Substrate-mode holographic polarization-division multi/demultiplexer for optical communications

Based on the diffractive properties of a transmission-type phase volume hologram, a new type of polarization-division multi/demultiplexer for optical communications is presented.     

Raman-amplification and polarization-dependence measurement in a methane Raman shifter seeded by a liquid Raman oscillator

We perform Raman amplification in a high-pressure methane cell seeded by a low-threshold liquid Raman oscillator. The Raman frequency of the oscillator medium, dimethyl sulfoxide (DMSO), is tuned when it is mixed with water to fit the Raman frequency of methane. The Raman gain in this configuration is not so sensitive to the methane pressure, and the conversion efficiency is high. Using this configuration, we measure the polarization dependence of the Raman amplifier. An experiment is performed for three typical polarization states. Complete gain suppression is expected in some polarization states, but there is a little gain because of the incompleteness of the polarization state. Theoretically the results are analyzed when the x and the y components of the scattered waves are coupled.     

Diffractive-phase-element design that implements several optical functions

A scheme for the design of diffractive phase elements (DPE's) that integrates several optical functions is presented in a consistent sense based on the general theory of amplitude-phase retrieval and the Yang-Gu algorithm [Appl. Opt. 33, 209 (1994)]. We extend the original Yang-Gu algorithm to treat a system illuminated by a beam of incident light whose components are at different wavelengths, and a set of equations for determining the phase distribution of the DPE is derived. The profile of a surface-relief DPE can be designed with an iterative algorithm. Numerical simulations are carried out for the design of one-dimensional DPE's capable of both demultiplexing different wavelength components and focusing each partial wave at predetermined positions. The influence of the extension of sampling points in the DPE's from ideal geometric points to physical spots on design results is also investigated. The numerical simulation results show that the new algorithm can be used successfully to design the desired DPE's. It is therefore expected to be useful in the design of DPE's for micro-optical systems.     

Preparation of PbTiO3 thin films using an alkoxide-alkanolamine sol-gel system

The stable range of PbTiO₃ sol and the processing conditions of uniform thin films were investigated using a solution of titanium isopropoxide, three kinds of alkanolamines (monoethanolamine, diethanolamine, triethanolamine), lead acetate trihydrate and isopropanol. Depending on the sol state with various alkanolamine/alkoxide molar ratios, diethanolamine (DEA) was very effective in preparing uniform and dense oxide films through room-temperature reaction, owing to its superior stability during the hydrolysis and condensation reaction. Perovskite PbTiO₃ thin films were obtained on oxidized silicon wafer above 550 °C and completely pure films were obtained at 650 °C using DEA as a complexing agent. The dielectric constant and loss tangent of these thin films fired at 650 °C for 30 min were found to be 240 and 0.01 at 1 kHz, respectively.     

Single-Atom Metal Sites Anchored Hydrogen-Bonded Organic Frameworks for Superior “Two-In-One” Photocatalytic Reaction

Photoredox catalysis is a green solution for organics transformation and CO₂ conversion into valuable fuels, meeting the challenges of sustainable energy and environmental concerns. However, the regulation of single-atomic active sites in organic framework not only influences the photoredox performance, but also limits the understanding of the relationship for photocatalytic selective organic conversion with CO₂ valorization into one reaction system. As a prototype, different single-atomic metal (M) sites (M²⁺ = Fe²⁺, Co²⁺, Ni²⁺, Cu²⁺, and Zn²⁺) in hydrogen-bonded organic frameworks (M-HOF) backbone with bridging structure of metal-nitrogen are constructed by a typical “two-in-one” strategy for superior photocatalytic C N coupling reactions integrated with CO₂ valorization. Remarkably, Zn-HOF achieves 100% conversion of benzylamine oxidative coupling reactions, 91% selectivity of N-benzylidenebenzylamine and CO₂ conversion in one photoredox cycle. From X-ray absorption fine structure analysis and density functional theory calculations, the superior photocatalytic performance is attributed to synergic effect of atomically dispersed metal sites and HOF host, decreasing the reaction energy barriers, enhancing CO₂ adsorption and forming benzylcarbamic acid intermediate to promote the redox recycle. This work not only affords the rational design strategy of single-atom active sites in functional HOF, but also facilitates the fundamental insights upon the mechanism of versatile photoredox coupling reaction systems.     

卫星USB测控副载波同步算法研究

吉林一号卫星测控采用USB测控体制,遥控接收采用FFT+DPLL1+DPLL2的架构,FFT主要实现对载波的粗捕,DPLL1在FFT的基础上实现对载波相位的精跟踪,DPLL2实现副载波的跟踪。对遥控副载波跟踪所用到的数字PLL技术进行了研究,首先给出了载波多普勒折算到副载波上的方法,然后对模拟PLL数字化进行了详细的论述,并设计了遥控副载波同步用的PLL2,对其稳定性、快捕带及快捕时间、捕获带和捕获时间、同步速率等进行了分析和仿真。结果表明,该方法具有捕获时间短、跟踪精度高、稳定性好等特点,易于数字化实现,已成功在吉林一号系列卫星中得到应用。     

Monitoring the Dynamic Process of Formation of Plasmonic Molecular Junctions during Single Nanoparticle Collisions

The capability to study the dynamic formation of plasmonic molecular junction is of fundamental importance, and it will provide new insights into molecular electronics/plasmonics, single‐entity electrochemistry, and nanooptoelectronics. Here, a facile method to form plasmonic molecular junctions is reported by utilizing single gold nanoparticle (NP) collision events at a highly curved gold nanoelectrode modified with a self‐assembled monolayer. By using time‐resolved electrochemical current measurement and surface‐enhanced Raman scattering spectroscopy, the current changes and the evolution of interfacial chemical bonding are successfully observed in the newly formed molecular tunnel junctions during and after the gold NP “hit‐n‐stay” and “hit‐n‐run” collision events. The results lead to an in‐depth understanding of the single NP motion and the associated molecular level changes during the formation of the plasmonic molecular junctions in a single NP collision event. This method also provides a new platform to study molecular changes at the single molecule level during electron transport in a dynamic molecular tunnel junction.     

0.618法最优确定盘状摆动凸轮机构的最小基圆半径

在满足机构许用压力角条件下,采用０．６１８法最优确定盘状摆动凸轮机械的最小基圆半径。