Novel vitamin E derivative with 4-substituted resorcinol moiety has both antioxidant and tyrosinase inhibitory properties

A novel vitamin E derivative, (6″-hydroxy-2″,5″,7″,8″-tetramethylchroman-2″-yl) methyl 3-(2′,4′-dihydroxyphenyl)propionate (TM4R), which has a chromanoxyl ring and 4-substituted resorcinol moieties, was synthesized; and its inhibitory effects on tyrosinase, antioxidant ability, and lightening effect of ultraviolet B (UVB)-induced hyperpigmentation were estimated. TM4R showed potent inhibitory activity on tyrosinase, which is the rate-limiting enzyme in melanogenesis. The scavenging activities of TM4R on 1,1-diphenyl-2-picrylhydrazyl and hydroxyl radicals were found to be nearly the same as those of α-tocopherol. Furthermore, an efficient lightening effect was observed following topical application of TM4R to UVB-stimulated hyperpigmented dorsal skin of brownish guinea pigs. These results suggest that TM4R may be a candidate for an efficient whitening agent, possibly by inhibiting tyrosinase activity and biological reactions caused by reactive oxygen species.     

Structure and Bonding in Some Gd（Ⅲ） Metal Complexes Studied by Three-Dimensional X-Ray Analysis and ^155Gd Mossbauer Spectroscopy

Some functional lanthanide metal complexes, such as acetylacetonato complexes, ethylenediaminetetraacetato complexes, were successfully applied for diagnostic technique. The authors are interested in investigating the structure and bonding in lanthanide and actinide metal complexes using 166Er, t55Gd, and 237Np Mtissbauer spectroscopies in connection with single-crystal and/or powder X-ray diffraction, making clear the differences on their structures as well as the differences in the participation of 4f and 5f orbitals in the chemical bonds. In this article, the crystal structures of two novel Gd（Ⅲ） acetylacetonato complexes, Gd（pta）3 · 2H2O （pta = 1,1,1 -trifluoro-5,5-dimethy 1-2,4-hexanedione） and Gd（bfa）3 · 2H2O （bfa = 1, 1, 1 -trifluoro-4-phenyl-2-4-butanedione） were reported. Though both of them were dihydrate and had distorted square antiprismatical structure, Gd（pta）3 · 2H2O crystallizes in the P 2 1/n （#14） monoclinic space group and its lattice parameters are a = 1.4141（6） nm, b = 1.0708（3） nm, c =2.2344（4） nm, β =952.4（2）°, and Gd（bfa）3· 2H2O crystallizes in P 212121 orthorhombic space group and its lattice parameters were a = 1.322 （1） nm, b = 2.295 （1） nm, c = 1. 0786（8） nm. In the meantime, the authors had finished a systematic investigation on the ^155Gd Mossbauer isomer shift （δ） of various Gd（Ⅲ） metal complexes having a different coordination number （C.N.） and different ratios coordinating oxygen to nitrogen. A tendency for the 6 value to decrease with an increase in the C.N, and the number of the nitrogen atom coordinating to Gd was confirmed. This indicated that the Gd-O and/or Gd-N bond in the investigated Gd（Ⅲ） metal complexes had a small covalent contribution, which was possible to be deduced from the O and/or N atoms of the lisands donating electrons to 6s, 5d, and 4f orbitals of Gd.     

“Segment-wise model” for theoretical simulation of barely visible indentation damage in composite sandwich beams: Part II – Experimental verification and discussion

When localized transverse loading is applied to a sandwich structure, the facesheet locally deflects and the core crushes. A residual dent induced by the core crushing significantly degrades the mechanical properties of the sandwich structure. In a previous paper, the authors established a “segment-wise model” for theoretical simulation of barely visible indentation damage in honeycomb sandwich beams with composite facesheets. Honeycomb sandwich beam was divided into many segments based on the periodic shape of the honeycomb and complicated through-thickness characteristics of the core were integrated into each segment. In this paper, the new model is validated by experiments using specimens with different types of honeycomb cores. In addition, the damage growth mechanism under indentation load was clarified from the viewpoint of the reaction force from the core to the facesheet. The applicability of the model to other types of core materials is also discussed.     

