of motivated cognition. (PsycINFO Database Record (c) 2011 APA, all rights reserved)     

A Composite Formation Route to Well‐Crystalline Manganese Oxide Nanocrystals: High Catalytic Activity of Manganate–Alumina Nanocomposites

Manganese oxide nanocrystals are combined with aluminum oxide nanocrystals to improve their crystallinity via calcination without a significant increase of crystal size. A nanocomposite, consisting of two metal oxides, can be synthesized by the reaction between permanganate anions and aluminum oxyhydroxide keggin cations. The as‐prepared manganese oxide–aluminum oxide nanocomposite is X‐ray amorphous whereas heat‐treatment gives rise to the crystallization of an α‐MnO₂ phase at 600 °C and Mn₃O₄/Mn₂O₃ and γ‐Al₂O₃ phases at 800 °C. Electron microscopy and N₂ adsorption‐desorption‐isotherm analysis clearly demonstrate that the as‐prepared nanocomposite is composed of a porous assembly of monodisperse primary particles with a size of ～20 nm and a surface area of >410 m² g^?1. Of particular interest is that the small particle size of the as‐prepared nanocomposite is well‐maintained up to 600 °C, a result of the prevention of the growth of manganate grains through nanoscale mixing with alumina grains. The calcined nanocomposite shows very‐high catalytic activity for the oxidation of cyclohexene with an extremely high conversion efficiency of >95% within 15 min. The present results show that the improvement of the crystallinity without significant crystal growth is very crucial for optimizing the catalytic activity of manganese oxide nanocrystals.     

Intact and impaired mechanisms of action understanding in autism.

Typically developing children understand and predict others' behavior by extracting and processing relevant information such as the logic of their actions within the situational constraints and the intentions conveyed by their gaze direction and emotional expressions. Children with autism have difficulties understanding and predicting others' actions. With the use of eye tracking and behavioral measures, we investigated action understanding mechanisms used by 18 children with autism and a well-matched group of 18 typically developing children. Results showed that children with autism (a) consider situational constraints in order to understand the logic of an agent's action and (b) show typical usage of the agent's emotional expressions to infer his or her intentions. We found (c) subtle atypicalities in the way children with autism respond to an agent's direct gaze and (d) marked impairments in their ability to attend to and interpret referential cues such as a head turn for understanding an agent's intentions. (PsycINFO Database Record (c) 2011 APA, all rights reserved)     

A study on the optimization of KCI-based index (Kor-Factor) in evaluating Korean journals

This study describes the development process of Kor-Factor, which is a novel composite evaluation index that was developed to promote Korean domestic academic journals. As more data accumulate, the Kor-Factor’s optimization process was modified in an attempt to address possible drawbacks of the original form; the result is presented in this study. This study compares Kor-Factor with the Impact Factor, which is the most well-known single element evaluation index. We found that Kor-Factor demonstrates a better power of differentiation and a greater capacity to reflect the reputability of key journals. The modified Kor-Factor, which has been developed through an optimization process, reveals a greater power of differentiation than the original Kor-Factor; however, the modified version has less capacity to reflect reputability. The evaluation elements of the modified Kor-Factor are better and are more evenly reflected on the index value than those of the original version. Finally, we propose the establishment of an appropriate data measurement period for the actual application of the index.