Mössbauer studies and magnetic properties of SnO2 doped with Fe

Transparent conducting SnO₂ powders doped with 10% Fe content were prepared by a polymerized complex method under acidic solutions, and annealed finally at 550 °C, and at 600 °C. These samples were characterized by X-ray diffraction, magnetization, and Mössbauer spectrometry at room temperature. Rutile SnO₂ phase was obtained for both samples, and the crystallite sizes were in the range of 13-14 nm. Both samples exhibit magnetization and the saturation magnetization was smaller for the sample annealed at 600 °C than for sample annealed at 550 °C. Room temperature Mössbauer spectra for both samples showed the presence of two different paramagnetic iron sites but no magnetic sextets. These results suggest that ferromagnetism originates from magnetic defects and not directly from iron ions.     

Delay-time=code division multi-access in frequency-selective channel

A new hybrid multi-access technique, called delay-time/code division multi-access (DT/CDMA), is proposed. Multiplexing is accomplished in both the delay-time domain and code domain. Delay-time division multiplexing is achieved by assigning different cyclic time delays to the same spreading sequence. At a receiver, frequency-domain equalisation, despreading, and demultiplexing are performed simultaneously in the frequency domain. The bit error rate performance when using the proposed DT/CDMA in a frequency-selective Rayleigh fading channel is evaluated by computer simulation.     

The relationships between electrical conductivity of soil and reflectance of canopy,grain, and leaf of rice in northeastern Thailand

Soil salinity is a global environmental problem and the most widespread land degradation problem that reduces crop yields and agricultural productivity. The characteristic of soil salinity is conventionally measured by the electric conductivity (EC) of soil while remote-sensing techniques have been extensively applied to detect the presence of salts indirectly through the vegetation using crop spectral reflectance. This study aims primarily to investigate whether salt stress the rice can be detected by field reflectance or not, and second, to search the significant bands of vegetation indices that can indicate the relationships between the EC of soil and field hyperspectral reflectance of canopy, grain, and leaf of rice, using the normalized difference spectral index (NDSI). Field investigations on various paddy fields in northeastern Thailand were carried out in late November 2010 during the ripening season just before harvest in an attempt to realize the applications of the field hyperspectral technique for monitoring the spread of saline soils and estimation of the effects of soil salinity on rice plants. Jasmine rice and glutinous rice were two different rice species selected for this study. Rice plant investigations were conducted by collecting data on crop length, panicle length, canopy openness, leaf area index, and digital photographs of plant conditions from each site. The statistical analysis revealed that the changes in soil EC were significantly sensitive to the ripening stages of both jasmine rice and glutinous rice planted on different levels of soil salinity. Among reflectance measurements, canopy reflectance was highly correlated with soil EC. However, the estimated accuracies of the relationship between soil EC and reflectance of glutinous rice were relatively lower than those of jasmine rice.     

Discovering characteristic patterns from collections of classical Japanese poems

Waka is a form of traditional Japanese poetry with a 1300-year history. In this paper, we attempt to discover characteristics common to a collection ofwaka poems. As a schema for characteristics, we use regular patterns where the constant parts are limited to sequences of auxiliary verbs and postpostional particles. We call such patternsfushi. The problem is to automate the process of finding significantfushi patterns that characterize the poems. Solving this problem requires a reliable significance measure for the patterns. Brāzma et al. (1996) proposed such a measure according to the MDL principle. Using this method, we report successful results in finding patterns from five anthologies. Some of the results are quite stimulating, and we hope that they will lead to new discoveries. Mayumi Yamasaki, M.A.: She received her B.E. and M.A. degrees from Kyushu Institute of Technology in 1997 and from Kyushu University in 1999, respectively. Her research interests include machine discovery and datamining. Presently, she works at Fujitsu FIP Corporation. Masayuki Takeda, Dr. Eng.: He is an Associate Professor in Department of informatics at Kyushu University. He received his B.S., M.S., and Dr. Eng. degrees from Kyushu University in 1987, 1989 and 1996 respectively. His present research interests include pattern matching algorithims, text compression, discovery science, information retrieval and natural language processing. He is a member of Information Processing Society of Japan, Japanese Society for Artificial Intelligence and Japanese Society for Soft-ware Science and Technology. Tomoko Fukuda, M.A.: She is a Lecturer at Fukuoka Jo Gakuin University and at Junshin Women’s Junior College, She received her B.A. and M.A. degrees from Fukuoka Women’s University in 1987 and from Kyushu University in 1992 respectively. Her present research interests are in Japanese literature in the Heian period and classical 31-syllable Japanese poems. She is a member of Waka-Bungaku Kai (Society for Study of Japanese Poems) and Chuko-Bungaku Kai (Society for Study of Japanese Literature in the Heian Period). Ichiro Nanri, M.A.: He is an Associate Professor at Junshin Women’s Juior College. He received his B.A. and M.A. degrees from Kyushu University in 1990 and 1995 respectively. His present research interests are in Japanese language in the Heian-Kamakura period and classical 31-syllable Japanese poems. He is a member of Kokugo Gakkai (Society for Study of Japanese Language) and Kuntengo Gakkai (Society for Studyy of Old Language).     

Layer 1 virtual private networks: driving forces and realization by GMPLS

This article describes an emerging service for next-generation networks, layer 1 virtual private networks. L1VPNs allow customers desiring to connect multiple sites to be supported over a single shared layer 1 network. In the article we first describe the transport network's evolution and the shift in expectations of both service providers and customers. We provide an overview of the motivation for L1VPNs and examples of network usage. We follow by reviewing existing GMPLS mechanisms (addressing, discovery, and signaling) for realizing L1VPN functionality and identifying other work areas.     

Synthesis and Thermal Characterization of Novel Poly(tetramethylsilanthrylenesiloxane) and Poly(tetramethylsilphenanthrylenesiloxane) Derivatives

Summary Novel poly(tetramethylsilarylenesiloxane) derivatives, i.e. poly(tetramethyl-2,6-silanthrylenesiloxane) (P1), poly(tetramethyl-9,10-silanthrylenesiloxane) (P2), and poly(tetramethyl-1,8-silphenanthrylenesiloxane) (P3), were synthesized by polycondensation of novel disilanol monomers, i.e. 2,6-bis(dimethylhydroxysilyl)-anthracene (M1), 9,10-bis(dimethylhydroxysilyl)anthracene (M2), and 1,8-bis(dimethylhydroxysilyl)phenanthrene (M3), respectively. P1 and P3 were soluble in common organic solvents, such as benzene, toluene, chloroform, dichloromethane, tetrahydrofuran, etc. whereas P2 was almost insoluble in common organic solvents. It was revealed that P1 and P3 were amorphous and that P2 exhibited the crystallinity, as deduced from differential scanning calorimetry (DSC) and X-ray diffraction measurements. The glass transition temperatures (T_g’s) of P1 (118 °C) and P3 (100 °C) were much higher than that of poly(tetramethyl-1,4-silphenylenesiloxane). The temperature at 5% weight loss (T_d5) of P3 was 500 °C, which was higher than those of P1 and P2, and comparable to that of poly(tetramethyl-1,4-silphenylenesiloxane). It would be speculated that the thermostability of the series of poly(tetramethyl-silarylenesiloxane) derivatives is dependent on the stability of arylene moieties incorporated.     

Electron-beam doping-electron radiation effects in impurity overlayers and semiconductor substrates

3-9 MeV electrons were used to introduce impurity Ge atoms into Si wafers from Ge sheets, which are in contact with a Si surface at 20-60‡C in water bath. Concentration-dependent diffusivities of ∼10-18-10^-14 cm²sec^-1 for Ge in Si were measured. Activation energies of sputtering yield for Ge and of the diffusivity of Ge in Si are estimated to be ∼0.3 eV and ∼0.58 eV, respectively. In a case of hot (∼250‡C) irradiation in ∼1x10^-3 Torr vacuum, also the similar concentration profiles of impurity atoms in the substrates were observed.